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961.
Lianhe Shu 《Tetrahedron letters》2004,45(43):8115-8117
Asymmetric epoxidation of substituted cis-β-methylstyrenes using N-aryl substituted oxazolidinone-containing ketones as catalysts shows that substituents on the phenyl group of the olefin have significant positive effects on the enantioselectivity of the epoxidation, indicating a beneficial interaction between the phenyl group of the olefin and the phenyl group of the ketone catalyst. 相似文献
962.
Hashimoto T. Yoshinaga M. Ueda Y. Komazaki K. Asaoka K. Wang S. 《Journal of Thermal Analysis and Calorimetry》2002,69(3):909-917
The phase transitions of Ba2-xSrxIn2O5 were investigated with various thermal analyses and high-temperature X-ray diffraction. It was clarified that crystal structure
of Ba2-xSrxIn2O5 with x=0.0~0.4 varies from brownmillerite through distorted perovskite to another distorted perovskite with increase of temperature.
The phase transition from brownmillerite to distorted perovskite was revealed to be first order, whereas transition from distorted
perovskite to another one was second order. The specimen with x≥0.5 showed only one first order phase transition from brownmillerite to distorted perovskite. The phase diagram of Ba2-xSrxIn2O5 was established and existence of tricritical point at ~1100°C with x=0.4~0.5 was suggested.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
963.
Ion mobility spectrometry (IMS) is a proven technology for detection of vapor phase chemical warfare agents. The technology is suitable for field portable instrumentation due to its small size, high sensitivity, speed of analysis, and low power consumption. However, it suffers from a limited dynamic range and potential difficulties in identifying compounds in complex matrices. The use of gas chromatography (GC) coupled to IMS can overcome the difficulty of chemical identification in mixtures by separating the sample into individual components before detection. Using this approach, IMS technology has previously been adapted to detect biological aerosols using an open tube pyrolyzer and a short GC column (Py-GC-IMS). The open sample introduction tube of a Py-GC-IMS instrument would be a convenient configuration to accept aerosol particulates, and while viewed as needed for aerosol trapping, is not optimal for liquid chemical analyses. To examine the usefulness of an existing Py-GC-IMS system for analysis of chemicals in water, an existing open-port sample interface was replaced with a septum-equipped closed tube injector to contain analyte vapors resulting from liquid injection. Tributylphosphate (TBP) was used as a surrogate chemical warfare agent, and aqueous injections into both closed and open tube assemblies were performed. Sample introduction into the closed tube inlet was also accomplished using solid phase microextraction (SPME) preconcentration. The limit of detection for TBP using an open tube, closed tube, and closed tube configuration with SPME sample introduction was 0.980, 0.196, and 0.0098 mg/L, respectively. 相似文献
964.
965.
外加盐作用形成的正负离子表面活性剂双水相 总被引:1,自引:0,他引:1
癸基三乙基溴化铵-癸基磺酸钠(C10NE-C10SO3)等摩尔混合均相体系(即使在表面活性剂总浓度高达0.2 mol•L-1时仍然可形成稳定的均相溶液)在外加盐NaF、Na2SO4和Na3PO4的作用下可自发分离成两个水相(双水相).研究了该类双水相体系的形成、相行为及其对牛血清蛋白(BSA)的分配,并与普通的正负离子表面活性剂混合双水相体系进行了比较.结果表明,该类双水相体系克服了普通的正负离子表面活性剂混合双水相体系的一些不足,具有一些独特的优点.该类双水相体系的相行为可以通过外加盐进行调控,通过外加盐的种类来调控和优化BSA的分配行为.图1表2参8 相似文献
966.
967.
相转移催化法合成双3-苯丙烯酰基取代硫脲及双3-苯丙烯酰基取代胺衍生物 总被引:4,自引:0,他引:4
以3-苯丙烯酸为原料,经酰氯化,得到3-苯丙烯酰氯,在PEG-400为催化剂 的固液相转移催化条件下与硫氰酸铵及二胺类反应,一锅法制得双3-苯丙烯酰基 取代硫脲化合物。3-苯丙烯酰氯在PEG-600为催化剂的液液相转移催化条件下和 二胺类反应得到双-苯丙烯酰基取代胺化合物。反应条件温和、产率高。化合物经 元素分析、IR及^1H NMR证实。初步的生理活性研究表明,部分化合物具有良好的 抗炎活性。 相似文献
968.
在用琥珀酸二异辛酯磺酸钠(AOT)构建的具有长程有序结构的层状溶致液晶内, 用不同方式导入预制的亲油或亲水贵金属纳米粒子, 可得到纳米粒子分布在不同介观空间内的无机/有机杂合体. 依据小角X射线散射和偏光显微镜结果, 通过分析掺杂纳米粒子与液晶模板的相互作用, 对掺杂前后体系结构的变化及制得杂合体的稳定性进行了表征. 结果表明, 除考虑掺杂粒子与层状模板空间的匹配外, 体系中静电斥力、范德华引力和Helfrich涨落力之间的平衡是维持液晶结构稳定的基本条件. 相似文献
969.
制备了对丙烯直接气相环氧化具有较好催化性能的Ag-MoO3催化剂, 采用原位FT-IR技术研究了丙烯、环氧丙烷及丙烯+氧气的混合气在Ag和Ag-MoO3催化剂表面上的吸附及反应行为. 研究表明, 丙烯在Ag和Ag-MoO3催化剂表面上吸附后, 均不发生化学反应, 而环氧丙烷吸附后在较高温度下则发生开环和聚合反应直至产生积炭. 与Ag催化剂相比, 在Ag-MoO3催化剂上, MoO3的加入在降低催化剂活性的同时, 在一定程度上抑制了产物环氧丙烷的开环及深度反应, 使环氧丙烷的选择性提高. 另外, 在较低的反应温度和较短的滞留时间下, 环氧丙烷发生深度反应的程度明显降低. 相似文献
970.
A variety of quaternary and ternary systems of the type of dodecane/aliphatic alcohols/Na-dodecyl sulphate/water or a water-replacing component (formamide, ethylene glycol, propylene glycol, propylene carbonate, dimethylsulfoxide, acetonitrile) were subjected to a comparative analysis of microemulsification. The compositions of the systems of the type of oil/surfactant/cosurfactant/water or nonaqueous liquid were changed with respect to surfactant (Na-dodecyl sulfate and triton X 114) concentration, cosurfactant (homologous aliphatic alcohols) concentration and mixing ratio of water and water-replacing component. The appertaining phase diagrams were plotted and compared with those of aqueous systems.The experimental results suggest that the phase regions, which are designated as nonaqueous microemulsions, probably represent, not only microemulsions in the usual sense, but a separate kind of mixed phase whose microstructure is examined by special studies. Analogously to aqueous microemulsion systems, transparency and spontaneous formation of homogeneous multicomponent systems cannot serve as the sole criteria for waterless microemulsion formation. But they are important guiding properties of microemulsion formation in multicomponent systems.The variety of components involved in the chemical composition and the current insufficient knowledge do not permit to generally decide whether nonaqueous systems can be assigned to microemulsions or to molecular solutions. For clarifying this problem a detailed examination of the miscibility behavior, especially that of binary systems as a function of temperature, and the role that surfactant and cosurfactant play in the formation of homogeneous systems will be necessary. 相似文献