几种N-取代马来酰胺酸辅酶模型的核磁共振研究

我们对8种N-取代马来酰胺酸辅酶模型与不同类型的亲核试剂反应后生成的产物进行了¹H、¹³C NMR的研究, 测得¹H、¹³C谱化学位移,研 究探讨其规律性, 并测试了IR谱和元素分析.     

拟亚纯映射的充满圆

该文用较简明的方法讨论了平面上K 拟亚纯映射在\{lim[DD(X]r→∞[DD)]\}[TX-][SX(]S(r,f)[]lgr[SX)]=∞ 条件下及有限正级K 拟亚纯映射存在充满圆序列, 同时也证明了零级K 拟亚纯映射的最大型Borel方向及有限正级Borel方向上存在充满圆序列.     

二取双恶唑啉衍生物的合成及其在不对称环丙烷化反应中的应用

通过双亚氨酸盐酸盐与手性胺醇反应简便地合成了二取代双恶唑啉衍生物, 并将其与铜配位运用于重氮醋酸酯对烯烃的不对称环丙化反应, 不对称诱导反应光学产物收率最高达95%d.e.     

DISTRIBUTION OF THE（0，∞）ACCUMULATIVE LINES OF MEROMORPHIC FUNCTIONS

Suppose that f(z)is a meromorphic function of order λ（0<λ<+∞）and of lower order μ in the plane.Let ρ be a positive number such that μ≤ρ≤λ.(1)If f^(l)(z)(0≤l<+∞）has p(1≤p<+∞）finite nonzero deficient valnes αi(i=1,…，p)with deficiencies δ（αi,f^(l)),then f(z)has a (0,∞）accumulative line of order ≥ρin any angular domain whose vertex is at the origin and whose magnitude is larger than max(π/ρ，2π-4/ρ ∑i=1^p arcsin √δ（αi,f^(l))/2).(2)If f(z) has only p(0<p<+∞）（0,∞）,accumulative lines of order≥ρ：arg z=θk(0≤θ1<θ2<…<θp<2π，θp+1=θ1+2π）,then λ≤π/ω，where ω=min I≤k≤p(θk+1-θk),provided that f^(l)(z)(0≤l<+∞）has a finite nonzero deficient value.     

关于亚纯函数及其导数的唯一性

1 引言和主要结果 设f(z)是复平面上的亚纯函数,T(r.f)、N(r,f)、m(r,f)、…等是值分布理论中通常的符号(参阅[8]),文章中T(r,a)=o(T(r,f))表示当r→∞时可能除去至多一有限测度集后成立。 设f(z)、g(z)为复平面上的亚纯函数,a为任意复数,我们说a 是f(z)和g(z)的分机位:如果f(z)-a与g(z)-a有相同的零点.特别称a是f(z)和g(z)的CM-分担值(Coun-ting Multiplicities):如果 f(z)-a与g(z)-a具有相同的零点,且重数相同;称a是f(z)和     

Effects of barium on the nonlinear electrical characteristics and dielectric properties of SnO2-based varistors

The effects of barium on electrical and dielectric properties of the SnO_2·Co_2O_3·Ta_2O_5 varistor system sintered at 1250℃ for 60min were investigated. It is found that barium significantly improves the nonlinear properties. The breakdown electrical field increases from 378.0 to 2834.5V/mm, relative dielectric constant (at 1kHz) falls from 1206 to 161 and the resistivity (at 1kHz) rises from 60.3 to 1146.5kΩ·cm with an increase of BaCO_3 concentration from 0mol% to 1.00mol%. The sample with 1.00mol% barium has the best nonlinear electrical property and the highest nonlinear coefficient (α=29.2). A modified defect barrier model is introduced to illustrate the grain-boundary barrier formation of barium-doped SnO_{2}-based varistors.     

Low-threshold, high-efficiency, high-repetition-rate optical parametric generator based on periodically poled LiNbO3

We report a high-repetition-rate optical parametric generator (OPG) with a periodically poled lithium niobate (PPLN) crystal pumped by an acousto-optically Q-switched CW-diode-end-pumped Nd:YVO_4 laser. For the maximum 1064nm pump power of 970mW, the maximum conversion efficiency is 32.9% under the conditions of 250℃, 1064nm pulse repetition rate of 22.6kHz and pulse width of 12ns, and the PPLN OPG threshold in the collinear case is less than 23.7μJ. The output power increases with the increase of the crystal temperature. The 1485－1553nm signal wave and 3383－3754nm idler wave are obtained by changing the temperature and the angle of the PPLN crystal.     

Mid—Infrared Optical Parametric Oscillator Based on All—Solid—State—Pumped Periodically Poled LiNbO

We report the tunable mid-infrared generation with a periodically poled LinbO3(PPLN).Using an all-solid-state pumped Nd:YVO4 laser as the pump source and a PPLN nonlinear crystal with grating periods of 28.2-30.8μm,we have achieved wavelength conversion in the 2.90-4.05μm spectral range by period tuning.The use of confocal cavity design has brought a compact,all-solid-state configuration with an average output powers of idler up to -200mW.The maximum power of 277mW was obtained at the wavelength of 3.35um.