Toolkit for simultaneously improving production and environmental efficiencies

Central European Journal of Operations Research - Environmental efficiency should not be treated independently of production efficiency. Several studies have demonstrated that lean management can...     

Thermoset modified with polyethersulfone: Characterization and control of the morphology

Thermoset (TS) epoxy resins can be toughened with a thermoplastic (TP) for high-performance applications. The final structure morphology has to be controlled to achieve high mechanical properties and high impact resistance. Four polyethersulfone-modified epoxy resins are considered. They consist of different epoxy monomer structure (TGAP, triglycidyl-p-aminophenol and TGDDM, tetraglycidyl diaminodiphenylmethane) and a fixed amount of thermoplastic, and they are cured with two different amounts of curing agent. A reaction-induced phase separation occurs for all formulations generating morphologies, different in shapes and scales. The aim is to control the final morphology and in particular its dominant length scale. This morphology depends on the phase separation process, from the initiation to its final stage. The initiation relies on the relative miscibility of the components and on the stoichiometry between epoxy and curing agent. The kinetics depends on the viscosity of the systems. The different morphologies are characterized by electron microscopy or neutron scattering. Dynamic mechanical analysis allows confirming the presence of a phase separation even when it is not observable by electron microscopy. Vermicular morphologies with few hundreds nanometer width are obtained for the systems containing the TGAP as epoxy monomer. Systems formulated with TGDDM presents morphologies on much smaller scale of order a few tens of nanometers. We interpret the different sizes of the morphologies as a consequence of a larger viscosity for the TGDDM systems as compared to the TGAP ones rather than by a latter initiation of phase separation.     

Use of green alternative solvents in dispersive liquid-liquid microextraction: A review

Dispersive liquid-liquid microextraction is one of the most widely used microextraction techniques currently in the analytical chemistry field, mainly due to its simplicity and rapidity. The operational mode of this approach has been constantly changing since its introduction, adapting to new trends and applications. Most of these changes are related to the nature of the solvent employed for the microextraction. From the classical halogenated solvents (e.g., chloroform or dichloromethane), different alternatives have been proposed in order to obtain safer and non-pollutants microextraction applications. In this sense, low-density solvents, such as alkanols, switchable hydrophobicity solvents, and ionic liquids were the first and most popular replacements for halogenated solvents, which provided similar or better results than these classical dispersive liquid-liquid microextraction solvents. However, despite the good performances obtained with low-density solvents and ionic liquids, researchers have continued investigating in order to obtain even greener solvents for dispersive liquid-liquid microextraction. For that reason, in this review, the evolution over the last five years of the three types of solvents already mentioned and two of the most promising solvent alternatives (i.e., deep eutectic solvents and supramolecular solvents), have been studied in detail with the purpose of discussing which one provides the greenest alternative.     

From Lignin‐derived Aromatic Compounds to Novel Biobased Polymers

Nowadays, the synthesis of (semi)aromatic polymers from lignin derivatives is of major interest, as aromatic compounds are key intermediates in the manufacture of polymers and lignin is the main source of aromatic biobased substrates. Phenols with a variety of chemical structures can be obtained from lignin deconstruction; among them, vanillin and ferulic acid are the main ones. Depending on the phenol substrates, different chemical modifications and polymerization pathways are developed, leading to (semi)aromatic polymers covering a wide range of thermomechanical properties. This review discusses the synthesis and properties of thermosets (vinyl ester resins, cyanate ester, epoxy, and benzoxazine resins) and thermoplastic polymers (polyesters, polyanhydrides, Schiff base polymers, polyacetals, polyoxalates, polycarbonates, acrylate polymers) prepared from vanillin, ferulic acid, guaiacol, syringaldehyde, or 4‐hydroxybenzoic acid.

     

Cyclic coordinate descent in hydrothermal nonsmooth problems

In this paper we present an algorithm, inspired by the cyclic coordinate descent method, which allows the solution of hydrothermal optimization problems involving pumped-storage plants. The proof of the convergence of the succession generated by the algorithm was based on the use of an appropriate adaptation of Zangwill’s global theorem of convergence. Finally, the algorithm proposed is implemented using the Mathematica Package and is applied to an example to illustrate the results obtained.     

Transient natural convection cooling of a high Prandtl number fluid in a cubical cavity

This work presents a numerical analysis of the effects of thermal boundary conditions, fluid variable viscosity and wall conduction on transient laminar natural convection of a high Prandtl number (Pr=4×10⁴) fluid (Golden Syrup) in a cubical cavity. The simulations consider physical situations realizable at laboratory scale using a cavity with Plexiglas walls of 1 cm of thickness, and inside dimension of L=20 cm. The initial Rayleigh (Ra) number is 10⁶. The cavity is initially full of fluid at rest and at constant temperature (T _i =45°C) higher than the temperature of the walls (T _w =25°C). The time evolution of the flow patterns, the temperature contours, the mean temperature of the fluid and the Nusselt number (Nu) of eight different cases of cooling are presented and analyzed.     

Ostrowski type methods for solving systems of nonlinear equations

Four generalized algorithms builded up from Ostrowski’s method for solving systems of nonlinear equations are written and analyzed. A development of an inverse first-order divided difference operator for functions of several variables is presented, as well as a direct computation of the local order of convergence for these variants of Ostrowski’s method. Furthermore, a sequence that approximates the order of convergence is generated for the examples and it confirms in a numerical way that the order of the methods is well deduced.     

Generalized Hopf Bifurcation for Planar Vector Fields via the Inverse Integrating Factor

In this paper we study the maximum number of limit cycles that can bifurcate from a focus singular point p ₀ of an analytic, autonomous differential system in the real plane under an analytic perturbation. We consider p ₀ being a focus singular point of the following three types: non-degenerate, degenerate without characteristic directions and nilpotent. In a neighborhood of p ₀ the differential system can always be brought, by means of a change to (generalized) polar coordinates (r, θ), to an equation over a cylinder in which the singular point p ₀ corresponds to a limit cycle γ ₀. This equation over the cylinder always has an inverse integrating factor which is smooth and non-flat in r in a neighborhood of γ ₀. We define the notion of vanishing multiplicity of the inverse integrating factor over γ ₀. This vanishing multiplicity determines the maximum number of limit cycles that bifurcate from the singular point p ₀ in the non-degenerate case and a lower bound for the cyclicity otherwise. Moreover, we prove the existence of an inverse integrating factor in a neighborhood of many types of singular points, namely for the three types of focus considered in the previous paragraph and for any isolated singular point with at least one non-zero eigenvalue.     

Untersuchung von Fleisch, Fleischextrakt und Wurstwaren

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