YBa2Cu3O7—δ中Cu—O伸缩振动的红外吸收峰

测量了ｃ轴高度定向的ＹＢａ２Ｃｕ３Ｏ７－δ高Ｔｃ超导薄膜经３００～７５０℃退火后的红外反射光谱和不同掺Ｚｎ量的ＹＢａ２Ｃｕ３－ｘＺｎｘＯ７－δ块状材料的红外吸收光谱。根据这些光谱中Ｃｕ－Ｏ吸收峰的变化，证实了在ＹＢａ２Ｃｕ３Ｏ７－δ体系的红外光谱中，６３０ｃｍ＾－１、５９０ｃｍ＾－１、和５５０ｃｍ＾－１三个吸收峰分别对应的Ｃｕ－Ｏ伸缩振动膜，以及与氧缺位的关系。并讨论了二维电子气屏蔽对吸收峰的影响     

BPSCCO(2223)中类Ca2PbO4杂相析出的动力学研究

利用等温原位电阻测量和热重分析等方法,深入研究Bi_(1.6)Pb_(0.4)Sr_2Ca_2Cu_3O_(10+5)超导材料在不同温度下氧气和空气中的退火行为,发现电阻率和重量均随退火时间单调增加,最后趋于平衡.同时观察到类Ca_2PbO_4杂相析出,调制结构由Pb型(波矢q=β_1b)逐渐转变为Bi型(q=β_2b+c),适量的杂相析出使T_c(0)有所增高.根据电阻率变化的规律判断,类Ca_2PbO_4杂相析出受2223母相Bi_2-O_2层中Pb~(+2)离子的二维扩散控制,求得Pb~(+2)离子 关键词：     

TixY1-xBa2Cu3O7-δ超导体的红外、远红外光谱

本文报道了Ti_xY_1-xBa₂Cu₃O_7-δ(x=0.2和0.4)在4.2—300K的红外、远红外光谱。在50—360cm^-1波段内发现七个反射峰。它们分别与Ba,Cu,O离子团,Y,O离子团。Ti,O离子团,以及Cu—O键的振动有关,对于x=0.2的样品,存在两个反转结构。对于x=0.4的样品,则仅发现一个反转结构。在红外光谱中观察到六个反对峰和三个吸收峰,它们的强度大多随Ti含量的增加而增强。与Y₁Ba₂Cu₃O_7-δ的光谱结果比校,讨论了声子峰及反转结构的物理起因。 关键词：     

YBa2Cu3O7—δ中Cu—O伸缩振动的红外吸收峰

根据YBa_2Cu_3O_(7-δ)超导定向膜经不同温度退火后的红外反射光谱和不同掺Zn量的YBa_2Cu_(3-z)Zn_xO_(7-δ)的红外吸收光谱在500-700厘米~(-1)特征峰的变化,进一步讨论了YBa_2Cu_3O_(7-δ)中Ba-Ba层间和Y-Ba层间Cu-O键伸缩振动的三个红外吸收峰强度变化的本质。用红外入射光穿透深度随Y系样品电阻率提高而增大和对应二维CuO_2网络中Cu-O反称振动吸收的590厘米~(-1)峰强度变化不受氧缺位影响的事实,说明590厘米~(-1)的吸收峰不是氧缺位诱导的准局域振动模。同时对620厘米~(-1)和550厘米~(-1)吸收峰的解释也给予了必要的补充和验证。     

Ti_xY_(1-x)Ba_2Cu_3O_(7-δ)超导体的红外、远红外光谱

本文报道了Ti_xY_(l-x)Ba_zCu_3O_(7-8)(x=0.2和0.4)在4.2—300K的红外、远红外光谱。在50—360cm~(-1)波段内发现七个反射峰。它们分别与Ba,Cu,O离子团,Y,O离子团。Ti,O离子团,以及Cu--O键的振动有关,对于x=0.2的样品,存在两个反转结构。对于x=0.4的样品,则仅发现一个反转结构。在红外光谱中观察到六个反对峰和三个吸收峰,它们的强度大多随Ti含量的增加而增强。与Y_1Ba_2Cu_3O_(7-8)的光谱结果比校,讨论了声子峰及反转结构的物理起因。     

THE SCREENING EFFECT OF PHONON MODES IN HIGH-Tc OXIDE SUPERCONDUCTOR

This paper presents three different kinds of infrared (IR) spectra of oxide materials. The first one is the IR reflection spectra of Ti₂Ba₂Ca₂Cu₃O₁₀ superconducting film at the incident angles 7°, 12° and 30°. The second one is the IR spectra of nonsuperconducting ceramic materials YBa₂Cu₃O₆ and PrBa₂Cu₃O₇. The third one is the IR spectra of superconductor YBa₂Cu₃O_7-δ and of its film with the c-axis perpendicular to the film plane, as well as the changes in the spectra of these materials after annealing at different temperatures. It is found that in the spectra of high-T_c oxide superconductor, only the phonon modes along c-axis can be observed while the modes in a-b plane are absent. But in the spectra of nonsuperconductors the modes in a-b plane can be observed, particularly in the absorption spectra of the semiconductor YBa₂Cu₃O₆, all eleven allowed IR active modes have been detected. We suggest that the above experimental phenomena may result from the fact that the phonon modes vibrating in the a-b plane of the high-T_c oxide superconducting materials are almost screened by the free carriers which can move only in a-b plane.     

THE SCREENING EFFECT OF PHONON MODES IN HIGH-Tc OXIDE SUPERCONDUCTOR

This paper presents three different kinds of infrared (IR) spectra of oxide materials. The first one is the IR reflection spectra of Ti₂Ba₂Ca₂Cu₃O₁₀ superconducting film at the incident angles 7°, 12° and 30°. The second one is the IR spectra of nonsuperconducting ceramic materials YBa₂Cu₃O₆ and PrBa₂Cu₃O₇. The third one is the IR spectra of superconductor YBa₂Cu₃O_7-δ and of its film with the c-axis perpendicular to the film plane, as well as the changes in the spectra of these materials after annealing at different temperatures. It is found that in the spectra of high-T_c oxide superconductor, only the phonon modes along c-axis can be observed while the modes in a-b plane are absent. But in the spectra of nonsuperconductors the modes in a-b plane can be observed, particularly in the absorption spectra of the semiconductor YBa₂Cu₃O₆, all eleven allowed IR active modes have been detected. We suggest that the above experimental phenomena may result from the fact that the phonon modes vibrating in the a-b plane of the high-T_c oxide superconducting materials are almost screened by the free carriers which can move only in a-b plane.