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测量了YAG(Y3Al5O12)/Nd:YAG单晶、Nd:YAG前驱物及其在不同温度下煅烧获得粉体的拉曼光谱,对谱峰的振动模式进行了指认,对结果进行了分析.Nd:YAG前驱物在煅烧时,有一个由非晶态向晶态的转化过程;700℃下烧结前驱物获得非晶态产物的结构中含有AlO4四面体结构;随着煅烧温度的升高,拉曼光谱的变化主要表现在两个方面:一是谱峰半高宽(FWHM)减小,谱峰强度增大;二是一些拉曼光谱谱峰发生了频移,这是纳米多晶粉体的界面组元的有序度提高所致.另外,800℃下煅烧获得的Nd:YAG纳米粉体的品格振动模式与Nd:YAG晶体的晶格振动模式存在差异,这是纳米多晶粉体的界面组元的贡献所致. 相似文献
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Full-profile fitting of emission spectrum to determine transition intensity parameters of Yb~(3+):GdTaO_4 下载免费PDF全文
The Judd-Ofelt theoretic transition intensity parameters A_(tp)~k of luminescence of rare-earth ions in solids are important for the quantitative analysis of luminescence.It is very difficult to determine them with emission or absorption spectra for a long time.A "full profile fitting" method to obtain A_(tp)~k in solids with its emission spectrum is proposed,in which the contribution of a radiative transition to the emission spectrum is expressed as the product of transition probability,line profile function,instrument measurement constant and transition center frequency or wavelength,and the whole experimental emission spectrum is the sum of all transitions.In this way,the emission spectrum is expressed as a function with the independent variables intensity parameters A_(tp)~k,full width at half maximum(FWHM) of profile functions,instrument measurement constant,wavelength,and the Huang-Rhys factor S if the lattice vibronic peaks in the emission spectrum should be considered.The ratios of the experimental to the calculated energy lifetimes are incorporated into the fitting function to remove the arbitrariness during fitting A_(tp)~k and other parameters.Employing this method obviates measurement of the absolute emission spectrum intensity.It also eliminates dependence upon the number of emission transition peaks.Every experiment point in emission spectra,which usually have at least hundreds of data points,is the function with variables A_(tp)~k and other parameters,so it is usually viable to determine A_(tp)~k and other parameters using a large number of experimental values.We applied this method to determine twenty-five A_(tp)~k of Yb~(3+) in GdTaO_4.The calculated and experiment energy lifetimes,experimental and calculated emission spectrum are very consistent,indicating that it is viable to obtain the transition intensity parameters of rare-earth ions in solids by a full profile fitting to the ions' emission spectrum.The calculated emission cross sections of Yb~(3+):GdTaO_4 also indicate that the F-L formula gives larger values in the wavelength range with reabsorption. 相似文献
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采用提拉法成功生长出了优质的Cr,Tm,Ho∶ YAG晶体,并对其光谱及激光性能进行了研究.测量了晶体在350~2700 nm波段内的吸收光谱.用450 nm激光激发,测量了晶体的稳态和瞬态荧光光谱,拟合得到2.1 μm激光上能级的寿命为10.65 ms.用F-L公式计算了晶体在2.1 μm处的发射截面为6.92×10-20 cm2,并与其他Ho3+掺杂的激光晶体进行了对比.采用氙灯泵浦Cr,Tm,Ho∶ YAG晶体棒,实现2.1 μm的脉冲输出.在3 Hz和10 Hz时的激光阈值分别为33.11 J和33.88 J,斜效率均为4.5;,比市售成熟的激光棒的激光输出效率更高. 相似文献
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为探索新型激光材料,采用高温固相反应法合成了(1at;) Nd∶ YTaO4多晶粉末,研究了其结构与发光性质.利用Rietveld方法对样品的X射线衍射谱进行精修得到晶胞参数、原子坐标等.测试了样品8K温度下的激发光谱以及8K和室温下808 nm激发的荧光光谱,对发光谱峰进行了指认,获得了Nd3+在YTaO4中的晶场能级分裂.结果表明,Nd3++的4 F3/2→4I11/2跃迁的发射截面为28.4×10-20 cm2,荧光寿命为155μs.较小的发射截面和较长的能级寿命表明Nd∶YTaO4是一种很有希望的激光二极管抽运的调Q激光材料. 相似文献
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采用提拉法生长了直径为136mm的Nd3+:GGG单晶,通过X射线衍射和X射线荧光对晶体的结构、成分沿生长方向和径向的变化进行了测试分析.结果表明单胞晶格参数沿晶体的生长方向和径向均逐步变大,平均变化率分别为3.1×10-6(A)/ mm、1.3×10-5(A)/mm;沿着晶体的生长方向,Nd和Gd组分按指数函数规律逐步增加,而Ga组分则按高斯函数逐渐减小.沿晶体径向从内到外,Nd、Gd组分按线性规律逐渐增大,其变化率分别为0.0014 at;/ mm、0.00924 at;/ mm,Ga组分则按线性规律减小,变化率为-0.0117 at;/ mm.这些变化主要是由于Nd3+的分凝效应、Ga挥发所导致. 相似文献
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GdTaO4和LuTaO4是具有快发光衰减的新型重闪烁体。采用全谱拟合方法拟合了808 nm 激光二极管(LD)激发的M相Nd∶GdTaO4和M′相Nd∶LuTaO4的光致发光谱,给出了它们的跃迁强度参数Akt,p。在808 nm 激光激发下,GdTaO4中Nd3+离子4F3/2能级的上下两个晶场子能级的粒子布居数比例接近1,而在Nd∶LuTaO4中则为1.30、1.41,表明在808 nm激光激发下,Nd3+的4F3/2两个晶场子能级间的无辐射弛豫速率与激发速率相近。通过给出的跃迁强度参数Akt,p计算了Judd-Ofelt跃迁强度参数Ωt,计算了Nd3+在GdTaO4、LuTaO4中的2P3/2跃迁几率,表明GdTaO4和LuTaO4中Nd3+的数百纳秒发光跃迁是由高的无辐射跃迁几率导致的快发光衰减。 相似文献
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采用提拉法生长出了尺寸为?30 mm×50 mm的Yb, Ho∶GdScO3晶体。通过X射线衍射得到了晶体的粉末衍射数据,使用GSAS软件进行了全谱拟合,得到了晶体的结构参数。测试了晶体的拉曼光谱,在100~700 cm-1观察到18个拉曼振动峰。对Yb, Ho∶GdScO3晶体的光谱特性进行了表征,并计算了Yb3+的吸收截面,其在940、975 nm处的吸收截面分别为0.31×10-20、0.42×10-20 cm2。采用Judd-Ofelt理论计算了Ho3+的跃迁强度参量Ωt,Ω4/Ω6值为2.04,并计算了辐射跃迁概率、能级寿命及荧光分支比等光谱参数。结果表明,Yb, Ho∶GdScO3晶体的发光性能良好,是一种有前景的2~3μm激光晶体候选材料。 相似文献