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1.
电致发光薄膜是平板显示器的重要材料之一,我们从研究ZnS:Mn,Cu直流电致发光薄膜的大面积稳定发光开始,首次将稀土离子引进直流电致发光薄膜,实现了各色的直流电致发光,并研究其激发机理、过热电子的能量分布、稀土离子的碰撞截面和稀土离子发光中心在晶格中的位置等。在国内首先研制成功ZnS:Mn交流电致发光薄膜计算机终端显示器,并扩大面积到640×480像素(对角线10英寸)。为了实现彩色化显示,研制出稀土离子掺杂的各色交流电致发光薄膜。研究不同稀土离子在薄膜中的浓度猝灭,以便提高薄膜的发光亮度。在致力于实现彩色的过程中,首要的任务是提高蓝色电致发光薄膜的亮度和探索新的蓝色电致发光薄膜材料:从ZnS:TmF3到CaS:TmF3,发光亮度有了很大的提高;使SrS:Ce薄膜蓝色电致发光的亮度超过1000cd/m2;同时探索纳米Si和非晶Si/SiO2超晶格结构的蓝色电致发光。成功地实现了ZnS:Mn/SrS:Ce白色电致发光和SrS:HoF3三基色线谱发射的白色电致发光,发光亮度也超过1000cd/m2。 相似文献
2.
研究了不同比例的PVK与齐聚PPV衍生物DBVP掺杂体系的能量转移和发光特性.通过对PVK,DBVP及PVK:DBVP掺杂体系的UV-vis,PL和PLE光谱的研究,分析了PVK与DBVP之间的能量转移过程.利用PVK在体系中类似于溶剂的分散作用,制备了结构为ITO/PEDOT/PVK:DBVP/LiF/Al的电致发光器件,研究了掺杂体系的电致发光性能.结果表明,在掺杂体系的光致发光和电致发光中,PVK的发射被有效地抑制,PVK与DBVP之间发生了非常有效的能量转移,通过调节PVK与DBVP的比例,可以获得蓝色和绿色发光,同时可以改善器件的发光性能,当PVK与DBVP的重量比为1∶2时,器件的绿色发光效率达到1·06cd/A,此时发光亮度为52cd/m2. 相似文献
3.
报道了硅基有机微腔的电致发光(EL).该微腔由上半透明金属膜、中心有源多层膜和多孔硅分布Bragg反射镜(PS DBR)组成.半透明金属膜由Ag(20nm)构成,充当发光器件的负电极和微腔的上反射镜.有源多层膜由Al (1 nm) / LiF(05 nm) /Alq3/Alq3:DCJTB/NPB/CuPc/ITO/SiO2组成,其中的Al/LiF为电子注入层,ITO为正电极,SiO2为使正、负电极电隔离的介质层.该PS DBR是采用设备简单、成本低廉且非常省时的电化学腐蚀法用单晶Si来制备的;该PS
关键词:
电化学腐蚀
电致发光
窄峰发射
硅基有机微腔 相似文献
4.
5.
Changes in thin zinc-sulfide films under the action of the γ-radiation of Co60 are studied by investigating electroluminescence spectra of terbium embedded in these films as a luminescent probe. It is
shown that changes in the relation of the intensities of bands, a decrease in their halfwidth and the background component,
and simplification of the spectrum are observed in a short-wave region of the Tb radiation spectrum that corresponds to5D3→7Fj transitions. The same modification of the radiation spectrum is characteristic of ZnS films whose crystalline structure is
ordered in the course of thermal annealing at a temperature of 350°C. Based on the analysis of the data obtained it is inferred
that irradiating the ZnS films with small radiation doses of 104–105 rad leads to the ordering of their crystalline structure due to the elimination of one of the types of structural defects.
Institute of Physics of Semiconductors, National Academy of Sciences of Ukraine, 45, Nauka Ave., Kiev-28, 252650. Translated
from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 3, pp. 338–341, May–June, 1997. 相似文献
6.
Chongyu Mei Junqiao Ding Bing Yao Yanxiang Cheng Zhiyuan Xie Yanhou Geng Lixiang Wang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(9):1746-1757
Two orange phosphorescent iridium complex monomers, 9‐hexyl‐9‐(iridium (III)bis(2‐(4′‐fluorophenyl)‐4‐phenylquinoline‐N,C2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐PIr) and 9‐hexyl‐9‐(iridium(III)bis(2‐(4′‐fluorophenyl)‐4‐methylquinoline‐N,C2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐MIr), were successfully synthesized. The Suzuki polycondensation of 2,7‐bis(trimethylene boronate)‐9,9‐dioctylfluorene with 2,7‐dibromo‐9,9‐dioctylfluorene and Br‐PIr or Br‐MIr afforded two series of copolymers, PIrPFs and MIrPFs, in good yields, in which the concentrations of the phosphorescent moieties were kept small (0.5–3 mol % feed ratio) to realize incomplete energy transfer. The photoluminescence (PL) of the copolymers showed blue‐ and orange‐emission peaks. A white‐light‐emitting diode with a configuration of indium tin oxide/poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate)/PIr05PF (0.5 mol % feed ratio of Br‐PIr)/Ca/Al exhibited a luminous efficiency of 4.49 cd/A and a power efficiency of 2.35 lm/W at 6.0 V with Commission Internationale de L'Eclairage (CIE) coordinates of (0.46, 0.33). The CIE coordinates were improved to (0.34, 0.33) when copolymer MIr10PF (1.0 mol % feed ratio of Br‐MIr) was employed as the white‐emissive layer. The strong orange emission in the electroluminescence spectra in comparison with PL for these kinds of polymers was attributed to the additional contribution of charge trapping in the phosphorescent dopants. © 2007 Wiley Periodicals, Inc. JPolym Sci Part A: Polym Chem 45: 1746–1757, 2007 相似文献
7.
成功制备了结构为ITO/PDDOPV/PPQ/Al的异质结聚合物发光二极管。该器件在正反向偏压下均可发光。在正向偏压下的光发射主要来自PDDOPV,但在反向偏压下的光发射则包括来自PPQ的蓝光发射和PDDOPV的黄光发射。蓝光强度与黄光强度的比值随着反向偏压的增加而增加,当反向直流电压分别为22V、24V、26V、28V时,其电致发光光谱中PPQ与PDDOPV的峰高比IPPQ/IPDDOPV分别为1.092、1.329、1.605、2.046。换句话说,该器件的发光颜色是压控可调的,这对实现彩色显示是极为有利的。分析了在反向偏压下的发光机理以及IPPQ/IPDDOPV受电压控制的原因。 相似文献
8.
John A. Mikroyannidis Larysa Fenenko Masayuki Yahiro Chihaya Adachi 《Journal of polymer science. Part A, Polymer chemistry》2007,45(20):4661-4670
Three new copolymers, namely poly(fluorenevinylene‐alt‐naphthalenevinylene) ( N ), poly(fluorenevinylene‐alt‐anthracenevinylene) ( A ) and poly(fluorenevinylene‐alt‐pyrenevinylene) ( P ), were synthesized by Heck coupling of 9,9‐dihexyl‐2, 7‐divinylfluorene with a polynuclear aromatic dibromide. The 9,10‐disubstituted anthracene was obtained exclusively for A while N and P were obtained as a mixture of two isomers with predominant the 1,4‐disubstituted naphthalene and 1,8‐disubstituted pyrene, respectively. The polymers were soluble in common organic solvents and decomposed above 370 °C. Their glass transition temperature increased from 58 to 110 °C by increasing the number of the phenyl rings of the polynuclear aromatic moiety. Rather high‐efficiency blue and blue‐greenish photoluminescence (PL) of these copolymers in solution was largely decreased in their films, indicating the presence of concentration quenching in the solid state. The OLED using these polymers demonstrated green EL in the case of copolymers N and A , and red EL in the P derivative with ηEL = 0.26–0.31%. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4661–4670, 2007 相似文献
9.
John A. Mikroyannidis Helen A. Moshopoulou John A. Anastasopoulos Minas M. Stylianakis Larysa Fenenko Chihaya Adachi 《Journal of polymer science. Part A, Polymer chemistry》2006,44(23):6790-6800
Poly(9,9‐dihexylfluorene‐2,7‐vinylene‐alt‐dibenzothiophene‐2,8‐vinylene) (PS) and poly(9,9‐dihexylfluorene‐2,7‐vinylene‐alt‐dibenzothiophene‐5,5‐dioxide‐2,8‐ vinylene) (PSO) as well as corresponding model compounds were synthesized by Heck coupling. Both the polymers and model compounds were readily soluble in common organic solvents such as tetrahydrofuran, dichloromethane, chloroform, and toluene. The polymers showed a decomposition temperature at ~430 °C and a char yield of about 65% at 800 °C in N2. The glass‐transition temperatures of the polymers were almost identical (75–77 °C) and higher than those of the model compounds (26–45 °C). All samples absorbed around 390 nm, and their optical band gaps were 2.69–2.85 eV. They behaved as blue‐greenish light emitting materials in both solutions and thin films, with photoluminescence emission maxima at 450–483 nm and photoluminescence quantum yields of 0.52–0.72 in solution. Organic light‐emitting diodes with an indium tin oxide/poly(ethylene dioxythiophene):poly(styrene sulfonic acid)/polymer/Mg:Ag/Ag configuration with polymers PS and PSO as emitting layers showed green electroluminescence with maxima at 530 and 540 nm, respectively. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 6790–6800, 2006 相似文献
10.
有机薄膜电致发光器件失效过程的动态观测及分析 总被引:4,自引:0,他引:4
对有机薄膜电致发光器件失效的全过程进行了显微动态观察,发现器件工作时,有机层/金属界面形成的气泡逐渐变大变多,最终导致器件完全失效,气泡不仅含有水汽,还存在大量有机气体。 相似文献