光固化环氧丙烯酸酯/SiO2杂化材料的研究

用FTIR、SEM、DSC和TGA表征了光固化环氧丙烯酸酯／SiO2杂化材料[(EA-TMSPM)／SiO2]，研究了盐酸、γ-甲基丙烯酰氧丙基三甲氧基硅烷(TMSPM)和无机物浓度对(EA-TMSPM)／SiO2结构与性能的影响。结果表明，无机物浓度高的(EA-TMSPM)／SiO2杂化体系中SiO2粒子尺寸略大于无机物浓度低的体系；盐酸和无机物浓度的增加，都可以增强杂化材料的耐磨性。     

Theoretical calculation of energy levels and radiative lifetimes of Tl I

Considering the perturbation, the results of theoretical calculation of five Rydberg series energy levels 6s2ns^2S1/2 （n = 7 - 20）, 6s^2nd^2D3/2 （n = 6 - 20）, 6s^2nd^2D5/2 （n = 6 - 20）, 6s^2np^2P1/2^0 （n = 7- 20）, and 6s^2np^2P3/2^0 （n = 7-20） for Tl I are presented using the weakest bound electron potential model （WBEPM） theory. Furthermore, the radiative lifetimes of this five series are also calculated. The calculated values of energy levels and lifetimes are in good agreement with the experimental results.     

紫外光固化耐磨涂料的进展

综述了紫外光固化耐磨涂料的进展情况 ,着重介绍了溶胶 -凝胶法制备紫外光固化耐磨杂化涂料的研究进展。     

收益序列相关的动态资产-负债管理

以条件期望体现风险资产收益的相关性,建立了资产收益序列相关时资产-负债管理的动态均值-方差模型.采用Li和Ng(2000)的嵌入法,构造了一个具有二次效用函数的辅助问题,利用动态规划方法及原问题与辅助问题最优策略之间的关系,得到了原问题的最优投资组合策略和有效边界.     

基于Copula理论的装甲车辆齿轮传动箱系统的可靠性分析

应用Copula函数研究了某型装甲车辆齿轮传动箱的系统可靠性问题,得出了系统的可靠度函数和失效率,并与独立性下的可靠度函数进行比较,通过分析两种方法下可靠度的变化趋势,得出基于Copula函数的可靠度函数更接近于实际情况.     

金与银电极表面甘氨酸分子吸附作用的SERS光谱研究

本文利用表面增强拉曼光谱(SERS)技术研究了甘氨酸在金与银基底表面的吸附作用特征。研究表明甘氨酸分子以COO-的不对称形式吸附于金电极表面,且NH2也是其可能的吸附位点;而在银电极表面,则主要是通过COO-的对称形式而吸附。在此基础上,进一步研究了电极电位与溶液酸碱性对吸附于粗糙化银电极表面甘氨酸分子吸附作用的影响。研究结果表明,甘氨酸分子中去质子化羧基的吸附作用受电位影响较小,而电位对-NH3+吸附作用的影响程度较大。另一方面,溶液pH值对银电极表面的甘氨酸分子吸附行为的影响也较为显著。随着溶液酸性减小羧基倾向于相对于电极表面平行吸附。这是由于随着溶液碱性增大氨基质子化程度的减小,有利于氨基在银电极表面吸附。这将改变分子的吸附构型使其更接近于电极表面。这些变化主要出现在pH值大于10的条件下。     

超Li系统的Bargmann对称约束和双非线性化

给出超Li系统的一个显式对称约束和关于其Lax对的双非线性化.在此对称约束下,超Li系统的时间部分和空间部分分别被约化为有限维Liouville可积超Li系统.     

Hard X-ray one dimensional nano-focusing at the SSRF using a WSi2 /Si multilayer Laue lens

The multilayer Laue lens (MLL) is a novel diffraction optics which can realize nanometer focusing of hard X-rays with high efficiency. In this paper, a 7.9 μm-thick MLL with the outmost layer thickness of 15 nm is designed based on dynamical diffraction theory. The MLL is fabricated by first depositing the depth-graded multilayer using direct current (DC) magnetron sputtering technology. Then, the multilayer sample is sliced, and both cross-sections are thinned and polished to a depth of 35-41 μm. The focusing property of the MLL is measured at the Shanghai Synchrotron Facility (SSRF). One-dimensional (1D) focusing resolutions of 205 nm and 221 nm are obtained at E=14 keV and 18 keV, respectively. It demonstrates that the fabricated MLL can focus hard X-rays into nanometer scale.     

Design and preparation of LWIR narrow-band filter with wide rejection band

In this letter, using mult-half-wave structure and some chosen films optimized method, the long-wave infrared （LWIR） narrow-band pass filter is investigated, meanwhile the opposite of the substrate coated with long-wavelength pass film. The transmittance of design spectrum is more than 80% at wavelength region of 8.05 8.35 μm, and the average transmittance is less than 0.5% at wavelength region of less than 7.95 and 8.45 14 pro. The filter is prepared by thermal evaporation method, and plasma-assisted deposition technology. The experiment result shows that the average transmittance is about 75% in the transmission wavelength range, and the average transmittance of cut-off band is about 0.3%. The results show that multi-half-wave structure and some chosen films optimized method for the preparation LWIR narrow-band pass filter are feasible. The film system is simplified and is convenient to prepare the film.     

从矿物宝石到光电功能晶体——解读蒋民华先生《晶体赋》

晶体美丽有用,构造和谐有序。光电功能晶体可实现光能和电能的相互转化,在微电子、光电子、通信、航天及现代军事技术等高科技领域占有重要地位。人类认识晶体,源于天然矿物。从矿物晶体的发现到光电功能晶体的人工生长和应用经历了漫长的发展,晶体种类、晶体质量、生长理论、生长技术以及应用等方面均取得了较大进展。本文简述了从矿物宝石到晶体学发展的历程,介绍了压电晶体、电光晶体、激光晶体、非线性光学晶体和闪烁晶体等几类光电功能晶体发展历程及晶体生长研究的进展,展望了未来光电功能晶体的发展趋势。