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Structures and luminescence properties of Yb3+ in the double perovskites Ba2YB'O6 (B'=Ta5+, Nb5+) phosphors 下载免费PDF全文
The Yb3+ doped Ba2YB'O6 (B'=Ta5+, Nb5+) were prepared by high temperature solid-state reaction method, their structures were determined by x-ray diffraction and refined by Rietveld method. The diffuse reflection absorption, excitation and emission spectra of Yb3+:Ba2YB'O6 (B'=,Ta5+, Nb5+) were measured at room temperature. Under the excitation of ultraviolet light, these phosphors exhibit broad charge transfer band emissions of TaO6 or NbO6 centre with large Stokes shift. The Yb3+ doped into these hosts are situated at Y3+ sites of cubic symmetry (Oh). The experimental energy levels of Yb3+ in Ba2YTaO6 and Ba2YNbO6 were determined by photoluminescence and diffuse reflection absorption spectra. Their wavefunctions and theoretical energy levels were obtained by diagonalising the Hamiltonian matrix. The experimental energy levels were fitted by Levenberg--Marquardt iteration algorithm to determine crystal field parameters. Then, the magnetic-pole transition line strengths of Yb3+:Ba2YB'O6(B'=Ta5+, Nb5+) from (2F5/2)Γ8- to the low-energy states were calculated. 相似文献
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平面位势流动的速度图方法,对于一些特殊流动,有特别明显的优点。本文利用张量分析工具,对任意流面上的位势流,建立速度图方程,为解决一些特殊流动问题,提供一个分析方法。 相似文献
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以查尔酮衍生物为前体, 与盐酸羟胺在碱性条件下反应制得7个3-(2-羟基-4,6-二甲氧基苯基)-5-芳基异噁唑啉化合物(2a~2g), 产物经红外光谱、核磁共振谱、质谱和元素分析表征. 抑菌活性研究结果表明, 化合物2d和2e对大肠杆菌、金黄色葡萄球菌、枯草杆菌和绿脓杆菌均有一定抑制作用, 其中化合物2e对大肠杆菌、金黄色葡萄球菌表现出极好的抑菌活性. 相似文献
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基于国产化的2倍迈克尔逊型干涉物镜组,优选配置0.5倍适配镜,对白光LED照明光源进行带通滤波参数的仿真估算和实验性能比较,构建了整套大视场白光干涉精密测量装置系统并进行了实验测试,通过白光干涉轴向响应实验曲线确定了中心波长。实验结果表明:通过光谱滤波获得了较为理想的白光干涉轴向响应曲线;系统的水平最大视场达到了14 mm;高度为2.04μm和20.43μm的标准台阶样品的测量结果分别为2.05μm和20.47μm,10次测量重复精度(标准差)分别为12 nm和16 nm。对粗糙度样板、微机电系统传感结构和半导体晶圆膜层进行了实测,表明所研制的系统装置在三维光学无损精密检测领域的应用具有可行性。 相似文献
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Method for fitting crystal field parameters and the energy level fitting for Yb3+ in crystal Sc2O3 下载免费PDF全文
<正>A method to compute the numerical derivative of eigenvalues of parameterized crystal field Hamiltonian matrix is given,based on the numerical derivatives the general iteration methods such as Levenberg-Marquardt,Newton method, and so on,can be used to solve crystal field parameters by fitting to experimental energy levels.With the numerical eigenvalue derivative,a detailed iteration algorithm to compute crystal field parameters by fitting experimental energy levels has also been described.This method is used to compute the crystal parameters of Yb~(3+) in Sc_2O_3 crystal, which is prepared by a co-precipitation method and whose structure was refined by Rietveld method.By fitting on the parameters of a simple overlap model of crystal field,the results show that the new method can fit the crystal field energy splitting with fast convergence and good stability. 相似文献
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