热驱动谐振管回热器的时变数学模型

从自激振荡的稳定性入手,分别讨论了热声网络的周期时均和时变数学模型.用参数谐振理论讨论了热声自激振荡系统中回热器的参数储能实质.时变数学模型的建立对于深入理解热驱动谐振管回热器的热与声的能量转换实质具有重要的指导意义.     

Classical Study of Transfer and Ionization in A^2＋＋He Collisions

A simple model for the direct ionization and transfer ionization probabilities in A^2＋＋He collisions in a wide projectile energy range is proposed based on the Bohr-Lindhard model and the classical statistical model. The calculated cross sections are in satisfactory agreement with the experimental data available.     

Atomic Diffusion in Cu/Si （111） and Cu/SiO2/Si （111） Systems by Neutral Cluster Beam Deposition

The Cu films are deposited on two kinds of p-type Si （111） substrates by ionized duster beam （ICB） technique. The interface reaction and atomic diffusion of Cu/Si （111） and Cu/SiO2/Si （111） systems are studied at different annealing temperatures by x-ray diffraction （XRD） and Rutherford backscattering spectrometry （RBS）. Some significant results are obtained： For the Cu/Si （111） samples prepared by neutral dusters, the interdiffusion of Cu and Si atoms occurs when annealed at 230℃. The diffusion coefficients of the samples annealed at 230℃ and 500℃ are 8.5 ×10^-15 cm^2.s^-1 and 3.0 ×10^-14 cm^2.s^-1, respectively. The formation of the copper-silicide phase is observed by XRD, and its intensity becomes stronger with the increase of annealing temperature. For the Cu/SiO2//Si （111） samples prepared by neutral dusters, the interdiffusion of Cu and Si atoms occurs and copper silicides are formed when annealed at 450℃. The diffusion coefficients of Cu in Si are calculated to be 6.0 ×10^-16 cm^2.s^-1 at 450℃, due to the fact that the existence of the SiO2 layer suppresses the interdiffusion of Cu and Si.     

中速C3+与Ne原子靶相互作用过程中单电子转移绝对截面的测量

实验测量了2.2v₀—4.2v₀(v₀为玻尔速度,v₀=2.19×10⁸cm/s)的C³⁺与Ne原子碰撞过程中单电子转移绝对截面.将实验结果与多体经典轨道蒙特卡罗模拟计算结果进行了比较.用电离能的变化、屏蔽效应、动态关联对实验和理论计算结果间的数值差异做了分析.总体上,实验结果与多体经典轨道蒙特卡罗方法计算结果在趋势上相 关键词： 离子-原子碰撞 单电子转移 绝对截面     

100keV质子与低高能质子在绝缘微孔中输运特性的对比分析

为研究中能区带电粒子在绝缘微孔中传输的物理图像,利用MATLAB程序和蒙特卡罗方法建立理论模型,得到入射能量为10 keV,100 keV和1 MeV的质子,以-1?倾斜角入射到微孔后,出射粒子角分布、沉积电荷斑分布,以及粒子在微孔内的运动轨迹等传输特性.研究结果表明,在10 keV的低能区,微孔内壁沉积电荷的导向效应是主要的传输机制.在1 MeV的高能区,进入表面以下多次随机非弹性碰撞是主要的输运机制.在100 keV的中能区,无电荷斑时,主要是以进入表面以下的随机二体碰撞为传输机制;在电荷斑累积过程中,增强的库仑排斥力逐渐抑制入射质子在微孔内壁表面发生电子俘获;当达到充放电平衡后,主要传输机制为电荷斑辅助的近表面镜面散射行为.这一特性加深了对中能区质子在微孔中输运行为的认识,有助于对百keV质子微束的控制和应用.     

共识模型用于激光诱导击穿光谱检测泥蚶重金属铜的含量

为快速检测贝类重金属的污染,采用激光诱导击穿光谱(LIBS)结合多模型共识策略来预测泥蚶重金属铜的含量.分析铜元素的LIBS特征谱线,提取铜元素的特征峰强度、面积、峰强比等变量,分别构建多元线性回归模型,以及基于铜特征光谱区域信息构建偏最小二乘模型.在这些校正的成员模型预测残差向量间,通过拉格朗日乘数法优化各成员模型的线性组合,使共识模型的均方误差和最小,从而获得各成员模型的最优权系数.经外部预测集的验证,共识模型的预测结果优于任一成员模型,预测均方根误差为20.641mg/kg,相关系数为0.835,且预测偏差仅为-0.473,表明LIBS技术结合共识模型能用于重金属的定量检测.     

Guiding of 150 keV O6＋ ions through nanocapillaries in an uncoated Al2O3 membrane： special time dependence of the transmission profile width

<正>This paper reports that the transmission of O⁶⁺ ions with energy of 150keV through capillaries in an uncoated Al₂O₃ membrane was measured,and agreements with previously reported results in general angular distribution of the transmitted ions and the transmission fractions as a function of the tilt angle well fitted to Gaussian-like functions were observed.Due to using an uncoated capillary membrane,ourψ_c is larger than that using a gold-coated one with a smaller value of（?）,which suggests a larger equilibrium charge Q_∞in our experiment.The observed special width variation with time and a larger width than that using a smaller（?） were qualitatively explained by using mean-field classical transport theory based on a classical-trajectory Monte Carlo simulation.     

Alpha decay half-lives of heavy nuclei within a generalized liquid drop model

Theoretical α-decay half-lives of the heaviest nuclei are calculated using the experimental Qα value. The barriers in the quasi-molecular shape path is determined within a Generalized Liquid Drop Model (GLDM) and the WKB approximation is used. The results are compared with calculations using the DensityDependent M3Y (DDM3Y) effective interaction and the Viola-Seaborg-Sobiczewski (VSS) formulae. The calculations provide consistent estimates for the half-lives of the α decay chains of these superheavy elements. The experimental data stand between the GLDM calculations and VSS ones in the most time.     

罗丹明B类衍生物的合成及其对Cu2+的识别研究

以罗丹明B,水合肼和5-甲基水杨醛为原料,合成了5-甲基水杨醛-罗丹明类衍生物探针L。用经红外、核磁和质谱对其分子结构进行了表征,并采用紫外光谱法研究了其对Cu~(2+)的识别特性。结果表明:探针L对Cu~(2+)有选择性比色识别,在Cu~(2+)浓度1.0～10.0μmol·L~(-1)范围内,探针L在562nm处的吸光度与Cu~(2+)浓度呈现良好的线性关系(R=0.9994),检出痕为0.26μmol·L~(-1);Job曲线表明,探针与Cu~(2+)的络合比为1:1;利用探针L对Cu~(2+)的可逆性实验探索了探针的响应机理。     

铂纳米颗粒生长和表面结构的理论预测

本文应用最近所建立的凝结势模型[2009物理学报583293;2009J.Chem.Phys.130164711]来确定铂纳米颗粒的表面结构,利用分子动力学模拟验证了该模型的可靠性.基于该模型所进行的第一性原理计算表明,各种形状的铂颗粒表面都以fcc的(111)面为主(约80%),(100)面形成的概率约10%,该结果与已有实验观测相符合.由于凝结势计算简单,该模型应是一种从理论上确定纳米颗粒表面结构的简便方法.