Two Dimensional Locally Resonance Phononic Crystals for the Reduction of Vibration and Noise in Wheel-driven Bus

Acoustical Physics - In order to suppress the vibration and noise in the middle and low frequency band of the wheel-driven bus, this paper explores the application of the locally resonant phononic...     

半导体纳米复合材料的制备及其光电催化CO2还原

本实验通过模拟植物光合作用,设计制备了新颖的光电联合催化池3D-ZnO/Ni BiVO4/FTO,用电化学沉积法制备了泡沫镍负载的ZnO纳米棒光电阴极和BiVO4光电阳极,以0.1 mol·L^−1 KHCO3水溶液作为电解质,1 mmol·L^−1曙红Y为光敏剂,在−0.6 V硅太阳电池的电压下光电催化还原CO2得到了乙醇、乙酸和甲醇,总产率22.5μmol·L^−1·h^−1·cm^−2。实现了将太阳能贮存为化学能并减少了空气中的CO2,加深了学生对绿色化学和植物Calvin循环机理的理解。     

求解定常不可压Stokes方程的两层罚函数方法

借助于两套有限元网格空间提出了一种求解定常不可压Stokes方程的两层罚函数方法.该方法只需要求解粗网格空间上的Stokes方程和细网格空间上的两个易于求解的罚参数方程（离散后的线性方程组具有相同的对称正定系数矩阵）.收敛性分析表明粗网格空间相对于细网格空间可以选择很小，并且罚参数的选取只与粗网格步长和问题的正则性有关.因此罚参数不必选择很小仍能够得到最优解.最后通过数值算例验证了上述理论结果，并且数值对比可知两层罚函数方法对于求解定常不可压Stokes方程具有很好的效果.     

A Near-Infrared-Controllable Artificial Metalloprotease Used for Degrading Amyloid-β Monomers and Aggregates

Proteolysis of amyloid-β (Aβ) is a promising approach against Alzheimer's disease. However, it is not feasible to employ natural hydrolases directly because of their cumbersome preparation and purification, poor stability, and hazardous immunogenicity. Therefore, artificial enzymes have been developed as potential alternatives to natural hydrolases. Since specific cleavage sites of Aβ are usually embedded inside the β-sheet structures that restrict access by artificial enzymes, this strongly hinders their efficiency for practical applications. Herein, we construct a NIR (near-IR) controllable artificial metalloprotease (MoS₂-Co) using a molybdenum disulfide nanosheet (MoS₂) and a cobalt complex of 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid (Codota). Evidenced by detailed experimental and theoretical studies, the NIR-enhanced MoS₂-Co can circumvent the restriction by simultaneously inhibition of β-sheet formation and destroying β-sheet structures of the preformed Aβ aggregates in living cell. Furthermore, our designed MoS₂-Co is an easy to graft Aβ-target agent that prevents misdirected or undesirable hydrolysis reactions, and has been demonstrated to cross the blood brain barrier. This method can be adapted for hydrolysis of other kinds of amyloids.     

A Triply Negatively Charged Nanographene Bilayer with Spin Frustration

We report on the largest open-shell graphenic bilayer and also the first example of triply negatively charged radical π-dimer. Upon three-electron reduction, bilayer nanographene fragment molecule (C₉₆H₂₄Ar₆)₂ (Ar=2,6-dimethylphenyl) ( 1 ₂) was transformed to a triply negatively charged species 1 ₂^3.−, which has been characterized by single-crystal X-ray diffraction, electron paramagnetic resonance (EPR) spectroscopy and magnetic properties on a superconducting quantum interference device (SQUID). 1 ₂^3.− features a 96-center-3-electron (96c/3e) pancake bond with a doublet ground state, which can be thermally excited to a quartet state. It consists of 34 π-fused rings with 96 conjugated sp² carbon atoms. Spin frustration is observed with the frustration parameter f>31.8 at low temperatures in 1 ₂^3.−, which indicates graphene upon reduction doping may behave as a quantum spin liquid.     

Improved Initial Charging Capacity of Na-poor Na0.44MnO2 via Chemical Presodiation Strategy for Low-cost Sodium-ion Batteries

Sodium-ion batteries(SIBs)are promising for grid-scale energy storage applications due to the natural abundance and low cost of sodium.Among various Na insertion cathode materials,Na0.44MnO2 has attracted the most attention because of its cost effectiveness and structural stability.However,the low initial charge capacity for Na-poor Na0.44MnO2 hinders its practical applications.Herein,we developed a facile chemical presodiated method using sodiated biphenly to transform Na-poor Na0.44MnO2 into Na-rich Na0.66MnO2.After presodiation,the initial charge capacity of Na0.44MnO2 is greatly enhanced from 56.5 mA·h/g to 115.7 mA·h/g at 0.1 C(1 C=121 mA/g)and the excellent cycling stability(the capacity retention of 94.1%over 200 cycles at 2 C)is achieved.This presodiation strategy would open a new avenue for promoting the practical applications of Na-poor cathode materials in sodium-ion batteries.     

沉积粉尘的激波点火

采用瞬态阴影技术及红外光电传感器技术实验研究了沉积玉米粉的激波点火过程，并对此进行了理论分析。实验与理论分析结果表明，激波掠射沉积粉尘床后，粉尘颗粒先上扬到一定高度后才点火，颗粒的点火延迟时间与激波波前马赫数、气相氧气含量等因素有关。另外，沉积粉尘的激波点火延迟时间比相同条件下的悬浮粉尘激波点火延迟时间长。     

侧槽的拘束作用及对断裂韧性参量的影响

本文研究了侧槽对预制疲劳裂纹Ｃｈａｒｐｙ尺寸试样的拘束效应以及其对断裂韧性参量的影响。当侧槽深度大于临界值时，峰值载荷韧性Ｊｍ值与起裂韧性Ｊ１值基本相等。侧槽对试样的加厚作用可用试样的附加厚度表示，对于同样的侧槽深度，不同材料具有不等的附加厚度，试样取得最大附加厚度的侧槽深度为３３％。文中提出用拘束系数定量地估计侧槽对裂纹尖端的塑性拘束作用，能较好地解解放本试验结果。     

炸药驱动强电流短路开关的研

由于电磁轨道炮和其它强电流装置中短路运行的需要,研制了一种条形炸药驱动的大电流闭合开关。利用爆炸成型技术使金属飞板负电极在炸药部件作用下,大面积地同时切断绝缘薄膜,嵌入另一电极模槽中构成牢固的接触。开关的绝缘强度大于30kV,电感(包括传输线)小于50nH,最大峰值电流达到400kA,闭合接触电阻小于0.1m,动作时间约为14us。对于开关的爆轰,撞击及变形过程进行了一维和二维数值模拟计算,并提出了一个描述爆炸开关行为的经验模型。利用这个模型进行电磁轨道炮整个系统的数值模拟,同实验结果符合较好。