傅立叶变换红外光谱技术在超临界CO2作用聚合物体系中的应用

超临界CO₂（scCO₂）作为一种物理化学性质优良、具有高扩散速率及优良溶解性能的溶剂,在科学研究及工业生产中广受青睐。将scCO₂应用于聚合物体系中,CO₂ 与聚合物间特殊的相互作用有利于CO₂分子在聚合物中的吸附与扩散。同时通过CO₂的吸附及其对聚合物的溶胀和塑化作用,聚合物所处微观化学环境以及整体结构性质会发生一定的变化。由于傅立叶变换红外光谱（FTIR）技术能够有效地考察化学环境变化对分子结构造成的影响,这一表征技术在超临界CO₂作用体系中广为应用。本文主要选取了近年来利用FTIR技术考察scCO₂作用于聚合物体系的一些实例,从CO₂-聚合物相互作用机理,scCO₂对聚合物或生物大分子的加工过程的影响两方面,阐述了利用红外光谱技术在scCO₂作用体系中的应用以及前景。     

两个四硫富瓦烯分子正离子自由基TTF·^＋之间的共价吸引作用

使用MP2／6-311G方法得到了四硫富瓦烯自由基正离子二聚体（TTF·^＋ -TTF·^＋）能量极小点的结构．这显示这种正离子间的吸引作用存在．这种新的吸引作用是望远镜形状的20中心2电子分子间共价π/π键．这种共价π/π键的键能约为-21kcal·mol^-1,它被正离子间的库伦排斥作用掩盖．有负离子围绕的四硫富瓦烯自由基正离子二聚体（TTF·^＋ -TTF·^＋）体系是稳定的．     

University objectives and socioeconomic results: A multicriteria measuring of alignment

Universities develop technology transfer mechanisms as the tools required to undertake missions committed to the socioeconomic environment. In this work a new proposal to measure the extent to which the goals or strategic objectives of a university are aligned with the results obtained through its technology transfer mechanisms with the local community is presented. This will enable to perform a diagnosis, by comparing the situation sought by the University Management team (expected case) with the actual one that derives from the application of the plans that implement the technology transfer mechanisms (real case). To achieve this, two different Multicriteria Decision Analysis techniques e.g. Analytic Network Process (ANP) and Analytic Hierarchy Process (AHP) will be used. Both the methodology and the MCDA techniques proposed need to be explained and clarified to the different experts who collaborate in the study, hence the facilitating process, key to the whole procedure, will be analysed in detail.The model proposed in this study is applied to analyse the case of the National University of Colombia – Bogotá Campus. Findings show that the following questions can be answered: (i) How much importance is granted by the University Management to the objectives of the University? (ii) To what extent are the objectives of the university fulfilled by the technology transfer mechanisms to the socioeconomic environment? (iii) Are the objectives of the university aligned with the results achieved through the technology transfer mechanisms?     

人力资本存量计算方法的改进与试算

在Jorgenson和Fraumeni的理论框架下提出了一种计算人力资本存量的新方法,并且具体计算了我国2000年人力资本存量以及城乡人力资本存量.分析得出结论:我国人力资本总量巨大,而人均极少;城乡人均人力资本差距很大,且有进一步加大的趋势.     

Evolution of planetary boundary layer under different weather conditions,and its impact on aerosol concentrations

A field experiment was conducted in Tianjin,China from September 9-30,2010,focused on the evolution of Planetary Boundary Layer（PBL） and its impact on surface air pollutants.The experiment used three remote sensing instruments,wind profile radar（WPR）,microwave radiometer（MWR） and micro-pulse lidar（MPL）,to detect the vertical profiles of winds,temperature,and aerosol backscattering coefficient and to measure the vertical profiles of surface pollutants（aerosol,CO,SO₂,NO_x）,and also collected sonic anemometers data from a 255-m meteorological tower.Based on these measurements,the evolution of the PBL was estimated.The averaged PBL height was about 1000-1300 m during noon/afternoon-time, and 200-300 m during night-time.The PBL height and the aerosol concentrations were anti-correlated during clear and haze conditions.The averaged maximum PBL heights were 1.08 and 1.70 km while the averaged aerosol concentrations were 52 and 17μg/m³ under haze and clear sky conditions,respectively. The influence of aerosols and clouds on solar radiation was observed based on sonic anemometers data collected from the 255-m meteorological tower.The heat flux was found significantly decreased by haze （heavy pollution） or cloud,which tended to depress the development of PBL,while the repressed structure of PBL further weakened the diffusion of pollutants,leading to heavy pollution.This possible positive feedback cycle（more aerosols→lower PBL height→more aerosols） would induce an acceleration process for heavy ground pollution in megacities.     

海洋柔性结构涡激振动的流固耦合机理和响应

对近几十年来国内外在涡激振动的基础研究包括机理认识和动响应分析等方面的进展进行了论述,尤其针对海洋油气平台中的立管、隔水管等细长柔性结构的涡激振动.描述了涡激振动这种典型的非线性流固耦合现象所具有的特征,包括自激、自限制、展向相关、尾迹水动力与结构动力的流固耦合等及其主要影响参数.介绍了目前常用的结构响应预测方法和相关实验.通过讨论当前理论研究和实际工程中的热点问题,诸如多模态宽带振动、浮体运动与水下立管的耦合、响应抑制措施、双向振动、高雷诺数下的大尺度物理实验等,对今后该领域的研究方向进行了力所能及的展望.     

信息技术在美国大学物理课程中的应用——以美国俄亥俄州立大学为例

随着信息时代的来临,信息技术作为新型的教学工具逐步走进了校园,进入了课堂,成为现代化教学不可缺少的手段和教学改革的利器.文章根据作者在美国访学一年的经历,以美国俄亥俄州立大学为例,详细介绍信息技术在美国大学工科物理主要教学环节中的应用,并对中美大学在信息化建设方面的差异进行总结;通过比较可以看到,国内在信息技术常态化以及将信息技术深入融合到教学的具体环节方面和美国还存在有一定差距,需要进一步加强.     

Stochastic resonance in an over-damped linear oscillator

For an over-damped linear system subjected to both parametric excitation of colored noise and external excitation of periodically modulated noise, and in the case that the cross-correlation intensity between noises is a time-periodic function,we study the stochastic resonance(SR) in this paper. Using the Shapiro–Loginov formula, we acquire the exact expressions of the first-order and the second-order moments. By the stochastic averaging method, we obtain the analytical expression of the output signal-to-noise ratio(SNR). Meanwhile, we discuss the evolutions of the SNR with the signal frequency, noise intensity, correlation rate of noise, time period, and modulation frequency. We find a new bona fide SR. The evolution of the SNR with the signal frequency presents periodic oscillation, which is not observed in a conventional linear system. We obtain the conventional SR of the SNR with the noise intensity and the correlation rate of noise. We also obtain the SR in a wide sense, in which the evolution of the SNR with time period modulation frequency presents periodic oscillation. We find that the time-periodic modulation of the cross-correlation intensity between noises diversifies the stochastic resonance phenomena and makes this system possess richer dynamic behaviors.     

光电图像光照不均蜕化的校正及阈值分割方法*

分析了CCD获取的图像光照不均蜕化产生原因.针对光照不均蜕化的印刷电路板图像的具体情况,用同态滤波器在频域空间进行滤波而增强图像,从而改善图像的目标与背景对比度.讨论了最大类间方差法,给出了其优点.为了更好的分割图像,在此基础上,考虑两类间距与各类内聚性对图像分割的不同影响,提出了一种改进的最大类间方差法.最后对光照不均蜕化的PCB光电图像用不同方法进行了实验,结果表明改进方法能更好地分割图像.