水溶性有机材料的合成与结构的研究

本文采用新的合成方法,合成了双链磺酸盐、多羟基化合物和杂环的磺酸化合物,鉴定其结构,研究了结构与结构与性能的关系,并作为光亮镍的添加剂,获得实际应用。     

具有几何对称性的12参数矩形板元

1 引言 三角形板元中,形式最简单的是九参数元,节点参数是单元三个顶点上的函数值和两个一阶偏导数值,非协调九参三角形板元的研究取得了丰硕成果,根据不同方法已构造出多种收敛性能好的单元.相比之下,矩形板元的研究较少见报道.矩形板元中形式最简单的是12参元,节点参数是单元4个顶点上的函数值和两个一阶偏导数值,这类似于九参三角形板元.常见的12参矩形板元是ACM元,其形函数空间是完整3次多项式空间加上两个4次多项式的基函数,ACM元是C°元,但位移形函数的外法向导数平均值在单元间不连续,这类似于Zienkiewicz九参三角形板元,但由于矩形单元的特殊形状,ACM元是收敛的.龙驭球教授等在[1]中提出一种12参矩形广义协调元,其位移形函数的外法向导数平均值在     

一类改进的Wilson任意四边形单元

Wilson元是工程计算中数值效果很好的一种非协调元,但对任意四边形网格却不能收敛。石钟慈要求四边形单元满足对角线中点距离d_k=O(h_k~2),[2]、[3]提出了一个六参数非协调四边形单元。它对任意四边形网格收敛,但其单元上的形状函数非常依赖单元本     

二次多项式型平面光波导模式

用一级微扰理论，对二次多项式折射分布平面光波导，进行了波方程的解析求解，推得用Ａｉｒｙ函数表示的场解和色散方程。用一级微扰近似计算了传播常数，并与实验值进行了比较，其结果是符合的。     

一种具有应用潜力的等离子体用绿色荧光粉(英文)

研究了绿色荧光粉Ca2GeO4∶Tb3+的真空紫外光谱性质,用172 nm激发荧光粉,其发射峰在549 nm,此绿色发光峰归属于Tb3+的5D4→7F5磁偶极跃迁,Tb3+离子的最佳摩尔分数x=0.05。激发光谱中147 nm和172 nm的激发强度分别是218 nm的1.5和1.7倍。因为在等离子体显示中激发光波长是147 nm和172nm,因此荧光粉在这两个波长的激发强度对荧光粉在等离子体显示中的应用至关重要。Al3+的共掺杂可使荧光粉的发光强度增强2倍,因此,Ca2GeO4∶Tb3+是一种具有应用潜力的等离子体显示用绿色荧光粉。     

高能X射线源焦斑尺寸的时间分辨诊断

将门控分幅相机与快闪烁晶体结合,构成时间分辨X射线诊断系统,对神龙一号直线感应加速器产生的高能脉冲X射线源焦斑进行了测量,在时间间隔为10 ns的情况下,获得了焦斑尺寸随时间的变化曲线。在此基础上,设计了单像素尺寸为0.78 mm×0.78 mm的LYSO闪烁晶体阵列,并进行了X射线照射晶体阵列发光的初步实验,结果表明该阵列可用于高能X射线源焦斑的时间分辨诊断,并能显著提高成像的空间分辨力。     

新型含苯并磷杂环戊二烯结构荧光分子的合成及性能

以三苯胺、咔唑为电子给体, 苯并磷杂环戊二烯氧化物为电子受体, 设计合成了一类新颖的D-A-D 型荧光分子, 其结构经¹H NMR, ¹³C NMR, ³¹P NMR, IR和MS确认。通过紫外可见吸收光谱和荧光光谱系统研究了不同给体和受体单元对荧光分子的紫外吸收、液体荧光、固体荧光、溶致变色及聚集诱导发光等光物理性能的影响。结果表明：合成的三种分子具有良好的液体和固体荧光性能;化合物TBN-EPIO具有显著的溶致变色效应, 在四氢呋喃-水二元溶剂体系中, 具有聚集诱导发光(AIE)效应。此外, 利用密度泛函理论计算了分子的几何构型及前线分子轨道电子云。      

An Efficient Scheme for Multiparty Multi-particle State Sharing

We present an efficient scheme for sharing an arbitrary m-qubit state with n agents. In our scheme, the sender Alice first shares m Bell states with the agent Bob, who is designated to recover the original m-qubit state. Furthermore, Alice introduces n- 1 auxiliary particles in the initial state ｜0）, applies Hadamard （H） gate and Controlled-Not （CNOT） gate operations on the particles, which make them entangled with one of m particle pairs in Bell states, and then sends them to the controllers （i.e., other n - 1 agents）, where each controller only holds one particle in hand. After Alice performing m Bell-basis measurements and each controller a single-particle measurement, the recover Bob can obtain the original unknown quantum state by applying the corresponding local unitary operations on his particles. Its intrinsic efficiency for qubits approaches 100%, and the total efficiency really approaches the maximal value.     

Primary result of ^236U measurement with accelerator mass spectrometry at CIAE

The rare isotope ^236U has a half-life of 2.342（3）×107 years, and is produced principally by thermal neutron capture on ^235U. The isotopic atom ratio of ^236U/^238U depends on the integral thermal neutron flux received by the material of interest. ^236U is potentially useful as a ＂fingerprint＂ for indicating the presence of neutron-irradiated uranium usually originating from nuclear activity. By extracting negative molecular ion UO^- from the uranium oxide target, simulating the ^236U^16O^- beam transport with ^238U^16O^- and ^208Pb2^16O^- pilot molecular ion beam, transporting the ^236U-containing ion beam with a high resolution injection magnet analyzer and electrostatic analyzer system, and finally identifying and detecting ^236U with a time-of-flight detector （TOF）, a method for AMS （Accelerator Mass Spectrometry） measurement of ^236U was established on the HI-13 Accelerator AMS system at China Institute of Atomic Energy.     

Primary result of ~(236)U measurement with accelerator mass spectrometry at CIAE

The rare isotope 236U has a half-life of 2.342(3)×107 years,and is produced principally by thermal neutron capture on 235U.The isotopic atom ratio of 236U/238U depends on the integral thermal neutron flux received by the material of interest.236U is potentially useful as a fingerprint for indicating the presence of neutron-irradiated uranium usually originating from nuclear activity.By extracting negative molecular ion UO- from the uranium oxide target,simulating the 236U16O- beam transport with 238U16O- an...