全文获取类型
收费全文 | 1631篇 |
免费 | 522篇 |
国内免费 | 600篇 |
专业分类
化学 | 1062篇 |
晶体学 | 80篇 |
力学 | 118篇 |
综合类 | 56篇 |
数学 | 412篇 |
物理学 | 1025篇 |
出版年
2024年 | 9篇 |
2023年 | 48篇 |
2022年 | 64篇 |
2021年 | 38篇 |
2020年 | 54篇 |
2019年 | 75篇 |
2018年 | 80篇 |
2017年 | 78篇 |
2016年 | 72篇 |
2015年 | 48篇 |
2014年 | 104篇 |
2013年 | 110篇 |
2012年 | 93篇 |
2011年 | 120篇 |
2010年 | 107篇 |
2009年 | 110篇 |
2008年 | 125篇 |
2007年 | 96篇 |
2006年 | 87篇 |
2005年 | 78篇 |
2004年 | 94篇 |
2003年 | 89篇 |
2002年 | 77篇 |
2001年 | 59篇 |
2000年 | 71篇 |
1999年 | 84篇 |
1998年 | 72篇 |
1997年 | 91篇 |
1996年 | 57篇 |
1995年 | 46篇 |
1994年 | 69篇 |
1993年 | 53篇 |
1992年 | 41篇 |
1991年 | 34篇 |
1990年 | 37篇 |
1989年 | 23篇 |
1988年 | 20篇 |
1987年 | 19篇 |
1986年 | 25篇 |
1985年 | 17篇 |
1984年 | 13篇 |
1983年 | 26篇 |
1982年 | 14篇 |
1981年 | 9篇 |
1980年 | 5篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1959年 | 1篇 |
1957年 | 2篇 |
1956年 | 1篇 |
排序方式: 共有2753条查询结果,搜索用时 27 毫秒
101.
对白酒中的有机锡化合物运用NaBEt4进行衍生,并采用液液萃取和气相色谱—质谱法(GC-MS)对5种衍生物进行分析,建立了5种有机锡同时分析的新方法.选用选择离子扫描模式进行定性和定量分析,实验对影响反应的重要参数进行了优化.在优化条件下,5种有机锡化合物在0.01~4.0 μg·mL-1的线性范围内得获得了较好的线性,检测限,相关系数为0.992 3~0.999 9,检测限为0.4~5.0 μg·L-1.在0.05、0.50和4.0μg·mL-13个添加水平获得了较好的回收率,其相对标准偏差低于13.4%.该方法简便、快速、容易操作,初步运用于检测酒样中的有机锡化合物,取得较满意的结果. 相似文献
102.
采用两相法合成了CdSe/CdS核-壳结构的量子点, 用氨水催化水解正硅酸乙酯制得复合结构的CdSe/CdS/SiO2发光纳米球. 通过对量子点用量、氨水用量、反应时间及溶剂比例等实验条件的调节, 得到了单分散性较好, 尺寸在23~145 nm的复合发光纳米球. 利用紫外-可见吸收光谱和荧光发射光谱对其发光性能进行了研究, 同时利用透射电镜(TEM)观察复合纳米球的形貌. 结果表明, 复合发光纳米球样品的最高荧光量子产率可达8%. 相似文献
103.
针对用于快速传递对准的卡尔曼滤波器阶数高,计算量大,滤波更新率低,鲁棒性差及对准精度不高等问题,提出采用联合强跟踪Kalman滤波器进行快速传递对准。文中设计了联合强跟踪Kalman滤波器的结构和算法,同时利用改进的Elman网络进行信息分配系数的自适应调节,以实现融合信息在各子系统中的自适应分配。仿真结果表明,该滤波器不仅提高了解算速度,而且提高了系统鲁棒性和对准精度。 相似文献
104.
105.
<正>The measurements of the potential distributions in the boundary layer near meshes with different mesh spacing were conducted in weakly collisional plasmas using a fine-structured emissive probe and the results of the sheath thickness and electric field at the sheath-presheath edge were compared with theoretical models of collisional presheath and collisionless sheath.It was shown that,because the meshes are partially transparent to ions,the sheath is thinner and the electric field is stronger for the mesh of higher transmissivity,owing to the increased ion density in the sheath contributed from the ions transmitted from the other side of the mesh.However,the potential profiles in the presheath remain almost the same for different meshes except for the shift of the sheath-presheath edge.The thickness of the sheath decreases while the electric field at the edge increases with the increase of the neutral gas pressure.Furthermore, depending on the pressure,the measured electric fields at the edge are close to that from the models of a transition region. 相似文献
106.
Difference-frequency ultrasound generation from microbubbles under dual-frequency excitation 下载免费PDF全文
The difference-frequency (DF) ultrasound generated by using parametric effect promises to improve detection depth owing to its low attenuation, which is beneficial for deep tissue imaging. With ultrasound contrast agents infusion, the harmonic components scattered from the microbubbles, including DF, can be generated due to the nonlinear vibration. A theoretical study on the DF generation from microbubbles under the dual-frequency excitation is proposed in formula based on the solution of the RPNNP equation. The optimisation of the DF generation is discussed associated with the applied acoustic pressure, frequency, and the microbubble size. Experiments are performed to validate the theoretical predictions by using a dual-frequency signal to excite microbubbles. Both the numerical and experimental results demonstrate that the optimised DF ultrasound can be achieved as the difference frequency is close to the resonance frequency of the microbubble and improve the contrast-to-tissue ratio in imaging. 相似文献
107.
High-quality p-type boron-doped IIb diamond large single crystals are successfully synthesized by the temperature gradient method in a china-type cubic anvil high-pressure apparatus at about 5.5 GPa and 1600 K.The morphologies and surface textures of the synthetic diamond crystals with different boron additive quantities are characterized by using an optical microscope and a scanning electron microscope respectively.The impurities of nitrogen and boron in diamonds are detected by micro Fourier transform infrared technique.The electrical properties including resistivities,Hall coefficients,Hall mobilities and carrier densities of the synthesized samples are measured by a four-point probe and the Hall effect method.The results show that large p-type boron-doped diamond single crystals with few nitrogen impurities have been synthesized.With the increase of quantity of additive boron,some high-index crystal faces such as {113} gradually disappear,and some stripes and triangle pits occur on the crystal surface.This work is helpful for the further research and application of boron-doped semiconductor diamond. 相似文献
108.
An acoustic dipole radiation model for magnetoacoustic tomography with magnetic induction (MAT-MI) is pro-posed,based on the analyses of one-dimensional tissue vibration,three-dimensional acoustic dipole radiation and acoustic waveform detection with a planar piston transducer.The collected waveforms provide information about the conductiv-ity boundaries in various vibration intensities and phases due to the acoustic dipole radiation pattern.Combined with the simplified back projection algorithm,the conductivity configuration of the measured layer in terms of shape and size can be reconstructed with obvious border stripes.The numerical simulation is performed for a two-layer cylindrical phantom model and it is also verified by the experimental results of MAT-MI for a tissue-like sample phantom.The proposed model suggests a potential application of conductivity differentiation and provides a universal basis for the further study of conductivity reconstruction for MAT-MI. 相似文献
109.
分别采用微波加热乙二醇还原法(MW)和浸渍还原法(IR)制备以碳化钨(WC)为载体的Pt/WC催化剂, 并分别标记为: MW-Pt/WC及IR-Pt/WC. 用XRD、SEM对两种方法制备的复合材料的结构与形貌进行表征. 循环伏安测试结果表明MW-Pt/WC催化剂在酸性条件下的甲醇氧化性能比IR-Pt/WC催化剂更优, 表现在同一电位下MW-Pt/WC催化剂具有更高的电流且其氧化起始电位负移约30 mV, 还具有更大的电化学比表面积. 此外计时电流法实验结果表明MW-Pt/WC催化剂的稳定性高于IR-Pt/WC催化剂. 相似文献
110.