三个稀土-主族三金属Ln(III)-Sr(II)-K(I)配合物的结构与发光性质

用2,4,6-吡啶三甲酸和稀土钐、镝或钆的高氯酸盐溶液、碳酸锶、碳酸钾在180℃水热条件下进行反应,制备出3个含有3种金属离子的配位聚合物[LnSrK（ptc）₂（H₂O）]_n（Ln=Sm（1）、Dy（2）、Gd（3）,H₃ptc=2,4,6-吡啶三甲酸）。X射线单晶衍射分析表明三者具有相同的结构,属三斜晶系,P1空间群。配合物中配体2,4,6-吡啶三甲酸根以2种不同的配位方式与3种金属离子配位,一种方式中连接了7个金属离子,另一种方式中连接了8个金属离子。Ln（Ⅲ）为八配位,与羧基上的6个氧原子和2个吡啶环上的2个氮原子配位;Sr（Ⅱ）也是八配位,配位原子均为氧原子;K（I）与5个氧原子配位。荧光发射光谱表明,钐和镝的配合物在紫外光激发下均发射Sm（Ⅲ）和Dy（Ⅲ）两种离子的特征荧光,钆的配合物在紫外光激发下由于发生荷移跃迁而发射绿色荧光。     

Extraction of Strontium and Cesium by Dicarbollides, Crown Ethers and Functionalized Calixarenes

The two main classes of extractantsused for the extraction of cesium and strontium aredicarbollides and crown ethers. Dicarbollides wereused on a large scale for the extraction of these twoelements from high-activity waste. The basicdicarbollides present drawbacks since they need to bediluted in polar solvent such as nitrobenzene and theirefficiency strongly decreases as the acidity of liquidwaste increases. Crown ethers enable cesium andstrontium to be extracted if the concentration ofsodium or the acidity of solutions are not too high.Recently, calixarenes blocked in the 1,3-alternateconformation were used for the selective extractionof cesium, even from high-salt waste matrices.     

Optical and Electrical Properties of Ferroelectric SBN Thin Films Prepared by Sol-Gel Process

Strontium barium niobate thin films were prepared by sol-gel method on various substrates using an improved process, two-step heating process. The two-step heating process applies an additive heat-treatment before crystallization for enhancement of the densification and the nucleation of films. Also, highly c-axis oriented SBN thin films with various compositions were obtained on MgO(100) and Pt(100)/MgO(100) substrates. Their optical and electrical properties such as optical propagation loss, refractive index, P-E hysteresis, and dielectric constant, were characterized as a function of the film composition.     

Studies on growth and characterization of l-alanine strontium chloride trihydrate single crystals for optical applications

The optically transparent nonlinear optical single crystals of l-alanine strontium chloride trihydrate (LASCT) were grown by slow evaporation solution growth method using water as solvent. The purity of the crystals was increased by the method of recrystallization. The grown crystals were analyzed by the single crystal X-ray diffraction pattern which proved that LASCT belongs to monoclinic crystal system. The presence of various functional groups and modes of vibrations were identified by FTIR spectroscopy. The optical absorption study confirms the suitability of the crystal for device applications. The thermal strength and the decomposition of the grown crystals were studied using TG/DTA analyses. The dielectric constant and dielectric loss measurements of the grown crystals at different frequencies of the applied field were measured and reported. The mechanical strength of the crystal is estimated by Vicker's hardness test. The nonlinear optical properties of the grown crystals were confirmed by second harmonic generation test which shows the suitability of NLO applications.     

NSB对油菜某些生理特性及产量的影响

在油菜的蕾苔期、初花期喷施一定浓度的植物生长调节剂萘乙酸、微量元素锶和硼的混合配方,可以促进植物的生长发育和增强花粉的生活力,提高泌蜜量、叶绿素含量和硝酸还原酶的活性,增强植株的根系活力和抗旱性,加快可溶性糖的转移,同时能有效地提高油菜产量。     

锶改性对γ-Al2O3的高温热稳定作用

 研究了Sr（NO3）2浸渍改性对γ－Al2O3的高温热稳定作用,考察了Sr含量（SrO／Al2O3摩尔比为0．005～0．15）以及热处理温度（600～1150℃）和气氛等影响因素．BET比表面积和粉末X射线衍射结果表明,高温下Sr物种的引入明显地抑制了氧化铝比表面积的损失和α相变,而水蒸气的存在则削弱了Sr物种的高温稳定作用．随着Sr含量的增大,Sr物种的高温稳定作用增强,但过度提高Sr含量时（SrO／Al2O3比为0．15）,Sr物种的纯机械混合掺杂的负作用超过其对Al2O3的稳定作用．焙烧温度从600℃升至1150℃,氧化铝与Sr物种固相反应的产物由二铝酸盐转化至六铝酸盐．高温动力学研究结果表明,Sr的高温稳定作用主要是抑制焙烧过程中最初1h内的烧结和其后α相变引起的比表面积损失．     

Theoretical investigation of phase transition properties in strontium chalcogenides using potential model

The Born–Mayer potential has been employed to predict the phase transition pressure in four strontium monochalcogenides, namely, SrO, SrS, SrSe, and SrTe, which crystallize in the NaCl (B1) phase and with the application of pressure, transforms to the CsCl (B2) phase. The compression, bulk modulus and the first-order pressure derivative of bulk modulus have also been calculated and compared with the available experimental and other theoretical results. The calculated values of transition pressure and other elastic properties predict that the hardness and strength parameters depend on the crystal structure and have the different values for different structures.     

Luminescence of europium and ytterbium ions in strontium hexaborate

We have studied the luminescent properties of Eu^2+/3+ and Yb²⁺ ions in strontium hexaborate SrB₆O₁₀ for excitation in the 120–400 nm region. The luminescence spectra of Ln²⁺ ions in SrB₆O₁₀ consist of overlapping bands in the 370–520 nm region, due to 5d → 4f transitions at several nonequivalent centers. In the excitation spectra, besides the bands associated with 4f → 5d transitions in the Ln²⁺ ions, we also observe a band in the 135–160 nm region due to the transitions O(2p) → B(2s,2p) within the borate anions. The luminescence of the Eu³⁺ ions is excited most efficiently in the region of the Eu³⁺ charge transfer band (λ_max = 226 nm). The results obtained are compared with data for Ln in other strontium borates. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 6, pp. 770–774, November–December, 2006.     

Strontium‐based initiator system for ring‐opening polymerization of cyclic esters

An amino isopropoxyl strontium (Sr‐PO) initiator, which was prepared by the reaction of propylene oxide with liquid strontium ammoniate solution, was used to carry out the ring‐opening polymerization (ROP) of cyclic esters to obtain aliphatic polyesters, such as poly(ε‐caprolactone) (PCL) and poly(L ‐lactide) (PLLA). The Sr‐PO initiator demonstrated an effective initiating activity for the ROP of ε‐caprolactone (ε‐CL) and L‐lactide (LLA) under mild conditions and adjusted the molecular weight by the ratio of monomer to Sr‐PO initiator. Block copolymer PCL‐b‐PLLA was prepared by sequential polymerization of ε‐CL and LLA, which was demonstrated by ¹H NMR, ¹³C NMR, and gel permeation chromatography. The chemical structure of Sr‐PO initiator was confirmed by elemental analysis of Sr and N, ¹H NMR analysis of the end groups in ε‐CL oligomer, and Fourier transform infrared (FTIR) spectroscopy. The end groups of PCL were hydroxyl and isopropoxycarbonyl, and FTIR spectroscopy showed the coordination between Sr‐PO initiator and model monomer γ‐butyrolactone. These experimental facts indicated that the ROP of cyclic esters followed a coordination‐insertion mechanism, and cyclic esters exclusively inserted into the Sr–O bond. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1934–1941, 2003