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Adsorption-controlled transition of the electrical properties realized in Hematite(alpha-Fe2O3) nanorods ethanol sensing 下载免费PDF全文
Alpha-Fe2O3 nanorods are synthesized through a hydrothermal method with no surfactant introduced and ethanol sensors are fabricated from these nanorods.The device can respond to ethanol vapour in a concentration range from 1 to 1500 parts per million and shows both p-type and n-type responding characteristics during the investigation of the ethanol sensing.The sensor displays a p-type characteristic when the ethanol concentration is low and converted into an n-type characteristic as the concentration exceeds a certain value.Such a phenomenon is attributed to the chemisorbed oxygen,which leads to different modifications of the energy band at the surface,namely,depletion layer or inversion layer. 相似文献
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采用M-矩阵及Liapunov函数等方法,研究了随机Gilpin-Ayala互惠模型解的稳定性,并给出若干随机Gilpin-Ayala互惠模型的正平衡解稳定的充分条件.同时修正了文献-《Stability of Stochastic Gilpin-Ayala competition Models》的若干错误. 相似文献
95.
Quantitative structure-activity relationship (QSAR) model was used to predict and explain binding constant (log K) determined by fluorescence quenching. This method allowed us to predict binding constants of a variety of compounds with human serum albumin (HSA) based on their structures alone. Stepwise multiple linear regression (MLR) and nonlinear radial basis function neural network (RBFNN) were performed to build the models. The statistical parameters provided by the MLR model (R2=0.8521, RMS=0.2678) indicated satisfactory stability and predictive ability while the RBFNN predictive ability is somewhat superior (R2=0.9245, RMS=0.1736). The proposed models were used to predict the binding constants of two bioactive components in traditional Chinese medicines (isoimperatorin and chrysophanol) whose experimental results were obtained in our laboratory and the predicted results were in good agreement with the experimental results. This QSAR approach can contribute to a better understanding of structural factors of the compounds responsible for drug-protein interactions, and can be useful in predicting the binding constants of other compounds. 相似文献
96.
对取自退役飞机机翼蒙皮的光滑试件进行了等幅疲劳试验,通过疲劳断口分析得到了服役环境下飞机主体材料LY12CZ 铝合金蚀坑的拓扑特征.基于飞机结构的实际腐蚀尺寸,将蚀坑的宽度和深度作为等效裂纹的长轴和短轴,并应用 Stress Check 软件对蚀坑等效为裂纹的可行性进行了有限元分析.结果表明:实际蚀坑与等效裂纹对结构应力分布的影响十分相似;应力强度因子在蚀坑等效前后数值大小和变化趋势不大.在分析蚀坑对典型试件疲劳寿命影响时将蚀坑等效成半椭圆形裂纹,选取 Walker 公式作为扩展速率模型,并与试验值进行了对比.结果表明:预测值与试验值比较吻合,最大误差为9.23%,满足工程需求. 相似文献
97.
以电位滴定终点确定新方法探讨研究为例,从5个方面介绍将创新能力培养融入基础课教学的探索。通过该研究提高了学生基础课学习热情与学习质量。首先改进了二次差值微商终点计算方法,通过Excel 计算Δ2E/ΔV-V 二次差值微商法数据表中的最高点与最低点直线线性方程 y=ax+b,令 y=0, x=-b/a即为终点。另外,研究得到了模拟滴定曲线微分法确定电位滴定终点的新方法。用Excel 对滴定曲线进行三次方程模拟即:y=ax3+bx2+cx+d,二次微分后得到: d2y/dx2=6ax+2b, 当d2y/dx2=0,对应的x=-b/3a处即为滴定终点。2 相似文献
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《中国化学快报》2020,31(12):3047-3054
As a class of metal-free two-dimensional (2D) semiconductor materials, polymeric carbon nitrides have attracted wide attention recently due to its facile regulation of the molecular and electronic structures, availability in abundance and high stability. According to the different ratios of C and N atoms in the framework, a series of CxNy materials have been successfully synthesized by virtue of various precursors, which further triggers extensive investigations of broad applications ranging from sustainable photocatalytic reactions and highly sensitive optoelectronic biosensing. In view of topological structures on their electronic structures and material properties, the as-reported CxNy could be generally classified into two main categories with three- or six-bond-extending frameworks. Owing to the effective n→π* transition in most CxNy materials, the relative energy level of the lone-pair electrons on N atoms is high, which thus endows the materials with the capability of visible light absorption. Meanwhile, the different repeating units, bridging groups and defect sites of these two kinds of CxNy allow them to effectively drive a diverse of promising applications that require specific electronic, interfacial and geometric properties. This review paper aims to summarize the recent progress in topological structure design and the relevant electronic band structures and striking properties of CxNy materials. In the final part, we also discuss the existing challenges of CxNy and outlook the prospect possibilities. 相似文献
100.
建立高效液相色谱-串联质谱法同时测定土壤中戊唑醇、腈菌唑、腈苯唑、氟硅唑、三唑酮、丙环唑、烯唑醇、苯醚甲环唑8种杀菌剂残留量的方法。采用QuEChERS样品前处理方法对土壤样品进行提取、净化和富集,用电喷雾离子源、正负离子扫描,以多反应监测(MRM)模式进行定性和定量分析。在优化的实验条件下,8种杀菌剂的质量浓度在0.01~0.50 mg/L范围内与色谱峰面积均成良好的线性关系,相关系数均大于0.995,方法检出限为0.005~0.010 mg/kg。样品平均加标回收率为85.6%~102.2%,测定结果的相对标准偏差为4.6%~13.2%(n=5)。该方法操作简便,灵敏度和准确度高,满足土壤中戊唑醇等8种杀菌剂残留量的测定要求。 相似文献