恒流电晕充电对聚四氟乙烯多孔薄膜驻极体驻极态的影响

利用常温下恒流和恒压电晕充电、充电后的等温表面电位衰减、热刺激放电和扫描电镜等实 验手段研究了恒流和恒压电晕充电技术对聚四氟乙烯多孔薄膜驻极体驻极态的影响.与恒压电晕充电相比较，恒流电晕充电时由于流过薄膜的电流恒定，增加了注入电荷在多孔结构厚度方向界面处的俘获概率，使沉积电荷密度上升，改善了驻极体的储电能力.然而，这些位于不同层深多孔界面处的俘获电荷在这类功能膜储存或使用过程中，经外激发从脱阱位置 以跳动（hopping）模式输运至背电极的路径相对缩短将导致脱阱电荷衰减较快. 关键词： 恒流电晕充电 聚四氟乙烯多孔膜 驻极体 电荷稳定性     

直流电弧等离子体炬的特性研究

介绍了局部热力学平衡下描述直流电弧等离子体炬的磁流体力学模型，采用数值模拟方法研 究了等离子体炬内等离子体的传热和流动特性、湍流对等离子体炬内等离子体特性的影响， 以及等离子体炬运行参数对等离子体特性的影响.将数值模拟结果与已有的实验结果进行了 比较. 关键词： 等离子体炬 磁流体力学 数值模拟     

活性聚苯乙烯膜诱导碳酸钙异相成核结晶

0引言生物矿物材料(如骨、牙齿、贝壳等)的优异性能[1]使得无机材料的仿生合成(又称有机模板合成)成为近年来研究的热点之一[2]。该合成技术的优点是,通过有机物分子与无机离子的相互作用,能够在温和的条件下合成出具有多级结构、特殊形貌和优异性能的有机/无机复合材料。CaCO3     

火焰原子吸收法测定化妆品中的铬

采用火焰原子吸收分光光度法测定了兰州市的一些市售化妆品中铬的含量。结果表明,方法检测限(3σ)为0.003 mg/L,回收率在94%~105%之间,相对标准差小于1.3%,方法简便快速;市售多数化妆品中的铬含量超过国家标准,须引起人们的注意。     

色谱法在三氯半乳蔗糖合成中的应用

采用薄层色谱和柱色谱法，选择优化展开体系，有效地分析了三氯半乳蔗糖中间体2，3，6，3′，4′-五氧乙酰蔗糖混合物，并证实该混合物中杂质为三苯甲醇，为三氯半乳蔗糖的合成研究取得了重要发现。     

Synthesis, Crystal Structure and Antibacterial Activity of Two Hydrazones Derived from 2-Fluorobenzhydrazide

Two new Schiff base benzoyl hydrazone compounds, C14H10FN3O3 (Ⅰ) and C14H10F2N2O (Ⅱ), have been synthesized and characterized by elemental analysis, IR, UV and X-ray single-crystal diffraction. Both compounds crystallize in monoclinic, space group P21/c with a = 7.0514(14), b = 25.928(5), c = 7.7099(15), β = 111.823(2)°, V = 1308.6(4)3, Z = 4, C14H10FN3O3, Mr = 287.25, Dc = 1.458 g/cm3, μ(MoKα) = 0.115 mm-1, F(000) = 592, the final R = 0.0841 and wR = 0.2489 for 1901 observed reflections (I > 2σ(I)) for I; a = 11.232(3), b =12.735(4), c = 8.612(2) , β = 90.869(3)°, V = 1231.7(6)3, Z = 4, C14H10F2N2O, Mr = 260.24, Dc = 1.403 g/cm3, μ(MoKα) = 0.111 mm-1, F(000) = 536, the final R = 0.0453 and wR = 0.1085 for 1317 observed reflections (I > 2σ(I)) for Ⅱ. The antibacterial activities of both compounds against two bacteria were first studied and one compound showed considerable antibacterial activity against K. Pneumonia and S. aureus.     

8×8APD阵列激光三维成像接收机研制

为了实现对目标的无扫描阵列激光三维成像并研究系统参数对三维成像距离分辨率的影响,研制了8×8 pixel激光三维成像接收机。接收机采用线性模式APD阵列,设计了模拟信号放大、阈值处理将回波光信号转换为数字信号后,利用FPGA设计实现64通道高精度阵列计时系统,实现了对目标的无扫描实时三维成像功能。首先对设计完成的三维成像接收机组成及成像原理进行了介绍,对三维成像接收机中APD探测器阵列信号的模拟处理和数字处理流程和实现方式进行了说明。随后分别对三维成像的核心FPGA计时系统及探测器整体进行了电子学测试和实验测试。测试结果表明,FPGA计时子系统的时间分辨率优于140 ps,三维成像系统整体距离分辨率在0.2 m左右。最后对分辨率的误差进行了分析,结果表明,激光回波强度波动是影响此接收机距离分辨率的最主要因素。     

Strong Correlation of Fluorescence Photons without Quantum Interference

It has been predicted that a driven three-level V atom can emit strongly correlated fluorescence photons in the presence of quantum interference. Here we examine the effects of quantum interference on the intensity correlation of fluorescence photons emitted from a driven three-level A atom. Unexpectedly, strong correlation occurs without quantum interference. The quantum interference tends to reduce the correlation function to a normal level. The essential difference between these two cases is traced to the different effects of quantum interference on coherent population trapping （OPT）. For the V atom, quantum interference and coherent excitation combine to lead to OPT. For the A atom, however, the quantum interference tends to spoil OPT while the coherent excitation induces the effect.     

利用可调谐半导体激光光谱技术对含尘气体中NH3的测量

利用可调谐半导体激光吸收光谱技术(TDLAS)并结合波长调制,在近红外波段1531.7nm处对常温常压下的NH3进行浓度测量.在10 m的长程吸收池内得到了25×10-6的浓度信号,并且在25×10-5-400×10-6浓度范围内二次谐波信号与浓度具有良好的线性关系.讨论了粉尘颗粒对于二次谐波信号的干扰,并提出了利用激光强度线性拟合解决颗粒对气体测量干扰的方法.     

Density functional theory study of neutral AlS_n(n=2-9) clusters

This paper investigates the geometrical structures and relative stabilities of neutral AlS n(n = 2-9) using the density functional theory.Structural optimisation and frequency analysis are performed at the B3LYP/6-311G(d) level.The ground state structures of the AlS n show that the sulfur atoms prefer not only to evenly distribute on both sides of the aluminum atom but also to form stable structures in AlS n clusters.The structures of pure S n are fundamentally changed due to the doping of the Al atom.The fragmentation energies and the second-order energy differences are calculated and discussed.Among neutral AlS n(n = 2-9) clusters,AlS 4 and AlS 6 are the most stable.