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气相色谱-质谱法测定富马酸二甲酯时内标物的选择 总被引:1,自引:0,他引:1
探讨了当采用气相色谱-质谱法测定富马酸二甲酯(DMFU)时内标物的选择问题。采用HP-5MS毛细管色谱柱,在50℃~300℃范围内程序升温分离及采用在50~400amu范围内全扫描方式和选择离子监测模式检测。试验结果表明:以丙二酸二甲酯(DMM)、丙二酸二乙酯(DEM)和戊二酸二甲酯(DMG)作为内标物,既能保持DMFU与3种内标物有良好的分离度,又能保持长久的稳定性,且3种内标物与DMFU的保留时间差均小于2.8min。DMFU的线性范围均为0.005~5.0mg·L~(-1)。方法用于实际样品中DMFU的测定,以上3种物质作为内标,所得结果无显著差别,因此DMM、DEM、DMG均可作为比较理想的内标物用于日常用品中DMFU的检测。 相似文献
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The determination of uranium isotopic composition in trace samples is important in different fields. A new measurement method that uses an accelerator mass spectrometry (AMS) technique has been developed for the analysis of uranium isotopic ratios in ultra-trace uranium samples at the China Institute of Atomic Energy. As result, about 5-nanogram level uranium samples analyzed with AMS is achieved. 相似文献
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The rare isotope ^236U has a half-life of 2.342(3)×107 years, and is produced principally by thermal neutron capture on ^235U. The isotopic atom ratio of ^236U/^238U depends on the integral thermal neutron flux received by the material of interest. ^236U is potentially useful as a "fingerprint" for indicating the presence of neutron-irradiated uranium usually originating from nuclear activity. By extracting negative molecular ion UO^- from the uranium oxide target, simulating the ^236U^16O^- beam transport with ^238U^16O^- and ^208Pb2^16O^- pilot molecular ion beam, transporting the ^236U-containing ion beam with a high resolution injection magnet analyzer and electrostatic analyzer system, and finally identifying and detecting ^236U with a time-of-flight detector (TOF), a method for AMS (Accelerator Mass Spectrometry) measurement of ^236U was established on the HI-13 Accelerator AMS system at China Institute of Atomic Energy. 相似文献
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The rare isotope 236U has a half-life of 2.342(3)×107 years,and is produced principally by thermal neutron capture on 235U.The isotopic atom ratio of 236U/238U depends on the integral thermal neutron flux received by the material of interest.236U is potentially useful as a fingerprint for indicating the presence of neutron-irradiated uranium usually originating from nuclear activity.By extracting negative molecular ion UO- from the uranium oxide target,simulating the 236U16O- beam transport with 238U16O- an... 相似文献
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The present detection limit for 182Hf at CIAE HI-13 AMS systems could not satisfy various applications (e. g. detection of a nearby supernovae signal). Therefore, techniques were developed in this work to improve the AMS measurement of 182Hf mainly on building a new injector and using a method that based on solid-phase reaction for the preparation of HfF4 samples from HfO2. The experimental results show that mass resolution of the injector can reached 630, and the F-/O- and beam current of 180HfF5- for HfF4 samples produced by dry method is about 2—3 times and 1.5 times of that by previously method, respectively. 相似文献
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The schematic layout and principle of a Bragg curve detector were showed in this paper. A Bragg curve detector was systemically modified and its performance was improved. The total energy resolution of the detector is 0.9% for alpha particle at energy of 5.48 MeV from 241Am source, and the Bragg Peak resolution is 1.6%. Measurement of medium-weight nuclides by using the Bragg curve detector were carried at CIAE-AMS system. series of 36Cl and 41Ca standard samples were measured. The results showed that this Bragg curve detector could clearly identify isobars 36Cl-36S and 41Ca-41K. The results also showed that the ΔZ/Z of 1/47, corresponding to Bragg Peak resolution is 2.1% at ion atomic number of about 16. The Bragg curve detector can be successfully used for AMS measurement. 相似文献
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