丙烯腈-苯乙烯共聚物对聚甲醛的热稳定化作用

研究了丙烯腈-苯乙烯(AS)共聚物对聚甲醛(POM)的热稳定化作用. 结果表明, 在动态混炼条件下, 添加少量的AS共聚物可使POM的熔体稳定性和熔融滞留时间明显增大, AS最优添加质量分数为3%; 在静态加热条件下, AS的加入可使POM在升温过程中的分解温度显著提高, 在恒温过程中的失重率明显降低. 在动态或静态条件下, AS共聚物对POM热稳定性的贡献效果一致, 并且同时加入AS和三聚氰胺对POM的热稳定性改善更为显著. 红外分析结果表明, AS对POM的热稳定化作用源于分子链上的氰基对甲醛的有效吸收.     

外加电场法制备周期极化铌酸锂的重要结构参数的数值分析

外加电场法制备周期极化铌酸锂工艺的众多结构参数对极化进程有潜在的影响.本文采用数值方法系统的分析了周期极化的重要结构参数的影响,这些参数包括绝缘层介电常数、绝缘层厚度、电极宽度、外加电压幅度和光栅周期.证明了对极化进程影响最为显著的是电极宽度、外加电压幅度和光栅周期,它们应该是设计极化结构时需要考虑的主要参数.相对的,绝缘层介电常数、绝缘层厚度对极化进程的影响在一定条件下可以忽略.本文由此推论了一种简洁合理的极化结构设计步骤.另外,本文得到了光栅周期与最优电极宽度的二次拟合公式,它为设计提供了依据,降低了复杂程度.     

THERMAL DEGRADATION AND FLAME RETARDANCY OF CALCIUM ALGINATE FIBERS

Calcium alginate fibers were prepared by wet spinning of sodium alginate into a coagulating bath containing calcium chloride.The thermal degradation and flame retardancy of calcium alginate fibers were investigated with thermal gravimetry(TG),X-ray diffraction(XRD),limiting oxygen index(LOI) and cone calorimeter(CONE).The results show that calcium alginate fibers are inherently flame retardant with a LOI value of 34,and the heat release rate(HRR),total heat release(THR),CO and CO_2 concentrations during ...     

Poly(ethylene terephthalate)/carbon black composite fibers prepared by electrospinning

Poly(ethylene terephthalate)(PET)/carbon black(CB) composite fibers with improved mechanical properties in tensile modulus and tensile strength are prepared by eletrospinning. Stable dispersions suitable for electrospinning are obtained by dispersing melt pre-compounded PET/CB composites in hexafluoroisopropanol. The fiber morphology and CB dispersion are investigated by FESEM and TEM. The addition of CB has no obvious effect on fiber diameter, and the average fiber diameters for all the samples are around 2-3 μm. CB in the fibers is in the form of submicron-sized clusters. The thermal properties of the PET/CB composite fibers are evaluated by DSC, showing almost unchanged melting temperature and crystallinity. Uniaxial tensile tests are used to measure the mechanical properties of the PET/CB composite fiber mats. The fiber mats containing 1 wt%-8.5 wt% CB have significantly improved tensile modulus compared to neat PET fiber mat, showing reinforcing effect of CB. The electrical conductivity of the fiber mats has also been tested.     

Preparation of POE/PS blends with fine particle sizes by diffusion and subsequent polymerization of styrene in POE pellets

Ethylene-α-octene copolymer(POE)/polystyrene(PS) blend pellets with fine particle sizes were prepared by diffusion and subsequent polymerization of styrene in POE pellets through a one-pot procedure.The effects of the amounts of styrene and BPO on PS content,monomer efficiency and monomer conversion were investigated.The blend pellets were characterized by Micro-FTIR and FESEM,showing homogeneous diametrical distributions of PS and particle size.After melt-processing into rods,the average particle sizes are almost doubled,but still in submicron scale.Compared to neat POE rods,the blend rods with PS content higher than 15% exhibit improved tensile modulus and tensile strength without significantly losing ductility,being attributed to the small sizes,complex nature of particles and the existence of POE-g-PS copolymer that result in good interfacial adhesion.POE/PS pellets were compared with the previously reported PP/PS pellets,and the differences between the two systems are attributed to the different morphology of the two matrices: POE is completely amorphous at the diffusion and polymerization temperature,while i PP is semicrystalline.Without efficient impediment of the crystal lamellae in POE pellets,styrene diffuses easily in POE pellets.     

静电纺丝法制备聚甲醛纳米纤维

以六氟异丙醇为溶剂, 用静电纺丝的方法制备了聚甲醛纳米纤维. 利用场发射扫描电镜对纤维形貌进行了表征, 纤维的直径为0.3~1.2 μm. 讨论了溶液浓度、接收距离、电压和温度等纺丝参数对纤维形貌的影响. 用DSC方法对电纺纤维膜的结晶性能进行了研究, 并与溶液浇铸膜的进行了比较. 结果表明, 电纺纤维膜的熔点与溶液浇铸膜的相同, 与溶液的浓度无关, 但结晶度比溶液浇铸膜的低. 力学性能用拉伸试验进行了测试, 观察到很长的断裂伸长率.     

周期性极化铌酸锂波导全光开关特性分析

从理论方面研究了基于和频与差频级联二阶非线性效应的周期性极化铌酸锂波导全光开关的特性,给出了耦合模方程在满足相位匹配条件下小信号近似的解析表达式.用数值方法求解耦合模方程,讨论了相位失配情况下输出的信号光功率与控制光功率的关系.分析了全光开关器件的极化反转光栅周期、晶体温度、控制光波长等参量的容差特性与相互作用长度和晶体温度的关系 关键词： 级联二阶非线性 光开关 准相位匹配 周期性极化铌酸锂     

多透镜谐振腔光束参数不变性研究

给出了多透镜光学谐振腔的解析,分析了透镜腔光束参数的动态特性。提出一种补偿热焦距变化的影响的新观念,从而给出一种新形式的热稳定谐振腔——控制型热稳腔,或称软性腔。 关键词：     

洗气瓶连接方法的改进

GB/T 223.69-1997钢铁及合金化学分析方法《管式炉内燃烧后气体容量法测定碳含量》需用两个洗气瓶,1#洗气瓶内盛高锰酸钾-氢氧化钾溶液,2#洗气瓶内盛浓硫酸。在天气变化明显或天气炎热季节,仪器夜晚停用后,常因1#洗气瓶内留有带压氧气加上高锰酸钾分解产生氧气会压迫洗液回流至缓冲瓶,污染连接管。因连接管大多用医用胶管,致使管子、洗液早期失效。每当回流现象发生,轻时更换连接管,严重时须更新洗液。为防止回流现象发生,本试验在仪器上加装两个Y型三通管(市场有售),连接方法见图1。图1洗气瓶连接方法Fig.1 New way of connection of gas washing bottles图1中单线为医用胶管,B为三通管。工作时把A处用夹子夹住,工作完毕放开夹子。用这种方法完全解决了洗液回流的问题。洗气瓶连接方法的改进@乐婷$河南二纺机股份有限公司!信阳464000 @朱俊青$河南二纺机股份有限公司!信阳464000 @于建$河南二纺机股份有限公司!信阳464000 @周珍琥$河南二纺机股份有限公司!信阳464000     

GRAFTING OF POLYSTYRENE ONTO A NANOMETER SILICA SURFACE BY MICROEMULSION POLYMERIZATION

The grafting of polystyrene onto a nanometer silica surface by microemulsion polymerization is described. Silicawas functionalized with 3-methacryloxypropyltrimethoxysilane coupling agent before polymerization. A mixture of ionic andnon-ionic surfactants as well as water-soluble and oil-soluble initiators were used. The effect of the amount of silica and ionicsurfactant on the graft polymerization was studied. The graft polymerization procedure for styrene was also applied to methylmethacrylate. Composite particles with a core-shell structure were obtained and the yield and grafting efficiency of monomerwere high.