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Energy Transfer from Ce^3+ to Eu^2+ in LiSrBO3 and Its Potential Application in UV-LED-Based White LEDs 下载免费PDF全文
Ce3+/Eu2+ codoped LiSrBO3 phosphor is synthesized, and its luminescent characteristics are investigated. LiSrBO3:Ce3+,Eu2+ phosphor exhibits varied hues from blue to white and eventually to yellow by resonance-type energy transfer from Ce3+ ion to Eu2+ ion and tuning the relative proportion of Ce3+/Eu2+ properly. Energy transfer mechanism in LiSrBOa:Ce3+, Eu2+ phosphor is dominated by the dipole-dipole interaction, and the critical distance of the energy transfer is estimated to be about 2 nm by both spectral overlap and concentration quenching methods. Under UV radiation, white light is generated by coupling 436 and 565nm emission bands attributed to Ce3+ and Eu2+ radiations, respectively. 相似文献
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采用两波耦合非同时读出实验装置 ,测量了掺铈钾钠铌酸锶钡 (Ce∶KNSBN)晶体两波耦合过程中的信号光和抽运光非同时打开条件下两波耦合增益的时间变化规律 ,讨论了光扇的入射光强阈值及光扇效应对两波耦合动态过程的影响。结果表明 :6 32 .8nmHe Ne激光在Ce∶KNSBN晶体中写入体光栅时 ,光扇效应存在明显的写入光强阈值特性 ,当入射光强大于 30mW /cm2 时 ,才存在强烈的光扇效应。利用修正耦合波方程对Ce∶KNSBN晶体中的两波耦合动态过程、增益随着信号光和抽运光打开时间间隔Δt的变化进行了模拟计算 ,理论模拟结果与实验测量结果基本一致 相似文献
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电磁感应透明的重要参量之一是透明窗口的光谱线宽。在Λ-型三能级原子系统中,电磁感应透明的光谱线宽由两低能级间的相干失相速率决定,若两低能级同属于原子基态的精细结构,则电磁感应透明窗口的极限线宽很窄。但较强的耦合场作用往往会导致电磁感应透明窗口的功率展宽,而减弱耦合场又会影响电磁感应透明的对比度和深度。为此,通过引入微波控制场共振作用于基态精细能级间构成三场作用下的准Λ-型四能级系统,利用微波控制场来抑制耦合场所引起的电磁感应透明窗口的功率展宽。结果表明,引入微波控制场不仅得到了双窗口电磁感应透明,而且在保持较好对比度的条件下,使得电磁感应透明的光谱线宽明显小于不加微波场的情况。 相似文献
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The SrZnP2OT:Eu^2+, Mn^2+ phosphor is synthesized by high temperature solid state reaction. The luminescence properties and the energy transfer between Eu^2+ and Mn^2+ are investigated. The emission bands of this phosphor peaked at 42Ohm and 67Ohm are originated from the 5d → 4f transition of Eu^2+ and from the 4T1 (4G) --〉 6A1 (6S) transit/on of Mn^2+, respectively. With the increasing Mn^2+ concentration, the intensity of fixed concentra- tion Eu^2+ decreases and the intensity of Mn^2+ also increases. It is suggested that there is an energy transfer from Eu^2+ to Mn^2+ in SrZnP2O7 host. According to Dexter's energy transfer formula of multipolar interaction, the energy transfer between Eu^2+ and Mn^2+ is due to the electric dipole-quadrupole interaction of the resonance transfer. 相似文献
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采用非同时读出条件下晶体两波耦合实验装置,以单束光入射Ce:KNSBN光折变晶体,通过改变抽运光偏振方向和品体c轴的夹角φ.系统记录了不同φ角下的抽运光透射光强I',随时间的变化情况.实验结果表明,当φ≤30°时,基本没有光扇效应;实验研究了正交偏振光写入下Ce:KNSBN晶体的两波耦合动态过程,并与e光写入下两波耦合动态过程进行了比较,发现正交偏振光写入时光扇噪声得到了明显抑制,在相同的写入参量条件下光栅的衍射效率明显提高. 相似文献