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Effects of barium on the nonlinear electrical characteristics and dielectric properties of SnO2-based varistors 下载免费PDF全文
The effects of barium on electrical and dielectric properties of the SnO_2·Co_2O_3·Ta_2O_5 varistor system sintered at 1250℃ for 60min were investigated. It is found that barium significantly improves the nonlinear properties. The breakdown electrical field increases from 378.0 to 2834.5V/mm, relative dielectric constant (at 1kHz) falls from 1206 to 161 and the resistivity (at 1kHz) rises from 60.3 to 1146.5kΩ·cm with an increase of BaCO_3 concentration from 0mol% to 1.00mol%. The sample with 1.00mol% barium has the best nonlinear electrical property and the highest nonlinear coefficient (α=29.2). A modified defect barrier model is introduced to illustrate the grain-boundary barrier formation of barium-doped SnO_{2}-based varistors. 相似文献
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Phase Transition and High Piezoactivity of Sb Doped (Na0.53K0.435Li0.035)Nb0.94Ta0.06 O3 Lead-Free Ceramics 下载免费PDF全文
Lead-free piezoelectric ceramics with the composition of (Na0.53K0.435Li0.035)Nb0.94Ta0.06 O3 (NKLNST) axe synthesized by a conventional solid-state sintering process. An MPB-like region between orthorhombic and pseudocubic phases is found in this system. The density, piezoelectric and dielectric properties axe enhanced greatly in this region. A composition (Na0.53K0.435Li0.035)(Nb0.94Ta0.06)O3 is found to have excellent electrical properties: d33 = 320pC/N, kp= 49% and kt =43%, as well as relatively low loss, tan δ=4.2%, and high relative density higher than 96%, which indicate that this ceramics is a promising lead-free piezoceramics replacing for lead zirconate titanate. 相似文献
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(Na0.52K0.44Li0.04)Nb0.9-xSbxTa0.1O3 Lead-Free Piezoelectric Ceramics with High Performance and High Curie Temperature 下载免费PDF全文
(Na0.52K0.44Li0.04)Nb0.9-x Sbx Ta0.1O3 lead-free piezoelectric ceramics are prepared by a solid-state reaction method. With increasing Sb content, the transition temperature from orthorhombic to tetragonal polymorphic phase decreased. A composition (Na0.52K0.44Li0.04)Nb0.863Sb0.037Ta0.1O3 is found to possess excellent piezo- electric and electromechanical performances (d33 = 306pC/N, kp =48%, and kt=50%), and high Curie temperature (Tc = 320 ℃). These results indicate that (Na0.52K0.44Li0.04)Nb0.863Sb0.037 Ta0.1O3 is a promising lead-free piezoceramics replacement for lead zirconate titanate. 相似文献
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Phase Transition and High Piezoactivity of Sr Doped Lead-Free (Na0.53K0.422Li0.048) (Nb0.89Sb0.06Wa0.05)O3 Ceramics 下载免费PDF全文
Lead-free piezoelectric ceramics (Na0.53K0.422Li0.048 ) (Nb0.89Sb0.06 Ta0.05 )03 (NKLNST) + x tool SrCO3 are prepared by conventional solid state sintering method. The specimens with pure perovskite structure show tetragonal phase at x 〈 0.01, and become pseudo-cubic phase at x 〉 0.02. A lattice parameter discontinuity is found in the specimens with 0.004 〈 x 〈 0.0075, along with a great improvement in piezoactivity. The 0.004 mol SrCO3 added NKLNST ceramics possesses outstanding performances of kp = 0.53, kt = 0.26, and d33=309 pC/N. Moreover, the Sr^2+ modification inhibits the gra/n growth, decreases the Curie temperature, and induces a diffuse phase transition. 相似文献
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研究了Sr对新型(Co, Nb)掺杂SnO2压敏材料微观结构和电学性质的影响.当SrCO 3的含量从零增加到1.50mol%时,(Co, Nb)掺杂SnO2压敏电阻的击穿电压从240V/mm猛增 到1482V/mm.样品的微观结构分析发现, 当SrCO3的含量从零增加到1.50 mol%时, SnO2的晶粒尺寸迅速减小.晶界势垒高度测量揭示,SnO2晶粒尺寸的迅速减小是击穿
关键词:
碳酸锶
二氧化锡
势垒
电学非线性 相似文献
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利用直流电电化学沉积法将生长碳纳米管(CNT)的催化剂镍均匀地附着在石墨电极(GE)表面,再通过化学气相沉积法制备得到原位生长碳纳米管化学修饰电极(GSCNT-CME).电化学沉积的金属镍和所制备的修饰电极分别用光学显微镜、扫描电子显微镜(SEM)和电子能谱(EDX)进行表征,所得修饰电极的电化学性能用[Fe(CN)6]3-/[Fe(CN)6]4-溶液进行表征.结果表明:经直流电电化学沉积,可以在石墨电极表面沉积一层致密的金属镍,能生长出管径均匀的碳纳米管,所制得的修饰电极具有良好的电化学响应灵敏性和准确性,可在电化学检测领域发挥重要的应用. 相似文献
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研究了Sr对新型(Co, Nb)掺杂SnO2压敏材料微观结构和电学性质的影响.当SrCO3的含量从零增加到1.50mol%时,(Co, Nb)掺杂SnO2压敏电阻的击穿电压从240V/mm猛增到1482V/mm.样品的微观结构分析发现, 当SrCO3的含量从零增加到1.50 mol%时, SnO2的晶粒尺寸迅速减小.晶界势垒高度测量揭示,SnO2晶粒尺寸的迅速减小是击穿电压急剧增高的主要原因.对Sr含量增加引起SnO2晶粒减小的根源进行了解释.掺杂1.50 mol% SrCO3的SnO2压敏电阻非线性系数为21.4,击穿电压高达1482V/mm. 相似文献
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原子核物理中α衰变是典型的量子隧道效应,势垒隧穿模型能够很好地解释α衰变的实验规律,包含了丰富的物理思想和巧妙的数学处理方法.但势垒隧穿理论模型的数学推导和计算复杂,为了避开繁琐的数学计算,直观地体现物理思想,引入Mathematica数学软件来开展α衰变势垒隧穿模型的教学.通过Mathematica软件强大的符号和数值计算功能,良好的人机交互性,可以方便地完成复杂的数学推导和数值计算,形象地给出不同势垒的理论计算结果,动态展示出α衰变势垒隧穿的物理图像.在核物理教学中引入数学软件,可有效地提高课堂教学的效率,培养学生自主学习能力,提升教学效果. 相似文献
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