氩气等离子体聚合大豆油的合成及摩擦学性能研究

利用氩气等离子体降低大豆油(SO)中不饱和C=C双键的含量,得到高黏度的聚合油PAR2.采用凝胶渗透色谱仪分析了PAR2的分子量分布;采用四球摩擦磨损试验机考察了PAR2及同黏度级别的光亮油175BS的摩擦学性能;采用X射线光电子能谱仪分析了钢球摩擦表面元素的化学成分及状态.结果表明:氩气等离子体处理使得PAR2在40℃下的黏度由33.8 cSt增加到956 cSt;与175BS相比,PAR2表现出更为优良的黏温及低温流动性能.与此同时,PAR2中的聚合物主要由SO的二聚物及高分子量的齐聚物组成,其数均分子量M n分别达到2 735和5 434.此外,PAR2的承载能力以及减摩抗磨性能优于175BS;这是由于PAR2在金属表面形成的由羧酸铁组成的边界润滑膜与高价氧化铁膜共同作用,从而有效地减轻金属表面的摩擦与磨损所致.     

Suppression of mode competition in fiber lasers by using a saturable absorber and a fiber ring

An erbium-doped fiber (EDF) laser was configured with a fiber grating, a fiber ring resonator, and a saturable absorber by using un-pumped EDF as mode selection element. The laser showed single mode operation with a narrow linewidth of 5 kHz. The mode selection mechanisms of the un-pumped EDF and the ring resonator are theoretically and experimentally analyzed.     

Three-dimensional clogging structures of granular spheres near hopper orifice

The characteristic clogging structures of granular spheres blocking three-dimensional granular flow through hopper outlet are analyzed based on packing structures reconstructed using magnetic resonance imaging techniques.Spheres in clogging structures are arranged in a way with typical features of load-bearing,such as more contacting bonds close to the horizontal plane and more mutually-stabilized contact configurations than packing structures away from the orifice.The requirement of load-bearing inevitably leads to the cooperativity of clogging structures with a correlation length of several particle diameters.This correlation length being comparable with the orifice diameter suggests that a clogging structure is composed of several mutually-stabilized structural motifs to span the orifice perimeter,instead of a collection of independent individual spheres to cover the whole orifice area.Accordingly,we propose a simple geometric model to explain the unexpected linear dependence of the average size of three-dimensional clogging structures on orifice diameter.     

各向异性焊缝缺陷超声阵列全聚焦成像方法

针对奥氏体不锈钢焊接构件安全评价需要,对各向异性结构中超声波传播特性进行了研究,利用射线追踪法确定了各向异性介质中声波传播路径。在传统全聚焦成像基础上,发展了一种用于各向异性焊缝中缺陷检测的超声阵列全聚焦成像方法。通过数值仿真和实验,研究了介质材质对超声阵列成像的影响,结果表明,发展的全聚焦成像方法可以很好实现各向异性焊缝中缺陷检测,缺陷定位更准确。项目研究工作为奥氏体不锈钢焊缝检测提供了可行的技术方案.     

天花粉蛋白的聚乙二醇定点修饰及其性质的初步研究

用聚乙二醇(PEG)定点修饰天花粉蛋白(TCS), 并比较了修饰前后TCS的生物活性、免疫原性及药代动力学等诸多性质. 选择TCS分子上可能的抗原决定簇位点KR173-174进行定点突变, 并将所构建的突变体TCS_KR173-174CG在大肠杆菌中表达及纯化. 通过该突变体第173位引入的半胱氨酸残基进行PEG定点修饰. 通过比较研究, 分析所构建的PEG修饰型TCS的DNA酶活性、致核糖体失活活性、免疫原性、急性毒性以及药代动力学性质, 研究结果表明, 所构建的突变型TCS(mTCS)的活性与野生型TCS(wTCS)活性几乎相当, 而免疫原性已显著降低. PEG修饰型TCS虽有活性下降, 但其免疫原性、急性毒性以及药代动力学性质得到显著提升. 表明通过基因工程及化学修饰方法改造TCS是可行的, 所构建的突变型及PEG修饰型TCS值得进一步研究.     

四磺酸酞菁钴-DDAB表面活性剂薄膜电极的电化学与电化学催化研究

四磺酸酞菁钴配合物阴离子(CoPcTS_4-)在水溶液中可借助离子交换进入阳离子表面活性剂双十二烷基二甲基溴化铵(DDAB)薄膜,从而形成CoPcTS_4-DDAB薄膜电极.循环伏安法表明,该薄膜电极在pH7.0的空白缓冲溶液中十分稳定,有两对准可逆的还原氧化峰,其中第一对峰的E_pc1=-0.28V,E_pa1=-0.18V(vs.SCE),为中心离子Co(II)Co(I)的还原氧化峰;第二对峰的E_pc2=-1.30V,E_pa2=-1.18V,为酞菁环的还原氧化峰.应用循环伏安法估计了该薄膜体系的电荷传递扩散系数D_ct和表观非均相电极反应速率常数k^o'.CoPcTS_4-DDAB薄膜电极可用于对三氯乙酸(TCA)的电化学催化还原.催化电流与TCA浓度在4×10^-5～1×10^-3molL范围内成线性关系.     

室温下稳定的多波长掺铒光纤激光器的研究

通过在线形谐振腔中引入一段缠绕在压电陶瓷上的单模光纤作为正弦相位调制器,使得激射波长的损耗不固定,抑制由于掺铒光纤的均匀展宽效应引起的模式竞争,从而避免了在室温下不稳定的单波长激射,实现了多波长掺铒光纤激光器的稳定输出。为了获得平坦的多波长输出,在谐振腔里使用了一个损耗峰位于1530nm处的长周期光纤光栅,以获得较为平坦的增益谱。通过两个3dB耦合器制成的反射型梳状滤波器的滤波作用,实验中观察到稳定的多波长激射,相邻波长间隔约为0．45nm。中心9个波长的输出功率平坦度为10dB,边模抑制比大于25dB。     

酞菁钴－表面活性剂薄膜修饰电极及其催化性能

将酞菁钴(CoPc)掺入阳离子表面活性剂双十二烷基二甲基溴化铵(DDAB)的氯仿溶液,并涂布于热解石墨电极表面,待氯仿挥发后即制得CoPc-DDAB薄膜电极。循环伏安实验表明,在KBr溶液中,该薄膜电极有一对良好且稳定的还原氧化峰,E_pc=-0.45V,E_pa=-0.24V(vs.SCE).探讨了该体系的电化学行为,估计了该体系的电化学参数。可将该薄膜电极用于催化卤代乙酸的电化学还原。     

A unidirectional room temperature multi-wavelength fiber ring laser without isolator

A simplified ring cavity for achieving a unidirectional room temperature multi-wavelength erbium-doped fiber ring laser without optical isolator is demonstrated. The fiber ring cavity is built in such a way that the optical fields propagating in two directions suffer different losses caused by one sampled fiber Bragg grating. Furthermore, simultaneous multi-wavelength lasing with 0.8-nm intervals is demonstrated with sinusoidal phase modulation just before the sampled fiber Bragg grating to prevent single-wavelength lasing and unstable wavelength oscillation.     

A unidirectional room temperature multi-wavelength fiber ring laser without isolator

A simplified ring cavity for achieving a unidirectional room temperature multi-wavelength erbium-doped fiber ring laser without optical isolator is demonstrated. The fiber ring cavity is built in such a way that the optical fields propagating in two directions suffer different losses caused by one sampled fiber Bragg grating. Furthermore, simultaneous multi-wavelength lasing with 0.8-nm intervals is demonstrated with sinusoidal phase modulation just before the sampled fiber Bragg grating to prevent single-wavelength lasing and unstable wavelength oscillation.