防紫外线伞ATR-OMNI采样器的FTIR分析

本实验使用OMNI采样器，直接对伞面内外进行单反射ATR的分析，快速、简便、不破坏样品，得到分辨率很好的红外图谱，再配合红外谱库的谱图检索，可以分别得到匹配率95％以上的尼龙－6和聚酯型聚氨酯的分析结果。     

THE STUDY OF SERS EFFECT AND ADSORPTION PROPERTY ON Cu SURFACE FOR PNBA

With different amounts of KCl added in the PNBA(p- nitro benzoic acid) aqueous solution, the factors affecting the SERS (Surface Enhanced Raman Scattering) are studied systematically on the surface of Copper. The results show that in PNBA aqueous solution the occurrence of SERS effect stongly depends on the existence of Cl^-. The amount of KCl added affects not only the emergence and the intensity of SERS effect, but also the adsorption properties such as the adsorption manner,etc.     

等离子体噻吩聚合膜的研究及I+注入的掺杂效应

以噻吩为单体,在等离子体环境中聚合成致密的有机膜。利用Rutherford背散射(RB2S)和质子弹性反冲(ERD)、傅里叶红外谱(FTIR)测定了膜的成分和结构;从近红外-可见-紫外光的反射和透射谱,运用传递矩阵方法研究了膜的光学性质;此外,还探讨了24keV的I⁺离子束的注入对等离子体噻吩聚合膜的掺杂效应。结果表明,注入层内电荷载流子的输运机理可用Mott的可变自由程跳跃(VRH)理论给以解释。 关键词：     

冈村枝管藻孢子体的形态和超微结构

从日本冲绳采回枝管藻，用毛细管将成熟多室孢子囊挑出，在试验室条件下培养，可长成孢子体．用光学显微镜和透射电子显微镜观察发现：孢子释放后形成盘状体附着在基质上，念珠状同化丝从盘状体中间分生．同化丝可从中间部位产生分支，多室孢子囊位于部分同化丝的近端部；同化丝大量产生后基部细胞平行排列，中空，形成假薄壁组织，而后孢子体进入伸长生长阶段；在每个盘状体细胞和同化丝细胞中都有多个色素体和线粒体，蛋白核突出于色素体其他部分，类脂体存在于类囊体中；在同化丝的细胞壁上存在缺口；对同化纤毛而言，色素体和线粒体数量少，紧贴细胞膜，质壁分离严重，在细胞壁上存在“通道”．     

Andreev-Fano Effect in a Hybrid Normal-Metal/Superconductor Interferometer

We report on a new type of Fano effect, named as Andreev-Fano effect, in a hybrid normal-metal/supeeconductor (N/S) interferometer embedded with a quantum dot. Compared with the conventional Fano effect, AndreevFano effect has some new features related to the characteristics of Andreev reflection. In the Iinear response regime, the line shape is the square of the conventional Fano shape, while in the nonlinear transport, a sharp resonant structure is superposed on an expanded interference pattern, which is qualitatively different from the conventional Fano effect. The phase dependence of the hybrid N/S interferometer is also distinguished from those of all-N or all-S interferometers.     

用于ψ＇→γ＇xcJ→γ＇γJ/ψ过程中多极分析的产生子

为了实验研究粲偶素ψ＇级联衰变过程ψ＇→γ＇xcJ→γ＇γJ/ψ,一个用于正确描述全部末态角分布的产生子是必要的．可以通过分析角分布的关联来确定这一过程的多极展开参数（或者等效的螺旋度振幅），而从中可以知道高阶电磁多极矩和相对论修正的贡献，同时可以检验ψ＇是不是ψ＇（2S）和ψ＇（1D）的混合．介绍了一个能完全描述这一过程的角分布的产生子，同时讨论了测量多极参数的测量方法．这些都可以被用在BESⅢ或者CLEOc的分析当中．     

The Properties of Light Pressure Force with High Order in Laser Fields

1　Ｉｎｔｒｏｄｕｃｔｉｏｎ　　Ｉｎｒｅｃｅｎｔｙｅａｒｓ,ｂｏｔｈｔｈｅｔｈｅｏｒｅｔｉｃａｌａｎｄｅｘｐｅｒｉｍｅｎｔａｌｉｎｖｅｓｔｉｇａｔｉｏｎｓｏｎｌａｓｅｒｃｏｏｌｉｎｇａｎｄｔｒａｐｐｉｎｇｈａｖｅｂｅｃｏｍｅｏｎｅｏｆｔｈｅｍａｊｏｒｆｉｅｌｄｓｉｎａｔｏｍｉｃ,ｍｏｌｅｃｕｌａｒａｎｄｏｐｔｉｃａｌ ｐｈｙｓｉｃｓ[1～ 8] .Ｔｈｅｄｅｖｅｌｏｐｍｅｎｔｏｆｌａｓｅｒｃｏｏｌｉｎｇａｎｄｔｒａｐｐｉｎｇｔｅｃｈｎｏｌｏｇｙｉｓｉｍｐｏｒｔａｎｔｆｏｒｔｈｅａｐｐｌｉｃａｔｉｏｎｓｓｕ…     

Effect of end groups on complexation kinetics between cyclodextrins and guest polymers

α‐Cyclodextrin (α‐CD) has been complexed with various poly(ethylene glycol) (PEG) derivatives in aqueous solution. It has been found that the end groups of PEG derivatives affect the complexation kinetics greatly, but have only a little influence on the thermodynamic behavior. By increasing the hydrophobicity of end groups, the complexation speeds up rapidly. On the other hand, the bulky end groups slow down the threading of polymeric guests into the cavity of CD. By changing the hydrophobicity and the size of end groups, the complexation rate can be adjusted in the range of several orders of magnitudes, which should be quite useful in the design of new supramolecular systems. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2050–2057, 2006     

Sn-C60薄膜的紫外吸收光谱和X-射线衍射谱分析

对Sn-C60薄膜进行紫外可见光吸收，X-射线衍射和扫描电镜的测定结果显示，薄膜样品紫外可见光吸收的两个短波段吸收峰比纯C60薄膜的吸收峰显著下降，说明Sn-C60薄膜的电子光吸收跃迁为间接跃迁，能带中有杂质能级的存在；样品的X射线衍射峰则对应于面心立方结构；扫描电镜结果显示薄膜为纳米级颗粒组成。     

Effect of the Electron-LO-Phonon Coupling on an Exciton Quantum Dot

The influence of the electron-LO-phonon coupling on energy spectrum of the low-lying states ofan exciton inparabolic quantum dots is investigated as a function of dot size. Calculations are made by using the method of few-bodyphysics within the effective-mass approximation. A considerable decrease of the energy in the stronger confinement rangeis found for the low-lying states of an exciton in quantum dots, which results from the confinement of electron-phononcoupling.