阳离子交换皂石黏土在基质辅助激光解吸电离飞行时间质谱分析中的应用

将一种人工合成的无机聚合物——蒙脱石皂石黏土（smectite，Sm）应用于基质辅助激光解吸电离飞行时间质谱分析（matrix-assisted laser desorption/ionization time of flight mass spectrometry, MALDI-TOF-MS），以检测糖类化合物。 将传统的有机基质2，4，6-三羟基苯乙酮（trihydroxyacetophenone, THAP）与阳离子交换后的皂石黏土混合制备成新型复合基质，应用于糖类化合物的检测。通过比较不同的制样方法，测定不同分子直径的糖类化合物，发现由于受复合基质晶面间距的限制，只有小分子糖类化合物能进入晶面间隙充分接触有机基质并被离子化，从而实现对小分子糖类化合物的选择性检测。     

The optimization of hydrothermal process of MoS_2 nanosheets and their good microwave absorption performances

In this study,flower-like MoS_2 constructed by nanosheets was synthesized by a simple hydrothermal method.The hydrothermal process was optimized and the effects of hydrothermal condition,including reaction temperature,reaction time and the ratio of Mo source to S source(Mo:S) in precursor,on microwave absorption performances and dielectric properties were investigated.Our results showed that when the reaction temperature was 180℃,the reaction time was 18 h,and the Mo:S was 1:3.5,the synthesized MoS_2 had the best performance:Its minimum reflection loss could reach-55.78 dB,and the corresponding matching thickness was 2.30 mm with a wide effective bandwidth of 5.17 GHz.Further researches on the microwave absorption mechanism revealed that in addition to the destructive interference of electromagnetic waves,various polarization phenomena such as defect dipole polarization were the main reasons for microwave loss.We believe that MoS_2 is a candidate for a practical microwave absorbent.     

西北太平洋表层沉积物地球化学特征及其物源指示意义

为深入了解西北太平洋表层沉积物地球化学特征及物质来源，对大洋40航次在西北太平洋马尔库斯-威克海山区采集的表层沉积物进行了全岩地球化学和黏土矿物测试分析。结果表明，研究区表层沉积物稀土元素（REE)平均质量分数为302.87×10^-6，北美页岩标准化稀土配分模式与黄土相似，并具Ce轻微负异常和Eu无异常特征。稀土配分模式、判别函数（discriminant functions,DF）、M/I（蒙脱石/伊利石）及涂片鉴定等结果指示沉积物物源具有多源性，主要为陆源风尘物质，并受海洋自生物质的强烈影响，海山玄武岩及其蚀变产物和硅质生物也有一定的贡献。研究区沉积物稀土特征既不同于边缘海沉积物，也有别于远洋沉积物，而与弧后盆地沉积物类似。结合1/δCe-LREE/HREE和LREE/HREE-Y/Ho判别图解结果，研究区沉积物物源结构属性应介于边缘海沉积物与远洋沉积物之间，为洋陆过渡区沉积。     

基于图像的二维剪纸自动生成方法

中国剪纸的设计极具挑战性, 要求画面简洁、直观, 还需要表达特定的文化内涵, 且整张剪纸须整体连通。提出了一种基于图像的二维剪纸自动生成方法, 能够将任意数码照片自动转化为剪纸图形。首先，利用图像分割方法建立区域连接图; 接着, 基于该连接图对颜色、边界对比度和区域连通性进行数学建模, 并获得优化目标函数; 最后, 通过模拟退火算法求解目标方程, 自动生成保持图像内容的剪纸图形。还开发了连通性后处理和区域指定等用户交互工具, 允许用户在自动生成的剪纸图形中方便地加入个人设计。实验表明, 所生成的剪纸图形画面简洁、整体连通。 本方法在降低剪纸设计难度的同时还可满足个性化的设计需求, 有助于传播和传承我国的民间剪纸艺术。     

Selective Oxidation of Methane into Methanol Under Mild Conditions

Selective oxidation of methane to methanol under mild conditions has been considered as a dream reaction but suffers from poor efficiency due to the strong C-H bond of methane and easy overoxidation of the methanol product. For overcoming these problems, a series of strategies has been developed for improving methanol productivity with oxidants of hydrogen peroxide and even a mixture of oxygen and hydrogen at mild temperatures. Significant achievements in these strategies using effective catalysts, such as supported metal nanoparticles, colloidal metal nanoparticles, and metal@zeolites are briefly concluded. Moreover, the current challenges, future perspectives for preparing active, selective, and stable catalysts, have been discussed. The zeolite fixed metal nanoparticle structure has been found to boost the reaction by benefiting the formation and enrichment of peroxide intermediates, which might guide the development of more efficient catalysts.     

大跨度脊谷式膜屋盖风载分布的实验研究

基于台州某风雨操场脊谷式张拉膜屋盖缩尺模型风洞试验的数据结果,选取典型测点,研究了屋面迎风前缘、过渡区及中轴区的平均风压和脉动风压系数的分布特性。同时,鉴于屋盖的不规则曲面造型,表面风压梯度变化较大,采用单一体型系数反映屋面风载已不能满足要求。文中在结合屋盖自身复杂体型和风压分布特征基础上,按各榀各边片将屋面划分为不同区域,对5个不利风向角下的区域体型系数进行统计分析,并给出各区域体型系数建议取值。最后,针对这类体型屋盖特点和风压分布特性,得出一些结论和建议,为进一步研究该类屋盖的风荷载特性和结构抗风设计提供了依据。     

Viscoelastic response and interlaminar delamination resistance of epoxy/glass fiber/functionalized graphene oxide multi-scale composites

Graphene oxide (GO) was functionalized using three different diamines, namely ethylenediamine (EDA), 4,4′-diaminodiphenyl sulfone (DDS) and p-phenylenediamine (PPD) to reinforce an epoxy/glass fiber (EP/GF) composite laminate, with the aim of improving the overall composite mechanical performance. Different mechanical characterization techniques were used to determine the mechanical performance, including: tensile stress strain, double cantilever beam (DCB) mode-I fracture toughness and dynamic mechanical thermal analysis (DMTA). Scanning electron microscopy (SEM) was used to support the results and conclusions. The results demonstrated remarkable enhancements in the mechanical performance of EP/GF composite laminates by incorporation of functionalized graphene oxide (FGO) nanofiller, whilst the mechanical performance of the GO reinforced composite only improved marginally. Finally, the mechanical performance of the EP/GF/FGO multi-scale composites was found to be dependent on the type of FGO functional groups; of which EDA exhibited the highest performance. These investigations confirmed that the EDA-FGO-reinforced EP/GF composites possess excellent potential to be used as multifunctional engineering materials in industrial applications.     

A carbon risk prediction model for Chinese heavy-polluting industrial enterprises based on support vector machine

Chinese heavy-polluting industrial enterprises, especially petrochemical or chemical industry, labeled low carbon efficiency and high emission load, are facing the tremendous pressure of emission reduction under the background of global shortage of energy supply and constrain of carbon emission. However, due to the limited amount of theoretic and practical research in this field, problems like lacking prediction indicators or models, and the quantified standard of carbon risk remain unsolved. In this paper, the connotation of carbon risk and an assessment index system for Chinese heavy-polluting industrial enterprises (eg. coal enterprise, petrochemical enterprises, chemical enterprises et al.) based on support vector machine are presented. By using several heavy-polluting industrial enterprises’ related data, SVM model is trained to predict the carbon risk level of a specific enterprise, which allows the enterprise to identify and manage its carbon risks. The result shows that this method can predict enterprise’s carbon risk level in an efficient, accurate way with high practical application and generalization value.     

Study on the thermal decomposition of famciclovir

Journal of Thermal Analysis and Calorimetry - The thermal decomposition of famciclovir (FCV) was measured with thermogravimetry, differential scanning calorimetry, and thermogravimetric analysis...     

关于有限群表示范畴上几乎可裂序列的注记(英文)

本文给出几乎可裂序列的Green对应.主要结果为:设X是不可分解非投射kG-模,Y是相应的不可分解非投射kL-模,那么(i)0→Ω~2(X)→(XU)_0→X→0是可裂正和列当且仅当0→Ω~2(Y)→(YU)_0→Y→0是可裂正和列;(ⅱ)0→Ω~2(X)→(X(U)_0→X→0是几乎可裂正和列当且仅当0→Ω~2(Y)→(YU)_0→Y→0是几乎可裂正和列.