排序方式: 共有33条查询结果,搜索用时 15 毫秒
1.
微波常压法合成水杨酸酯 总被引:15,自引:0,他引:15
在浓硫酸催化下,采用微波常压法由水杨酸分别与正丁醇、异丁醇、正戊醇和异戊醇反应合成相应的水杨酸酯。结果表明:当水杨酸:醇:H2SO4=1:5.5:0.3(摩尔比)时,采用560W微波辐射22min,水杨酸酯的产率可达88.7% ̄96.4%,反应速度至少是常规反应的14倍。 相似文献
2.
本文采用离子束溅射Bi/Te和Sb/Te二元复合靶,直接制备n型Bi2Te3热电薄膜和p型Sb2Te3热电薄膜.在退火时间同为1 h的条件下,对所制备的Bi2Te3薄膜和Sb2Te3薄膜进行不同温度的退火处理,并对其热电性能进行表征.结果表明,在退火温度为150 ℃时,制备的n型Bi2Te3关键词:
薄膜温差电池
2Te3薄膜')" href="#">Sb2Te3薄膜
2Te3薄膜')" href="#">Bi2Te3薄膜
离子束溅射 相似文献
3.
4.
Growth and Characterization of CIS Thin Films Prepared by Ion Beam Sputtering Deposition 总被引:1,自引:0,他引:1 下载免费PDF全文
Copper indium diselenide (CuInSe2) thin films were prepared by ion beam sputtering Cu, In and Se targets continuously on BK7 glass substrates and the three-layer film was then annealed in the same vacuum chamber. X-ray diffraction shows that the CuInSe2 thin films have a single chalcopyrite structure with preferential (112) orientation. Scanning electron microscopy reveals that the CIS thin films consist of uniform and densely packed grain clusters. Energy dispersive x-ray spectroscopy demonstrates that the elemental composition of CIS films approaches the stochiometric composition ratios of 1:1:2. Raman measurement shows that the main peak is at about 174cm^-1 and this peak is identified as the A1 vibrational mode from chaicopyrite ordered CulnSe2. Optical transmission and absorption spectroscopy measurement reveal an energy band gap of about 1.05 eV and an absorption coefficient of 10^5 cm^-1. The film resistivity is about 0.01 Ωcm. 相似文献
5.
Composition-Dependent Characterization of Sb2Te3 Thin Films Prepared by Ion Beam Sputtering Deposition 总被引:1,自引:0,他引:1 下载免费PDF全文
The optimization of ion beam sputtering deposition process for Sb2 Te3 thin films deposited on BK7 glass substrates is reported. The influence of composition ratio on the thermoelectric properties is investigated. X-ray diffraction shows that the major diffraction peaks of the films match with those of Sb2 Te3. Hall effect and Seebeck coefficient measurement reveal that all the samples are of p-type. The Sb2 Te3 thin films exhibit the Seebeck coefficient of 190μVk^-1 and the electrical conductivity of 1.1 × 10^3 Scm^-1 when the atomic ratio of Sb to Te is 0.65. Carrier concentration and motility of the films increase with the increasing atomic ratio of Sb to Te. The Sb2 Tea film with a maximum power factor of 2.26×10^-3 Win^-1K^-2 is achieved when annealed at 400℃. Raman measurement shows that the main peaks are at about 120 cm^-1, 252 cm^-1 and 450 cm^-1, in agreement with those of V-VI compound semiconductors. 相似文献
6.
Magnetic rotation in 82Rb has been investigated for the first time by g-factor measurement of intra-band states of the magnetic-rotational band built on the 11- state. The g-factors were measured by a TMF-IMPAD method and calculated by a semi-classical model of independent particle angular momentum coupling assumption. The g-factors and deduced shears angles decrease with the increasing of spin along the band, illustrating a step-by-step alignment of the valence protons and neutrons. The rapid alignment of the valence neutrons leads to a decrease of g-factors. The present results vividly reveal the shears mechanism of magnetic rotation. 相似文献
7.
通过芳胺的重氮化-偶合反应合成了8个偶氮基杯芳烃化合物, 其结构经IR, 1H NMR, ESI-MS和元素分析表征. 通过UV-Vis, 1H NMR和IR考察了溶液pH值对所合成化合物5,11,17,23-四[(2-苯并噻唑基)偶氮基]-25,26,27,28-四羟基杯芳烃(3)和5,17-二[(1-萘基)偶氮基]-25,26,27,28-四羟基杯芳烃(4)的偶氮-醌腙互变异构的影响. 结果表明, 随着溶液pH值增加, 醌腙体在偶氮-醌腙互变异构平衡中的比例增加, 当pH≥10时, 几乎全部转变为醌腙体. 特别当溶液pH=-1时, 化合物4可以形成一种大的共轭体系, 使其λmax由477 nm红移至545 nm. 相似文献
8.
总结和归属了N,N′-二乙酰基丁二酰二肼,N,N′-二乙酰基癸二酰 二肼以及4种N,N′-二酰基戊二酰二肼和4种N,N′-二酰基己二酰二肼共10个化合物在电子轰击电离质谱(EIMS)中的主要裂解方式和特征,指明了主要碎片离子的来源和结构;这10种化合物质谱图中的主要碎片峰均来自于羧基的α-裂解和重排α-裂解,由其裂解产生的基峰离子H2NNHCO(CH2)nC≡0^ 以及RCONHNHCO(CH)nC≡0,RCONHN^ H3等离子是该类化合物共同的特征离子。 相似文献
9.
10.
采用离子束溅射在K9玻璃基底上沉积了不同厚度的Cu膜,利用Lambda-900分光光度计,测量了波长为310 nm到1300 nm范围内Cu膜的反射率和透射率.选定波长为310、350、400、430、550、632、800、1200 nm时对薄膜的反射率、透射率和吸收率随膜厚变化的关系进行研究.同时,对Cu膜的光学常量也进行了讨论.结果显示,Cu膜的光学特性都有明显的尺寸效应.将波长为550 nm时的反射率和透射率随Cu膜厚度变化关系的交点对应厚度作为特征厚度, 该厚度可认为是金属Cu膜生长从不连续膜进入连续膜的最小连续膜厚.根据这一特征判据,离子束溅射沉积Cu膜样品的最小连续膜厚为33 nm.利用原子力显微镜观测了膜厚在特征厚度附近时Cu膜的表面形貌. 相似文献