聚苯胺/钡铁氧体复合材料的制备及电磁性能

"采用原位掺杂聚合法,将聚苯胺对粒径在60~80 nm的M型钡铁氧体颗粒(BaFe12O19)进行包覆,得到了具有导电性和磁性的复合材料．通过X射线衍射、傅利叶变换红外光谱仪、扫描电镜和透射电镜等测试手段对材料的形貌和结构进行了表征．结果表明：PANI链段与BaFe12O19颗粒之间存在着作用力．使用振动磁强计和四探针法测定了复合材料的磁性能与电性能,其中50%复合材料的饱和磁化强度为22.2 emu/g,电导率为0.069 S/cm．"     

An Artificially Garnet Crystal Materials Using In Terahertz Waveguide

A hypothesis is brought forward that the materials with low propagation loss in both optical and microwave band may exhibit good performance in terahertz （THz） band because THz wave band interspaces those two wave bands. For the purpose-of exploring a kind of low-loss material for THz waveguide, Lu2.1Bi0.9Fe5O12（LuBiIG） garnet films are prepared by liquid phase epitaxy （LPE） method on a gadolinium gallium garnet （GGG） substrate from lead-free flux because of the good properties in both optical and microwave bands. In microwave band, the ferromagnetic resonance （FMR） linewidth of the film 2△H = 2.8-5.1Oe; in optical band, the optical absorption coefficient is 600cm^-1 at visible range and about 100-170cm^-1 when the wavelength is longer than 800nm. In THz range, our hypothesis is well confirmed by a THz-TDS measurement which shows that the absorbance of the film for THz wave is 0.05-0.3 cm 1 and the minimum value appears at 2.3 THz. This artificial ferromagnetic material holds a great promise for magnetic field tunable THz devices such as waveguide, modulator or switch.     

聚苯胺钡铁氧体纳米复合材料的制备、表征及性能

采用原位掺杂聚合法, 将聚苯胺(PANI)对粒径在60~80 nm的M型钡铁氧体颗粒(BaFe12O19)进行了包覆, 得到了具有棒状结构的复合材料. 通过X射线衍射(XRD)、傅里叶变换红外光谱(FTIR)、扫描电子显微镜(SEM)和透射电子显微镜(TEM)等测试手段对材料的形貌和结构进行了表征. 结果表明, PANI链段与BaFe12O19颗粒之间存在作用力. 使用振动磁强计和四探针法测定了复合材料的磁性能与电性能后发现, 饱和磁化强度与矫顽力均随聚苯胺含量的增加呈规律性下降趋势, 而电导率呈上升趋势. 复合材料的吸收特性测试结果表明, 该材料反射率小于-20 dB时, 带宽可以达到15.07 GHz. 同时详细地讨论了纳米复合材料的聚合机理及相互作用.     

The structural and magnetic properties of barium ferrite powders prepared by the solben gel method

In this paper, M-type hexagonal barium ferrite powders are synthesized using the sol-gel method. A dried precursor heated in air is analyzed in the temperature range from 50 to 1200 ℃ using thermo-gravimetric analysis and differential scanning calorimetry. The effects of the additives and the cacinating temperature on the magnetic properties are investigated, and the results show that single-phase barium ferrite powders can be formed. After heat-treating at 950 ℃ for 4h with 3 wt% additive, the coercivity and saturation magnetization are found to be 440 Oe and 57.9 emu/g, respectively.     

多层周期薄膜中静磁表面波宽度模色散特性研究

首先建立了有限宽度、具有任意参数的多层薄膜结构中的静磁表面波（MSSW）宽度模普适色散方程,这一理论包含了利用多层薄膜控制静磁表面波色散特性的所有情形,使研究更加符合实际.对多周期的[(YIG/GGG)₁₀/金属层]多层膜结构窄样品中MSSW宽度模色散特性进行了数值计算,MSSW在多层窄样品中的工作主模为一阶宽度模式,多层膜的周期及参数可以有效地控制MSSW的色散特性,样品宽度效应也会对色散特性产生影响. 关键词：     

铁磁/非铁磁/铁磁层状薄膜的巨磁阻抗效应的计算

基于文献[17]和[18]提出的铁磁非铁磁铁磁层状薄膜的电磁模型,详细研究了层状薄膜的巨磁阻抗增强效应,以及磁性层和非磁性层厚度与层状薄膜的巨磁阻抗效应的关系.分析表明,铁磁层和非铁磁层薄膜的电阻率相差越大,越有利于获得显著的巨磁阻抗效应;对于总厚度要求一定的层状薄膜,铁磁层和非铁磁层薄膜存在一最佳厚度 关键词： 巨磁阻抗效应 磁性薄膜 趋肤效应     

The structural and magnetic powders prepared by properties of barium ferrite the sol-gel method

In this paper,M-type hexagonal barium ferrite powders are synthesized using the sol-gel method.A dried precursor heated in air is analyzed in the temperature range from 50 to 1200 C using thermo-gravimetric analysis and differential scanning calorimetry.The effects of the additives and the cacinating temperature on the magnetic properties are investigated,and the results show that single-phase barium ferrite powders can be formed.After heat-treating at 950 C for 4h with 3 wt% additive,the coercivity and saturation magnetization are found to be 440 Oe and 57.9 emu/g,respectively.     

Texture and self-biased property of an oriented M-type barium ferrite thick film by tape casting

In this paper,the oriented M-type barium ferrite(BaM) thick films with different thicknesses are prepared by tape casting.It is found that the crystallographic alignment degree(f),the pore and the squareness ratio(Mr/Ms) are not affected by the thickness of the film.XRD and SEM results show that the thick film has hexagonal morphology with a crystal texture of c-axis grains perpendicular to film plane.The hysteresis curve indicates that the BaM thick film exhibits a self-biased property with a remanent magnetization of 3.30 T,a squareness ratio(Mr/Ms) of 0.81,and a coercivity of 0.40 T.The results show that the BaM thick film has potential for use in self-biasing microwave devices,and also proves that the tape casting technique is capable of fabricating high-quality barium ferrite films,thus providing a unique opportunity to realize the large area production of thick film.     

磁场诱导的单离子各向异性反铁磁链的比热

利用改进的Schwinger玻色子平均场理论,研究了横向外加磁场下自旋为1的单粒子各向异性海森堡反铁磁链的热力学性质.发现在外加磁场下预示这一体系中存在Luttinger液体相—完全极化相相变的比热奇性,并给出了相应的相图.研究还发现,单粒子各向异性对比热的影响较小,这和纵向场的结果完全不同.以上结果对整自旋的反铁磁链具有普适性,对实验研究具有指导性. 关键词： 反铁磁链 热力学性质 Schwinger 玻色子     

Magneto-optical and Microwave Properties of LuBiIG Thin Films Prepared by Liquid Phase Epitaxy Method from Lead-Free Flux

Lu2.1Bi0.9Fe5O12 （LuBiIG） garnet films are prepared by liquid phase epitaxy （LPE） method on gadolinium gallium garnet （GGG） substrates from lead-free flux. Three-inch single crystal garnet films with （444） orientation and good surface are successfully fabricated. The lattice mismatch to the GGG（111） substrate is as small as 0.08%. The ferromagnetic resonance （FMR） linewidth of the film is 2AH = 2.8-5.10e, the Faraday rotation is 1.64 deg/μm at 633nm at room temperature and the optical absorption coefficient of the film is 600cm-1 in visible range and about 100-170 cm-1 when the wavelength is larger than 800 nm. The epitaxy film possesses dominating in-plane magnetization with a saturation magnetization of about 1562G. These superior optical, magnetic-optical （MO） and microwave properties of our garnet films have potential applications in both MO and microwave devices.