Intrinsic charge transport behaviors in graphene-black phosphorus van der Waals heterojunction devices

Heterostructures from mechanically-assembled stacks of two-dimensional materials allow for versatile electronic device applications. Here, we demonstrate the intrinsic charge transport behaviors in graphene-black phosphorus heterojunction devices under different charge carrier densities and temperature regimes. At high carrier densities or in the ON state,tunneling through the Schottky barrier at the interface between graphene and black phosphorus dominates at low temperatures. With temperature increasing, the Schottky barrier at the interface is vanishing, and the channel current starts to decrease with increasing temperature, behaving like a metal. While at low carrier densities or in the OFF state, thermal emission over the Schottky barrier at the interface dominates the carriers transport process. A barrier height of ~67.3 meV can be extracted from the thermal emission-diffusion theory.     

离子色谱法测定清洗液废酸中的4种阴离子

介绍了清洗液废酸中F-、Cl-、SO42-和NO3-的测定方法,通过一定的前处理,减少清洗液废酸中金属离子及残留酸液的干扰,有效去除了对色谱柱带来的污染。利用优化的实验条件,准确测定了清洗液废酸中F-、Cl-、SO42-和NO3-的含量,检出限分别为0.04、0.09、0.71、0.27mg/L,回收率为94%—109%。     

Vertical vibrations of elastic foundation resting on saturated half-space

This paper is mainly concerned with the dynamic response of an elastic foun- dation of finite height bounded to the surface of a saturated half-space.The foundation is subjected to time-harmonic vertical loadings.First,the transform solutions for the governing equations of the saturated media are obtained.Then,based on the assumption that the contact between the foundation and the half-space is fully relaxed and the half- space is completely pervious or impervious,this dynamic mixed boundary-value problem can lead to dual integral equations,which can be further reduced to the Fredholm integral equations of the second kind and solved by numerical procedures.In the numerical exam- ples,the dynamic compliances,displacements and pore pressure are developed for a wide range of frequencies and material/geometrical properties of the saturated soil-foundation system.In most of the cases,the dynamic behavior of an elastic foundation resting on the saturated media significantly differs from that of a rigid disc on the saturated half-space. The solutions obtained can be used to study a variety of wave propagation problems and dynamic soil-structure interactions.     

气相色谱法测定蔬菜中的13种农药残留量

建立了快速、简便测定蔬菜中的13种农药残留的方法。样品用乙腈∶乙酸=1000∶1(V/V)溶液提取,QuEChERS(Quick,Easy,Cheap,Effective,Rugged,Safe)方法净化,采用气相色谱法测定。13种有机氯农药加标回收率为70.0%—105.1%,该方法具有回收率高、样品处理快速、溶剂使用量少等优点,能够应用于蔬菜中农药残留量的快速检测。     

上覆单相弹性层的饱和地基上刚性圆板的扭转振动分析

采用解析的方法研究了上覆单相弹层的饱和地基上刚性圆板的扭转振动。首先运用积分变换技术分别求解了单相弹性介质和饱和介质情况时的控制方程，然后按混合边值条件建立了上覆单相弹性层的饱和地基上刚性圆板扭转振动的对偶积分方程，并把对偶积分方程化为易于数值求解的第二类Fredholm积分方程，并给出了数值算例。     

层状地基中单桩扭转振动特性分析

采用积分变换和Muki的方法求解了层状地基中单桩的扭转振动问题.在分析过程中,首先对基本控制方程进行Hankel变换,建立了单层地基的初参数解答和刚度矩阵,得到层状地基的递推矩阵;然后利用递推矩阵、边界条件和桩-土变形协调条件建立了层状地基中单桩扭转振动问题的基本积分方程并进行数值求解.文末数值算例给出了退化的层状地基中刚性单桩的扭转变形,其结果与已有经典解答吻合良好.同时,并研究了两层地基中单桩的扭转动力响应,分析了桩-土参数对动力响应的影响,所得结论对工程实践和桩基扭转波检测有一定的指导意义.     

饱和地基上弹性基础的竖向振动特性研究

采用解析的方法研究了饱和地基上受一简谐竖向荷载作用下弹性基础的动力响应．在分析中,首先利用积分变换技术获得了饱和介质基本控制方程的变换解,然后基于基础-半空间完全放松接触、半空间表面完全透水或不透水的假设,建立了该动力混合边值问题的对偶积分方程,并把该对偶积分方程进一步化为易于数值求解的第二类Fredholm积分方程A·D2文末数值算例给出了动力柔度系数、位移和孔隙水压力随振动频域和土-基础体系物理力学参数特性的变化曲线．结果表明:饱和地基上弹性基础的动力响应完全不同于饱和地基上刚性圆板的动力响应．所用方法可用于研究波的传播、土-结构动力相互作用等许多问题．