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91.
《Analytical letters》2012,45(11):2397-2407
Abstract A spectrophotometric procedure for the determination of ampicillin (Amp.) in pure solutions and in its pharmaceutical preparations has been developed. This new method offers advantages of simplicity, rapidity and stability in comparison with the official BP (1980) method. The proposed method is based on the formation of a colour condensation product through the reaction of ampicillin and nitrobenzene derivatives in an alkaline aqueous-acetone medium 40% (v/v). Beer's law is obeyed in the range 0.5–28 μg ml?1. The colours were produced within 20 min. after heating at 60±5°C and stable for at least 6 h. The method is relatively accurate (recovery 100±2%) and precise (RSD 1.9%) and can be used successfully for the preparation of capsules, syrup and ampoules. 相似文献
92.
《Analytical letters》2012,45(2):228-242
Abstract A new luminescence method based on the minocycline (MNC)-europium (Eu3+)-sodium dodecylbenzene sulfonate (SDBS) system was developed for the determination of MNC. SDBS formed a ternary complex with MNC-Eu3+ and significantly enhanced the luminescence intensity of Eu3+. The enhanced luminescence intensity showed a good linear relationship with the concentration of MNC over the range of 4.0 × 10?7 ~ 1.0 × 10?5 mol L?1 with a detection limit of 2.0 × 10?8 mol L?1. This method is rapid and sensitive, and has been successfully applied for the determination of MNC in capsules and human urine/serum samples. The luminescence mechanism is also studied. 相似文献
93.
《Analytical letters》2012,45(11):1981-1991
Abstract A micro enzyme sensor using creatine amidinohydrolase (EC 3. 5. 3. 3) and sarcosine oxidase (EC 1. 5. 3. 1) was developed for measuring creatine. The sensor consisted of platinum and silver wires fixed in a glass tubing with epoxy resin adhesive, and creatine amidinohydrolase and sarcosine oxidase immobilized on their tip by cross-linking method. The calibration curve for measurement of creatine, the effects of pH, temperature, the amount of flavin adenine dinucleotide and compounds on the sensitivity, and the life-time of the sensor were examined. Under optimal conditions, the response of the sensor was linear in the concontration range of 10 μ M ~ 0.65 mM creatine. 相似文献
94.
《Analytical letters》2012,45(17-18):1449-1464
Abstract Spectrophotometric Method for the Rapid Determination of Microgram Amounts of Ethionamide A simple and sensitive method for the determination of microgram amounts of ethionamide is described. Ethionamide is converted to corresponding 2-ethyl-γ-pyridyl thiohydroxamic acid which gives a purple violet colour (Λmax 510 nm) with ferric chloride in acidic medium. This forms the basis for the quantitative determination of ethionamide in its pure form and in tablet form. The influence of substrates, commonly employed as excipients, is studied. An attempt has been made to determine ethionamide in the presence of other antitubercular drugs. 相似文献
95.
《Analytical letters》2012,45(3-4):283-293
Abstract A spectrofluorimetric procedure for the determination of micromolar concentrations of antimony(III) was devised based on its reduction of cerium(IV) to produce fluorescent cerium(III). The method was optimized and the reaction was fast enough in hydrochloric acid media without the need for iodide or osmium(VIII) as catalysts. Linear calibration graphs were obtained in the range 1-10 10?6M. The standard deviation for determining 5 × 10?6M antimony(III)(10 times) was 1.43 × 10?7M and the relative error was -3.4 %. The method was applied to the determination of antimony(III) in its mixture with antimony(V), total antimony was later determined after reduction with mercury metal in deoxygenated solutions. The affect several reducing agents on the determination of antimony-was also examined. 相似文献
96.
《Analytical letters》2012,45(1-3):340-348
A flow injection spectrophotometric procedure with symmetric merging zones for dipyrone determination in pharmaceutical formulations is proposed. The determination is based on the formation of a blue complex (monitored at a wavelength of 642 nm) yield in the complexation reaction of dipyrone with Fe(III) in acid medium. Under optimum conditions, a calibration curve was obtained from 3.5 to 281 mg L?1 with a detection limit of 2.8 mg L?1 and the samples throughput was 80 h?1. The analytical results obtained for commercial formulation samples by applying the proposed method were in good agreement with labeled values and those obtained by a comparative procedure at a 95% confidence level. 相似文献
97.
98.
《Journal of Coordination Chemistry》2012,65(5):373-381
The crystal structure of the rigid bidentate nitrogen ligand bis[N-(2,6-diisopropylphenyl)imino]acenaphtene (o, o'-iPr2C6H3-BIAN) is described. Syntheses, electronic spectra and electrochemical properties of two copper complexes containing (o,o'-iPr2C6H3-BIAN), namely, [CuCl(o,o'-iPr2C6H3-BIAN)2]Cl (1) and [Cu(o,o'-iPr2C6H3-BIAN)2](CIO4)(AcOH)2 (2), where AcOH=acetic acid, are reported. Although in both complexes two o,o'-iPr2C6H3-BIAN ligands are coordinated, geometries about the copper atom are significantly different. While complex 2 displays a strongly "flattened" distortion towards square-planar geometry, in complex 1 square-pyramidal coordination with an almost perfect planar arrangement of two o,o'-iPr2C6H3-BIAN ligands around the copper centre is suggested. 相似文献
99.
100.
化妆品中2种限用呫吨染料的高效液相色谱检测 总被引:1,自引:0,他引:1
建立了化妆品种中2种限用呫吨染料酸性黄73和溶剂橙16的高效液相色谱/二极管阵列检测器检测方法。在ODS C18反相色谱柱上,流动相为0.1 mol/L乙酸铵-甲醇-乙腈(体积比为65:17.5:17.5)等度洗脱,检测波长为492 nm,柱温35℃,流速1.0 mL/min。以保留时间定性,外标法定量。在5~500μg/mL范围内,酸性黄73和溶剂橙16的质量浓度与各自相应的峰面积呈现良好的线性关系,仪器检出限均为0.5μg/mL。样品前处理方法采用甲醇作溶剂超声提取,酸性黄73和溶剂橙16的加标回收率分别在91.2%~106.2%和93.2%~101.5%范围内。 相似文献