能量色散X射线荧光法快速测定高冰镍中铁的含量

应用能量色散ｘ射线荧光法快速测定高冰镍中铁的含量。以一次射线的康普顿散射射线作内标，同时采用“负补偿法”校正干扰元素Ｃｕ和Ｎｉ对铁特征荧光的增强作用，取得较好效果，试验表明：本法具有操作简单、速度快、精度耘高等优点。对由￣２３８Ｐｕ放射性同位素源、闪烁探测器和双道谱仪组成的测量系统，测定铁含量的精度（ＲＳＤ）达到１．８％，平均绝对误差为０．１６％，单样分析时间为９６ｓ。     

不同形貌ZrWMoO8粉体的制备、表征及其负热膨胀特性

采用水合前驱物分解的方法, 以钨酸铵、钼酸铵及硝酸氧锆为原料制备了不同形貌的ZrWMoO8粉体. 对其前驱体进行了热重-差热分析(TG-DSC), 并以X射线粉末衍射(XRD)、扫描电子显微镜(SEM)及X射线荧光光谱仪(XRF)等手段考察了不同胶凝剂(HCl, HClO4, HNO3, H2SO4及H3PO4)对产物结构和形貌的影响. 结果表明, 胶凝剂的选择对ZrWMoO8粉体的形貌有较大影响. 在100—700 ℃范围内, 以HCl为胶凝剂制备出来的立方相ZrWMoO8粉体的热膨胀系数为-3.84×10-6 K-1.     

动力学-双波长法测定岩石矿物中痕量铼及负峰可测性研究

铼(Ⅳ)催化α-呋喃甲酰二肟(α-FDO)酸解反应,在一定条件下其光谱的正、负峰吸光度之和与时间星线性并与铼浓度相关。据此,建立了动力学一双波长测定痕量铼的方法。方法检出限为0.05ng/ml,铼浓度在<10ng/ml范围线性颇佳,表观摩尔吸光系数ε为4.5×10~7L·mol(-1)·cm~(-1)。方法用于辉钼矿和岩石中痕量铼的测定,结果与中子活化等方法相符。本文还就本体系为例对分光光度法中负峰的出现和可测规律进行了探讨。     

共沉淀法制备负热膨胀性ZrW2O8粉体及其粒径控制初探

Negative thermal expansion (NTE) material ZrW₂O₈ powders were synthesized using co-precipitation route. The precursor of ZrW₂O₈ was studied by Thermogravimetric and differential scanning calorimetry (TG-DSC). The structure and morphology of the resulting powders were characterized by Powder X-ray diffraction (XRD) and Scanning electron microscopy (SEM), respectively. The results showed that the samples were single phase of α-ZrW₂O₈ with regular shape. High temperature X-ray diffraction measurement indicated that the thermal expansion coefficient of ZrW₂O₈ was -10.35 × 10^-6 K^-1 in the temperature range from room temperature to 150 ℃, -3.08 ×10^-6 K^-1 from 200 ℃ to 600 ℃ and the average value was -5.38 × 10^-6 K^-1. At the same time, polyethylene glycol (PEG) was used as dispersant to primary control the size of ZrW₂O₈.     

Proposed Chiral Doublet Bands in ^98Tc

High spin states in odd-odd ^98 Tc nuclei are studied by in-beam γ-ray spectroscopy with the ^96 Zr（^6Li, 412） fusionevaporation reaction at a beam energy of 35MeV. The previous level scheme is updated. A band based on 1090.7keV is expanded, and another band based on 1920.6 keV is newly identified. The observed two negative parity bands in ^98 Tc are proposed to be a pair of chiral doublet bands with the configuration πg9/2 vh11/2. The evidence supporting the assignment of the chiral doublet bands is discussed. Signature splitting and signature inversion are observed in the πg9/2 vh11/2 band in ^98Tc.     

Complete moment and integral convergence for sums of negatively associated random variables

For a sequence of identically distributed negatively associated random variables {Xn; n ≥ 1} with partial sums Sn = ∑i=1^n Xi, n ≥ 1, refinements are presented of the classical Baum-Katz and Lai complete convergence theorems. More specifically, necessary and sufficient moment conditions are provided for complete moment convergence of the form ∑n≥n0 n^r-2-1/pq anE（max1≤k≤n｜Sk｜^1/q-∈bn^1/qp）^＋〈∞to hold where r 〉 1, q 〉 0 and either n0 = 1,0 〈 p 〈 2, an = 1,bn = n or n0 = 3,p = 2, an = 1 （log n） ^1/2q, bn=n log n. These results extend results of Chow and of Li and Spataru from the indepen- dent and identically distributed case to the identically distributed negatively associated setting. The complete moment convergence is also shown to be equivalent to a form of complete integral convergence.     

Complexity of asymptotic behavior of solutions for the porous medium equation with absorption

In this paper we analyze the large time behavior of nonnegative solutions of the Cauchy problem of the porous medium equation with absorption u t-u m + γup = 0, where γ≥ 0, m 1 and p m + 2/N . We will show that if γ = 0 and 0 μ 2N/(N(m-1)+2), or γ 0 and 1/(p-1)μ2N/(N(m-1)+2), then for any nonnegative function φ in a nonnegative countable subset F of the Schwartz space S (R N ), there exists an initial-value u0 ∈C(RN) with lim x →∞ u 0 (x) = 0 such that φ is an ω-limit point of the rescaled solutions t μ/2 u(t β·, t), where β =[2-μ(m-1)]/4 .     

气相色谱-负化学源质谱法测定蜂蜜和奶粉中氯霉素残留量

研究了蜂蜜和奶粉中氯霉素残留量的气相色谱——质谱分析方法。将样品溶于水，其中的氯霉素残留物用乙酸乙酯提取，提取物用C18固相萃取柱净化，净化液再用乙酸乙酯反提取，经N，O-双(三甲基硅烷基)三氟乙酰胺(BSTFA) 1％三甲基氯硅烷(TMCS)衍生后，用配有负化学源质谱检测器的气相色谱仪测定。当添加水平为0．1～10μg/kg时，回收率为80．4％～95．3％，相对标准偏差为9．3％～18．1％。     

催化裂化过程中负氢离子转移反应和氢转移反应的不同特征

 基于重质油在酸性Y分子筛催化剂上的反应,区分了负氢离子转移反应和氢转移反应,认为负氢离子转移和氢转移是重质油催化反应过程中的两个不同过程. 确定了大庆减压蜡油在酸性Y分子筛催化剂上反应时,负氢离子转移反应主要发生在反应前期(转化率为5%～10%)至反应中后期(转化率为60%～70%)的转化深度区间,而氢转移反应主要发生在反应后期(转化率＞60%～70%). 负氢离子转移反应基本不产生焦炭,焦炭主要通过氢转移反应产生. Y分子筛上发生的主要是汽油烯烃和环烷烃之间的氢转移反应.     

NH3BH3的双接触蓝移双氢键的理论研究

运用量子化学从头算方法研究了NH3BH3与含大的分子内超共轭的质子给体CHF3, H2CO, HCOOH, HCOCl和HNO形成的双接触弯曲双氢键B—H2…H—X(X＝C, N)的分子结构、电子密度拓扑性质与频率位移特征. 计算结果表明, 在所有体系中, 由于双氢键的形成, B—H键拉长且伸缩振动频率红移, 而X—H键长减小且伸缩频率蓝移. 弯曲的双接触构型导致分子间超共轭减小、X—H键的大的正重极化与正重杂化以及分子内超共轭减小三个因素导致了X—H键蓝移; B—H键红移的主要原因是B—H键的负的重极化与负的重杂化.