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Wu Bin Lyu Pin Wang Kaixuan Qiu Xiaoyan Liu Taifeng Zhang Fang Li Hexing Xiao Shengxiong 《Research on Chemical Intermediates》2018,44(10):6327-6337
Research on Chemical Intermediates - Upon oxidation, a graphyne-like porous carbon-rich network (GYLPC), which is a two-dimensional carbon material consisting of sp- and sp2-hybridized carbon atoms... 相似文献
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Luminescent coordination polymers can be potential chemosensors and extensive efforts are being devoted to improve their selectivity and sensitivity. In this work, we report a new kind of fluorene‐based Tb‐CP, Tb4L6·7DMF·5H2O ( Tb 4 L 6 , H2L = 4,4′‐(9,9‐dimethyl‐9H‐fluorene‐2,7‐diyl)dibenzoic acid), showing 2D network and strong blue emission. Meanwhile, Tb 4 L 6 exhibits excellent selectivity and sensitivity for picric acid (PA). The quenching constant (Ksv) of Tb 4 L 6 is equal to 4.5 × 104 L/mol during the concentration range of 0–30 μmol/L, which approaches the best reported CPs‐based on PA sensor up to now. Moreover, we went into depth on the possible mechanisms of luminescence quenching. 相似文献
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二氢吩嗪衍生物由于其独特的氧化还原活性而备受关注. 本文先设计合成了一种含有二氢吩嗪基团的单体5,10-二(4-甲酰基苯基)-5,10-二氢吩嗪(M1), 再采用溶剂热法, 通过亚胺缩合反应制备了一种新型三维共价有机框架(3D COF, 3D-PN-2). 通过粉末X射线衍射(PXRD)、 氮气吸附-脱附、 傅里叶变换红外光谱(FTIR)和固体碳核磁共振波谱(13C CP/MAS NMR)等表征方法, 并结合理论模拟对其结构信息进行了研究, 得出3D-PN-2是具有十一重穿插金刚石(dia)拓扑结构的3D COF. 采用扫描电子显微镜(SEM)和透射电子显微镜(TEM)对其形貌进行了表征. 稳定性研究结果表明, 3D-PN-2具有较好的热稳定性和化学稳定性. 通过固体紫外-可见漫反射光谱研究了3D-PN-2的光吸收性能, 结果表明, 其在紫外和可见光区具有较宽的吸收范围(吸收边为 630 nm), 且具有较窄的能带间隙(2.11 eV). 通过循环伏安法研究了其氧化还原性能, 并计算得出其最高占有轨道能级(EHOMO)为-4.50 eV, 最低空轨道能级(ELUMO)为-2.39 eV. 相似文献
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石墨烯是一种具有单原子厚度的二维碳纳米材料,具有大的比表面积、高的导电性和室温电子迁移率,以及优异的机械力学性能.石墨烯还具有电化学窗口宽,电化学稳定性好,电荷传递电阻小,电催化活性高和电子转移速率快等电化学特性.化学修饰石墨烯,特别是氧化石墨烯(GO)和还原氧化石墨烯(rGO),可以被宏量、廉价地制备出来.它们具有可加工性能,可以被组装、加工或复合成具有可控组成和微结构的宏观电极材料.因此,石墨烯及其化学修饰衍生物是用于电化学生物传感的独特而诱人的电极材料.例如,GO是一种化学修饰石墨烯,也是石墨烯的重要前驱体;其边缘具有大量的羧基可用于共价固定酶,从而能实现酶电极的生物检测.在GO上的不可逆蛋白吸附也可以促进蛋白质的直接电子转移以提高其电化学检测性能.但是,GO大量的含氧官能团破坏了石墨烯本征的共轭结构,降低了其电学性能并限制了其实际应用.GO可以通过化学、电化学、热还原等技术转化成rGO,从而能部分修复其共轭结构,提高其导电性与传感性能.另一方面,石墨烯是一种零带隙材料;原子掺杂可以调控其能带结构,提高其电催化性能.石墨烯材料也常常需要通过与其它功能材料的复合进一步改善其可分散与可加工性能,提高其电催化活性和电化学选择性.本文综述了本征石墨烯(包括GO,rGO和掺杂石墨烯)以及石墨烯与生物分子、高分子、离子液体、金属或金属氧化物纳米粒子等复合材料修饰电极在检测各种生物分子方面的研究进展,并对该研究领域进行了展望. 相似文献
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Adam Ashcraft Kaixuan Liu Arindam Mukhopadhyay Victor Paulino Chuan Liu Brianna Bernard Dalia Husainy Tina Phan Jean‐Hubert Olivier 《Angewandte Chemie (International ed. in English)》2020,59(19):7487-7493
Locking‐in the conformation of supramolecular assemblies provides a new avenue to regulate the (opto)electronic properties of robust nanoscale objects. In the present contribution, we show that the covalent tethering of a perylene bisimide (PBI)‐derived supramolecular polymer with a molecular locker enables the formation of a locked superstructure equipped with emergent structure–function relationships. Experiments that exploit variable‐temperature ground‐state electronic absorption spectroscopy unambiguously demonstrate that the excitonic coupling between nearest neighboring units in the tethered superstructure is preserved at a temperature (371 K) where the pristine, non‐covalent assembly exists exclusively in a molecularly dissolved state. A close examination of the solid‐state morphologies reveals that the locked superstructure engenders the formation of hierarchical 1D materials which are not achievable by unlocked assemblies. To complement these structural attributes, we further demonstrate that covalently tethering a supramolecular polymer built from PBI subunits enables the emergence of electronic properties not evidenced in non‐covalent assemblies. Using cyclic voltammetry experiments, the elucidation of the potentiometric properties of the locked superstructure reveals a 100‐mV stabilization of the conduction band energy when compared to that recorded for the non‐covalent assembly. 相似文献
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本文通过固结磨料球与KDP晶体对磨的单因素试验探究固结磨料球中反应物种类、磨粒浓度、反应物浓度、基体硬度对摩擦系数、磨痕截面积和磨痕处粗糙度的影响,试验结果表明:KHCO3固结磨料球对磨后磨痕对称性好,磨痕处的粗糙度值低;磨痕截面积随磨粒和反应物浓度的增加而增大,随基体硬度的增大而降低;磨痕处粗糙度随磨粒和反应物浓度的增加先降低后上升,随基体硬度的增大先上升后降低;摩擦系数受磨粒和反应物浓度影响不明显,随基体硬度的增大而降低。选择KHCO3作为反应物,Ⅰ基体,磨粒浓度为基体质量的100%,反应物浓度为15%制备固结磨料球与KDP晶体对磨后的磨痕轮廓对称度好且磨痕处粗糙度值低,以该组分制备固结磨料垫干式抛光KDP晶体,可实现晶体表面粗糙度Sa值为18.50 nm,材料去除率为130 nm/min的高效精密加工。 相似文献
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Kaixuan Chen Zhenhua Ning Hengyi Xu Zhi Qi Guo Lu Furen Wang Daole Yin 《中国科学G辑(英文版)》2005,48(1):14-25
The amplitude-dependent ac susceptibility of high-temperature superconductors is shown to obey some empirical scaling relations.
We try to analyze this behavior by extending a dc nonlinear response function of mixed state to the ac cases. The derived
equations for critical current and ac susceptibility ξ(T) agree with the scaling relations of experimental data. 相似文献
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Rolling bearings act as key parts in many items of mechanical equipment and any abnormality will affect the normal operation of the entire apparatus. To diagnose the faults of rolling bearings effectively, a novel fault identification method is proposed by merging variational mode decomposition (VMD), average refined composite multiscale dispersion entropy (ARCMDE) and support vector machine (SVM) optimized by multistrategy enhanced swarm optimization in this paper. Firstly, the vibration signals are decomposed into different series of intrinsic mode functions (IMFs) based on VMD with the center frequency observation method. Subsequently, the proposed ARCMDE, fusing the superiorities of DE and average refined composite multiscale procedure, is employed to enhance the ability of the multiscale fault-feature extraction from the IMFs. Afterwards, grey wolf optimization (GWO), enhanced by multistrategy including levy flight, cosine factor and polynomial mutation strategies (LCPGWO), is proposed to optimize the penalty factor C and kernel parameter g of SVM. Then, the optimized SVM model is trained to identify the fault type of samples based on features extracted by ARCMDE. Finally, the application experiment and contrastive analysis verify the effectiveness of the proposed VMD-ARCMDE-LCPGWO-SVM method. 相似文献
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We described the design and synthesis of a colorimetric and ratiometric fluorescent probe based on a conjugated π-electron system that displayed differential fluorescence responses towards cyanide and sulfide and demonstrated its utility in intracellular ion imaging and logic gate. 相似文献