Cs4SrI6:Eu晶体的生长和闪烁性能研究

采用垂直布里奇曼法成功生长了一种Cs4SrI6:3;Eu闪烁晶体.毛坯晶体尺寸最大为φ25×70 mm3,是目前最大的Cs4SrI6:Eu单晶.XRD结果表明,晶体具有K4-CdCl6晶体结构,属于R-3C空间群,通过紫外-可见荧光光谱和X射线激发发射光谱,研究了晶体的荧光性能.研究了在137Cs662 keV辐射下Cs4SrI6:Eu单晶的闪烁性能和衰减时间,表明该晶体具有较高的光输出和优良的能量分辨率,衰减时间约为1.86μs.通过分析Eu2+在晶体中不同部位的浓度,计算出Cs4SrI6:Eu晶体中Eu2+的分凝系数约为1.136,结果表明Cs4SrI6:Eu晶体在辐射探测中具有潜在的应用前景.     

Tail wavelets in merger of binary compact objects

We present a model for tail wavelets, a phenomenon known as "echo" in the literature. The tail wavelet may appear in signal reconnaissances in the merger of binary compact objects, including black holes and neutron stars. We show that the dark matter surrounding the compact objects lead to a speculated tail wavelet following the main gravitational wave(GW). We demonstrate that the radiation pressure of the main wave is fully capable of pushing away the surrounding matter to some altitude, and splashing down of the matter excites the tail wavelet after ringing down of the main wave. We illustrate this concept in a simplified model, where numerical estimations are conducted on the specific distribution of dark matter outside the black hole horizon and the threshold values in accordance with observations. We study the full back reaction of the surrounding dark matter to the metric and find that the effect on to the tail wavelets is insignificant. We reveal the fine difference between the tail wavelets of a dressed and a bare black hole. We demonstrate that the tail wavelet can appear as a natural phenomenon in the frame of general relativity, without invoking modified gravities or quantum effects.     

Surface‐Enhanced Raman Scattering Based on Controllable‐Layer Graphene Shells Directly Synthesized on Cu Nanoparticles for Molecular Detection

Graphene shells with a controllable number of layers were directly synthesized on Cu nanoparticles (CuNPs) by chemical vapor deposition (CVD) to fabricate a graphene‐encapsulated CuNPs (G/CuNPs) hybrid system for surface‐enhanced Raman scattering (SERS). The enhanced Raman spectra of adenosine and rhodamine 6G (R6G) showed that the G/CuNPs hybrid system can strongly suppress background fluorescence and increase signal‐to‐noise ratio. In four different types of SERS systems, the G/CuNPs hybrid system exhibits more efficient SERS than a transferred graphene/CuNPs hybrid system and pure CuNPs and graphene substrates. The minimum detectable concentrations of adenosine and R6G by the G/CuNPs hybrid system can be as low as 10^?8 and 10^?10 M , respectively. The excellent linear relationship between Raman intensity and analyte concentration can be used for molecular detection. The graphene shell can also effectively prevent surface oxidation of Cu nanoparticles after exposure to ambient air and thus endow the hybrid system with a long lifetime. This work provides a basis for the fabrication of novel SERS substrates.     

Syntheses,Structures and Luminescent Properties of Eu- and Tb-MOFs with 3,5-Pyridinedicarboxylate and 1,2-Benzenedicarboxylate

Journal of Fluorescence - Two lanthanide-based MOFs (Ln-MOFs) were synthesized by reaction of Eu(III) or Tb(III) perchlorates with mixed dicarboxylates of 3,5-pdc and 1,2-bdc...     

Synthesis of PMHDO‐g‐PDEAEA well‐defined amphiphilic graft copolymer via successive living coordination polymerization and SET‐LRP

A series of well‐defined amphiphilic graft copolymer containing hydrophobic polyallene‐based backbone and hydrophilic poly(2‐(diethylamino)ethyl acrylate) (PDEAEA) side chains was synthesized by sequential living coordination polymerization of 6‐methyl‐1,2‐heptadiene‐4‐ol (MHDO) and single electron transfer‐living radical polymerization (SET‐LRP) of 2‐(diethylamino)ethyl acrylate (DEAEA). Ni‐catalyzed living coordination polymerization of MHDO was first performed in toluene to give a well‐defined double‐bond‐containing poly(6‐methyl‐1,2‐heptadiene‐4‐ol) (PMHDO) homopolymer with a low polydispersity (M_w/M_n = 1.10). Next, 2‐chloropropionyl chloride was used for the esterification of pendant hydroxyls in every repeating unit of the homopolymer so that the homopolymer was converted to PMHDO‐Cl macroinitiator. Finally, SET‐LRP of DEAEA was initiated by the macroinitiator in tetrahydrofuran/H₂O using CuCl/tris(2‐(dimethylamino)ethyl)amine as catalytic system to afford well‐defined PMHDO‐g‐PDEAEA graft copolymers (M_w/M_n ≤ 1.22) through the grafting‐from strategy. The critical micelle concentration (cmc) was determined by ?uorescence spectroscopy with N‐phenyl‐1‐naphthylamine as probe and the micellar morphology was visualized by transmission electron microscopy. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013     

液体表面张力系数的实验研究

改变液体的浓度可以调控液体的表面张力系数,各种形状膜架的挂膜时间与液体表面张力系数存在着一定的关系,本文对于这两个方面进行了实验研究,得出了相应的结果.此外,溶液的温度和空气的流动对挂膜时间都会产生影响.     

A new class of plane symmetric solution

A new class of static plane symmetric solution of Einstein field equation generated by a perfect fluid source is put forward. A special family of this new solution is investigated in detail. The constraints on the parameters by different energy conditions are studied. The classical stability of this solution is discussed. The junction conditions matching to Minkowski metric and Taub metric are analyzed respectively.     

PtBA-g-PPEGMEMA接枝共聚物的合成及其包埋阿霉素的研究

通过可逆加成-裂解链转移聚合和原子转移自由基聚合,制备了以聚丙烯酸叔丁酯为主链、以聚(聚乙二醇单甲醚甲基丙烯酸酯)为侧链的两亲性接枝共聚物PtBA-g-PPEGMEMA,该方法克服了以往通过聚合物修饰来引入接枝点时所存在的接枝点密度不高和不可控的局限性.接着,以PtBA-g-PPEGMEMA为载体,对抗肿瘤药物阿霉素进行了负载,制备得到了尺寸为164.8nm的纳米载药胶束.其释放试验表明,该体系具有缓释特征.