首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   578篇
  免费   124篇
  国内免费   146篇
化学   368篇
晶体学   7篇
力学   23篇
综合类   127篇
数学   149篇
物理学   174篇
  2023年   6篇
  2022年   11篇
  2021年   16篇
  2020年   11篇
  2019年   9篇
  2018年   5篇
  2017年   9篇
  2016年   17篇
  2015年   16篇
  2014年   27篇
  2013年   49篇
  2012年   64篇
  2011年   56篇
  2010年   62篇
  2009年   64篇
  2008年   53篇
  2007年   71篇
  2006年   76篇
  2005年   45篇
  2004年   37篇
  2003年   21篇
  2002年   18篇
  2001年   18篇
  2000年   19篇
  1999年   21篇
  1998年   27篇
  1997年   9篇
  1996年   2篇
  1995年   1篇
  1994年   1篇
  1993年   4篇
  1992年   2篇
  1989年   1篇
排序方式: 共有848条查询结果,搜索用时 46 毫秒
91.
图和线图的谱性质   总被引:5,自引:0,他引:5  
Let G be a simple connected graph with n vertices and m edges,Lo be the line graph of G and λ1(LG)≥λ2 (LG)≥...≥λm(LG) be the eigenvalues of the graph LG,.. In this paper, the range of eigenvalues of a line graph is considered. Some sharp upper bounds and sharp lower bounds of the eigenvalues of Lc. are obtained. In oarticular,it is oroved that-2cos(π/n)≤λn-1(LG)≤n-4 and λn(LG)=-2 if and only if G is bipartite.  相似文献   
92.
浙江植物区系增补   总被引:2,自引:0,他引:2  
本文报道了作者在整理鉴定近年调查采集的植物标本过程中发现的一些浙江植物区系新记录植物,计有2属(水禾属和带叶兰属)、5种、2变种,丰富了浙江植物区系的内容.同时对大叶葱芥的花部形态特征作了补充描述.引证的标本均保存于杭州大学植物标本室(国际代号HZU).1刺叶株(壳斗科Fagaceae)QuercussplnosaDavidexFranch,PI.David.l:274,1884;中国高等植物图鉴1:453,图905,1972.产仙居,上井,海拔875米,郑朝宗无号.分布福建、湖北、四川、云南、陕西、甘肃.浙江分布新记录.常绿灌木,叶厚革质,椭圆形或近圆形,边…  相似文献   
93.
采用紫外线、同平板梯度浓度亚硝基肌,纯铜蒸气激光诱变去甲基金霉素生产菌金霉素链霉菌的原生质体,结果表明原生质体对各种诱变剂的敏感性较高.正变幅度较大.原生质体经紫外线、同平板梯度浓度亚硝墓肌复合诱变后,筛选到一菌株,重新制备原生体,经激光诱变,选育出高产菌株S. A. HU02,去甲基金霉素效价从2831u/ml提高到4337u/ml,提高了53. 2,经多次传代产量性状非常稳定.  相似文献   
94.
95.
Cao J  Yang X  Hua X  Deng Y  Lai G 《Organic letters》2011,13(3):478-481
An interesting sequential Sonogashira coupling/alkynyl imine-allenyl imine isomerization/aza-Diels-Alder/elimination-aromatization reaction, providing a facile synthesis of substituted 2-azaanthracenes from 1,6-diynes and imidoyl chlorides, is reported. The easy procedure accessing the products efficiently from readily available starting materials may imply a potential synthetic application.  相似文献   
96.
The dissociation chemistry of the ortho-, meta- or para-isomers of protonated S-methyl methoxyl- (or chloro-) benzenylmethylenehydrazine dithiocarboxylate, RPhCHN–NHC(S)–SCH3 (R = MeO– or Cl–), has been investigated by collision induced dissociation experiments and DFT theoretical calculations. The three methoxyl-substituted isomers were easily differentiated according to the different abundance of the characteristic ion at m/z 136, resulting from the varying reactivity of the (NSC)SCH3 elimination. This fragmentation is triggered by the positive charge upon protonation on the imine N2. Relative to the meta isomer, the positive charge on N2 in the para isomer is dispersed due to the electron donating resonance of the methoxyl group, which leads to higher energy barrier in the dissociation reaction and the less abundant product ion (m/z 136) in the MS/MS. (NSC)SCH3 elimination of the ortho- isomer is further suppressed due to both the resonance effect and the “ortho effect” (an intramolecular hydrogen bond), with much higher energy barrier and extremely lower abundance of the fragment ion (m/z 136, 0.4%). The chloro substituted isomers, however, are short of the above positional effects due to the weak electronic effect of the substituent, and share the similar tandem mass spectrum.  相似文献   
97.
A family of eighth-order iterative methods for the solution of nonlinear equations is presented. The new family of eighth-order methods is based on King’s fourth-order methods and the family of sixth-order iteration methods developed by Chun et al. Per iteration the new methods require three evaluations of the function and one evaluation of its first derivative. Therefore this family of methods has the efficiency index which equals 1.682. Kung and Traub conjectured that a multipoint iteration without memory based on nn evaluations could achieve optimal convergence order 2n−12n1. Thus we provide a new example which agrees with the conjecture of Kung–Traub for n=4n=4. Numerical comparisons are made to show the performance of the presented methods.  相似文献   
98.
99.
The authors show that the Cauchy integral operator is bounded from Hωp(R1) to hωp(R1) (the weighted local Hardy space). To prove the results, a kind of generalized atoms is introduced and a variant of weighted "Tb theorem" is considered.  相似文献   
100.
Min Yao 《Optik》2009,120(16):824-828
The scintillation properties of astigmatic annular beams in a weak turbulent atmosphere are investigated. Expression for the on-axis scintillation index of an astigmatic annular beam is derived. It is found that the scintillation index of an astigmatic annular beam can be smaller than that of a Gaussian beam, an elliptical Gaussian beam and a stigmatic annular beam in a weak turbulent atmosphere under certain conditions. The scintillation properties of astigmatic annular beams are closely controlled by its beam parameters.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号