Experimental study of resistive bistability in metal oxide junctions

We have studied resistive bistability (memory) effects in junctions based on metal oxides, with a focus on sample-to-sample reproducibility, which is necessary for the use of such junctions as crosspoint devices of hybrid CMOS/nanoelectronic circuits. Few-nm-thick layers of NbO _x , CuO _x and TiO _x have been formed by thermal and plasma oxidation, at various deposition and oxidation conditions, both with and without rapid thermal post-annealing. The resistive bistability effect has been observed for all these materials, with particularly high endurance (over 10³ switching cycles) obtained for single-layer TiO₂ junctions, and the best reproducibility reached for multi-layer junctions of the same material. Fabrication optimization has allowed us to improve the OFF/ON resistance ratio to about 10³, but the sample-to-sample reproducibility is so far lower than that required for large-scale integration.     

Dy3+激活无水芒硝在真空紫外光激发下的发光性质

在空气中900℃温度下,将纯天然无水芒硝( Na2 SO4)和DyF3的混合粉末加热25 min,制备了Na2SO4:Dy3+新型发光材料.通过同步辐射研究了NaSO4:Dy3+的发光性质.并测量了在室温中真空紫外-紫外光下的发射和激发光谱.根据发射光谱得到了不同Dy3+掺杂浓度和不同激发下发光的黄蓝比(Y/B)是不同的.通过监测黄色发光得到的激发光谱,分别由Dy3+,4f9→4f85d跃迁(172 nm)、O2--Tm3+之间的电荷转移带(165 nm)引起的强激发谱和基质吸收(138,245 nm)、对应Dy3+,6 H15/2→4 D7/2,6H15/2→6 P3/2,6 H15/2→6P7/2跃迁(299,325,351nm)引起的弱激发谱组成.     

基于正交投影散度的高光谱遥感波段选择算法

由于高光谱数据的海量高维特征,对其进行降维处理成为高光谱遥感研究的一个重要问题.波段选择算法由于能够有效地保留原始数据的信息,在高光谱数据降维及后续的遥感识别与分类等方面具有明显的优越性.文章提出了一种基于正交投影散度(OPD)的波段选择方法,该方法继承了正交子空间投影(OSP)算法的特点,通过把原始数据投影到特征空间...     

纳米银粒子表面增强拉曼光谱在宠物饲料中三聚氰胺的速测研究

研究将制备的纳米银粒子作为表面增强拉曼光谱的增强试剂,实现对宠物饲料中三聚氰胺的快速定性定量分析。以709与1542cm-1处拉曼位移作为定性依据,以1149cm-1峰强度作为归一化标准,在1.0～10.0mg·kg-1浓度范围实现定量计算,检测限0.5mg·kg-1。研究发现,纳米银粒子对三聚氰胺具有较强的拉曼增强效应,特征峰信号强度与纳米银粒子加入时间,溶液涡旋强度有很大的关系,同时也受提取溶剂的种类、提取方式及样品加入量的影响。本方法中每个样品5min内完成分析,与现有方法相比,快速简便,对宠物饲料中三聚氰胺实现现场、快速检测。     

光辐射吸收材料表面形貌与吸收率关系研究

光辐射吸收材料不同的表面形貌对入射光具有不同的多重反射吸收效果,对光辐射的吸收有较大的影响,合适的表面形貌可以提高光辐射有效吸收率.本文通过光线追迹的方法对V形表面、正弦表面、具有正态倾角(平均倾角)分布的表面以及具有正态高度分布的表面进行模拟, 分析了这四种表面对光辐射吸收率的提升效果及其入射角特性.通过倾角分布分析,得出不同表面形貌提升吸收率共同的必要条件,即倾角中心分布至少大于30°,并指出V形表面在正入射时对吸收率提升的优越性. 关键词： 光吸收材料 表面形貌 吸收率 表面倾角分布     

Si(001)衬底上分子束外延生长Ge0.975Sn0.025合金薄膜

使用低、高温两步法生长的高质量Ge薄膜作为缓冲层,在Si(001)衬底上采用分子束外延法生长出Ge_0.975Sn_0.025合金薄膜.X射线双晶衍射和卢瑟福背散射谱等测试结果表明,Ge_0.975Sn_0.025合金薄膜具有很好的晶体质量,并且没有发生Sn表面分凝.另外,Ge_0.975Sn_0.025合金薄膜在500 ℃下具有很好的热稳定性,有望在Si基光电器件中得到应用. 关键词： GeSn Ge 分子束外延 外延生长     

In0.3Co4Sb12-xSex 方钴矿热电材料的制备和热电性能

用熔融退火结合放电等离子烧结法制备了In_0.3Co₄Sb_12-xSe_x(x=0—0.3)方钴矿热电材料,探讨了In的存在形式,系统研究了Se掺杂量对结构和热电性能的影响.结果表明:In可以填充到方钴矿二十面体空洞处,过量In在晶界处形成InSb第二相,Se对Sb的置换使晶格常数减小,In填充上限降低;In_0.3Co₄Sb_12-xSe_x样品呈n型传导,随着Se掺杂量的增大,载流子浓度降低,电导率下降,Seebeck系数增大,功率因子有所降低;由于在结构中引入了质量波动及晶格畸变,适量的Se掺杂可以大幅降低材料晶格热导率;样品In_0.3Co₄Sb₁₂和In_0.3Co₄Sb_11.95Se_0.05的最大ZT值均达到1.0以上. 关键词： 掺杂 填充式方钴矿 热电性能     

高功率固体激光装置光学元件"缺陷"分布与光束近场质量的定量关系研究

基于光传输理论,获得了弱调制情况下光学元件"缺陷"分布功率谱密度 (power spectral density, PSD)与光束近场强度分布PSD之间的定量关系;通过数值模拟的方法,针对高功率固体激光装置的基本单元(线性介质、非线性介质以及空间滤波器)对获得的理论关系进行了具体的验证和讨论.研究结果表明,弱调制下,只存在振幅型或位相型"缺陷"分布时,光学元件"缺陷"分布PSD与光束近场强度分布PSD通过近场强度分布PSD的系统传输因子联系,传输因子与系统的构型和运行状态有关.研究结果为光学元件"缺陷"分布指标的获得提供了理论基础,对高功率固体激光装置负载能力的提升起到了一定的指导作用. 关键词： 缺陷分布 功率谱密度 光学元件 光束质量     

A flexible fast 3D profilometry based on modulation measurement

This paper proposes a flexible fast profilometry based on modulation measurement. Two orthogonal gratings through a beam splitter are vertically projected on an object surface, and the measured object is placed between the imaging planes of the two gratings. Then the image of the object surface modulated by the orthogonal gratings can be obtained by a CCD camera in the same direction as the grating projection. This image is processed by the operations consisting of performing the Fourier transform, spatial frequency filtering and inverse Fourier transform. Using the modulation distributions of two grating patterns, we can reconstruct the 3D shape of the object. In the measurement process, we only need to capture one fringe pattern, so it is faster than the MMP and remains the advantages of it. In the article, the principle of this method, the setup of the measurement system, some simulations and primary experiment results are given. The simulative and experimental result proves it can restore the 3D shape of the complex object fast and comparatively accurate. Because only one fringe pattern is needed in the testing, our method has a promising extensive application prospect in real-time acquiring and dynamic measurement of 3D data of complex objects.     

Tunable nonlinear absorption of hydrogenated nanocrystalline silicon

Nonlinear absorption (NLA) of hydrogenated nanocrystalline silicon (nc-Si:H) has been investigated through the open aperture Z-scan method for the photon energy of the incident irradiance slightly less than the bandgap of the sample. NLA responses have been observed to be highly sensitive to the wavelength and intensity of the incident irradiance as well as to the bandgap of the sample, indicating greatly tunable NLA of nc-Si:H. The band tail of nc-Si:H appears to play a crucial role in such NLA responses.