猝灭-恢复型电化学发光传感器测定抗坏血酸的研究

制备了氮硫掺杂石墨烯量子点(NSGQDs),并将其修饰在金电极表面.基于NSGQDs良好的电化学发光(ECL)特性,以其为探针,进一步将铜-金属有机框架(Cu-MOF)修饰于该电极表面,构建了猝灭-恢复型ECL传感器用于抗坏血酸的高灵敏检测.由于NSGQDs表面存在大量氨基,当Cu-MOF存在时,NSGQDs的ECL信号猝灭;加入抗坏血酸后,Cu-MOF从NSGQDs表面自动脱落,NSGQDs的ECL信号得以恢复.NSGQDs的ECL信号恢复值与抗坏血酸浓度在0.1～40 μmol/L之间呈良好的线性关系,检出限为3.2 nmol/L.该法已用于血样中抗坏血酸的测定,并进一步研究了人血液中抗坏血酸24h的药代动力学规律.     

基于电感耦合等离子体的InP基半导体材料干法刻蚀的研究

研究了基于电感耦合等离子体(ICP)刻蚀系统的InP基半导体材料的干法刻蚀.采用Cl2/Ar/H:混合刻蚀气体,分别研究了氯气体积分数和ICP功率与刻蚀速率之间的关系,及镍、二氧化硅和二者结合型掩膜版的适用范围.获得有效的刻蚀速率为450～1 200 nm/min,InP对金属镍的选择性刻蚀比值为175～190.掩膜版...     

芯棒与口模反向旋转挤出聚乙烯管结构与性能的研究

采用自行研制的新型旋转挤出装置,通过芯棒与口模同时反向旋转挤出制备聚乙烯(PE)管.结果表明,在口模与芯棒反向旋转挤出过程中,管道内外壁除受到轴向应力作用外,还受到芯棒和口模旋转所施加的环向应力,其合力方向不再是沿管道轴向而是与其有一定的角度.因此,分子链的取向方向和以此链为初级成核点形成的串晶偏离轴向,增强了管道抵抗...     

First-principles study of a new BP2 two-dimensional material

Two-dimensional materials have a wide range of applications in many aspects due to their unique properties. Here we carry out a detailed structural search and design of the BP₂ using the first principles method, and find a new PMM2 sheet. The analysis of the phonon dispersive curves shows that the 2D PMM2 is dynamic stable. The study of molecular dynamics shows that the 2D PMM2 can be stable under high temperature, even at 600 K. Most importantly, when a suitable strain is applied, the structure can exhibit other electronic properties such as direct band gap semiconductor. In addition, the small strain can tune the band gap value of the PMM2 structure to around 1.4 eV, which is very close to the ideal band gap of solar materials. Therefore, the 2D PMM2 may have potential applications in the field of photovoltaic materials.     

Low-voltage soft robots based on carbon nanotube/polymer electrothermal composites

Nowadays, soft robots have become a research hot spot due to high degree of freedom, adaptability to the environment and safer interaction with humans. The carbon nanotube (CNT)/polydimethylsiloxane (PDMS) electrothermal composites have attracted wide attention in the field of flexible actuations due to large deformation at low voltages. Here, the preparation process of CNT/PDMS composites was designed and optimized, and electrothermal actuators (ETAs) were fabricated by cutting the CNT/PDMS composite films into a "U" shape and coating conductive adhesive. The deformation performance of the ETAs with different thicknesses at different voltages was studied. At a low voltage of about 7 V, the ETA has a deformation rate of up to 93%. Finally, two kinds of electrothermal soft robots (ETSRs) with four-legged and three-legged structures were fabricated, and their inchworm-like motion characteristics were studied. The ETSR2 has the best motion performance due to the moderate thickness and three-legged electrode structure.     

双自由度非定点斜碰撞振动系统的动力学分析

对两个单摆组成的双自由度、非定点、斜碰撞振动系统的动力学行为进行了详细研究．揭示了在双自由度、非定点、斜碰撞过程中恢复系数、摩擦系数、系统参数和碰撞前后系统状态之间的关系．基于Poincaré映射方法和非定点斜碰撞关系推导出该系统单碰周期n次谐运动存在性判据．根据Floquet理论分析了该系统次谐运动周期解的稳定性问题,给出了Floquet特征乘子的计算公式．通过数值仿真证实了该方法的有效性,同时分析了非定点、斜碰撞系统碰撞点位置的概率分布情况．     

超细聚酰胺6粒子增韧聚丙烯体系的研究

采用磨盘形力化学反应器室温下制备了聚丙烯 (PP) /聚酰胺 6 (PA6 )超细粉体 ,研究了其粒度、粒度分布及PA6超细粒子填充对PP力学性能的影响 .结果表明 ,磨盘形力化学反应器可有效实现PP/PA6的粉碎 ,所得粉体平均粒径达微米级 ,初级粒子尺寸甚至可达纳米级 ,粒度分布呈双峰分布状态 .在PA6和PP熔点之间的温度下加工可制得PA6超细粒于填充的PP/PA6共混体系 ,其力学性能明显好于PP/PA6简单共混体系 ,30 %PA6用量下 ,拉伸强度由 2 3 .2MPa提高至 2 9 3MPa ,Izod缺口冲击强度由 4.6 2kJ/m2 提高到6 .34kJ/m2 .形貌分析结果表明 ,由于基本保持了PA6超细粉体的原始尺寸 ,填充体系中PA6相区尺寸小、分布均匀 ,与使用增容剂得到的相区结构类似 .     

氧化锆对铜基甲醇合成催化剂的促进作用(英文)

采用离子掺杂价态补偿原理,在Ｃｕ－Ｚｎ－Ａｌ甲醇合成催化剂中添加适量氧化锆助剂研制Ｃｕ－Ｚｎ－Ａｌ－Ｚｒ催化剂的特性。实验结果表明,最佳反应温度为２３０℃,比Ｃｕ－Ｚｎ－Ａｌ约低１０℃。采用ＸＲＤ、ＵＶＤＲ、ＦＴＩＲ、ＴＰＤ和ＴＰＲ等谱学方法对２种催化剂进行表征显示,铜基催化剂的活性位可能是“Ｃｕ０－Ｃｕ＋－Ｏ－Ｚｎ２／Ａ２Ｏ３－ＺｒＯ２”,工作态Ｃｕ－Ｚｎ－Ａｌ－Ｚｒ催化剂表面上Ｃｕ／Ｃｕ０的比值、价态稳定性和对ＣＯ的吸附量均大于Ｃｕ－Ｚｎ－Ａｌ,这与该催化剂具有较好的低温活性和较高的热稳定性密切相关。     

分子复合法制备新型聚合物驱油剂CMC/P(AM-DMDAAC)

通过具有互补结构的阴离子聚合物羧甲基纤维素(CMC)与阳离子聚合物聚(丙烯酰胺-二甲基二烯丙基氯化铵)[P(AM-DMDAAC)]间的聚电解质分子复合作用,制备了分子复合型CMC/P(AM-DMDAAC)新型驱油剂.电导率测定及紫外光谱分析结果表明,CMC与P(AM-DMDAAC)可以在水相通过库仑力形成均相聚电解质复合溶液.由于分子复合形成的独特超分子结构,复合溶液粘度显著增加,分别为组分聚合物溶液的5.2倍和9.0倍,在高温和高剪切环境中的粘度保持能力也明显优于其组分聚合物.     

钾修饰的moo3/sio2催化剂的xrd和tpr表征

moo3/k2o/sio2催化剂;xrd;tpr;高硫合成气;甲硫醇