全文获取类型
收费全文 | 26724篇 |
免费 | 4433篇 |
国内免费 | 4329篇 |
专业分类
化学 | 20767篇 |
晶体学 | 439篇 |
力学 | 1324篇 |
综合类 | 319篇 |
数学 | 3062篇 |
物理学 | 9575篇 |
出版年
2024年 | 57篇 |
2023年 | 474篇 |
2022年 | 667篇 |
2021年 | 924篇 |
2020年 | 1075篇 |
2019年 | 1120篇 |
2018年 | 926篇 |
2017年 | 1006篇 |
2016年 | 1274篇 |
2015年 | 1303篇 |
2014年 | 1658篇 |
2013年 | 2081篇 |
2012年 | 2485篇 |
2011年 | 2600篇 |
2010年 | 2009篇 |
2009年 | 1892篇 |
2008年 | 2019篇 |
2007年 | 1846篇 |
2006年 | 1750篇 |
2005年 | 1405篇 |
2004年 | 1038篇 |
2003年 | 821篇 |
2002年 | 780篇 |
2001年 | 683篇 |
2000年 | 606篇 |
1999年 | 510篇 |
1998年 | 356篇 |
1997年 | 318篇 |
1996年 | 273篇 |
1995年 | 261篇 |
1994年 | 236篇 |
1993年 | 172篇 |
1992年 | 149篇 |
1991年 | 139篇 |
1990年 | 131篇 |
1989年 | 97篇 |
1988年 | 72篇 |
1987年 | 55篇 |
1986年 | 62篇 |
1985年 | 51篇 |
1984年 | 19篇 |
1983年 | 20篇 |
1982年 | 18篇 |
1981年 | 7篇 |
1980年 | 8篇 |
1979年 | 8篇 |
1973年 | 2篇 |
1971年 | 4篇 |
1957年 | 4篇 |
1936年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 125 毫秒
961.
High-power polarization-division-multiplexing (PDM) systems or functional modules, such as self-phase-modulation (SPM)-based all-optical regenerators, cross-phase-modulation (XPM)-based wavelength convertors or format convertors, all-optical logical gate, and so on, may suffer from the effects of pattern dependence. Such effects are experimentally investigated using relative time delay variation between bit sequences with orthogonal polarization states in a 2 × 10.65 Gb/s high-power on-off keying (OOK) PDM system. Eye-diagram-based signal-to-noise ratio (SNR) and bandwidth of broadened spectrum are measured and compared. An eye-diagram-based SNR fluctuation of up to 4 dB may occur as the delay changes. 相似文献
962.
The temperature fields and the energy dissipations of shape memory alloys during the stress-induced martensitic transformations are studied theoretically and experimentally. The effect of the loading rate is analyzed. It was found that the temperature field inside a shape memory alloy sample varies strongly in space and time. The increase rate of the temperature is given by the difference between the rate of the latent heat release and the rate of the heat convection and conduction. The notion and the rate dependence of the energy dissipation are discussed in connection with the stress–strain hysteresis, the entropy production, and the Clausius–Duhem inequality. 相似文献
963.
A comprehensive study on Raman spectroscopy with different excitation wavelengths, sample sizes, and sample shapes for optic phonons (OPs) and acoustic phonons (APs) in polar and non-polar nano-semiconductors has been performed. The study affirms that the finite size effect does not appear in the OPs of polar nano-semiconductors, while it exists in all other types of phonons. The absence of the FSE is confirmed to originate from the long-range Fr¨ohlich interaction and the breaking of translation symmetry. The result indicates that the Raman spectra of OPs cannot be used as a method to characterize the scale and crystalline property of polar nano-semiconductors. 相似文献
964.
Dirac equation in Kerr geometry was separated by Chandrasekhar in 1976. In the present paper, the radial parts of Dirac equation in Reissner-Nordström (RN) geometry are solved. We concentrate on two cases. The first one is that the energies of the waves are greater than the height of the potential barrier and the second one is that the waves hit on the potential barrier. In each case, the reflection and transmission coefficients and the wave function are computed. We compare the solutions with several parameters to show how the properties of the scattered wave depend on these parameters. 相似文献
965.
966.
Determination of hydroxysafflor yellow A in biological fluids of patients with traumatic brain injury by UPLC‐ESI‐MS/MS after injection of Xuebijing 下载免费PDF全文
Yong Guo Yang Wang Xi. Huang Huiying Lv Rong Fan Wei Huang Pingping Gan Wei Liu Kuipo Yan Zian Xia Jinfang Liu 《Biomedical chromatography : BMC》2014,28(8):1090-1095
A simple, novel, specific, rapid and reproducible ultra‐performance liquid chromatography electrospray ionization tandem mass spectrometry method has been developed and validated for the determination of hydroxysafflor yellow A (HSYA) in biological fluids (plasma, urine and cerebrospinal fluid) of patients with traumatic brain injury after intravenous injection of Xuebijing (XBJ). Liquid–liquid extraction was performed, and separation was carried out on an Acquity UPLC? BEH C18 column, with gradient elution using a mobile phase composed of methanol and 0.1% formic acid at a flow rate of 0.3 mL/min. A triple quadrupole tandem mass spectrometer with electrospray ionization was used for the detection of HSYA. The mass transition followed was m/z 611.0 → 491. The retention time was less than 3.0 min. The calibration curve was linear in the concentration range from 2 to 6125 ng/mL for cerebrospinal fluid, plasma and urine. The intra‐ and inter‐day precisions were <10%, and the relative standard deviation of recovery was <15% for HSYA in biological matrices. The method was successfully applied for the first time to quantify HSYA in the biological fluids (especially in cerebrospinal fluid) of patients with traumatic brain injury following intravenous administration of XBJ. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
967.
968.
969.
Experimental and numerical investigation of aramid fibre reinforced laminates subjected to low velocity impact 总被引:1,自引:0,他引:1
The low velocity impact performance of domestic aramid fibre reinforced laminates is investigated experimentally and numerically. Laminates with different thicknesses are impacted by drop-weight test machine under different impact energies. The time histories of impact force are recorded and ultrasonic C-scan technology is used to inspect the internal damage of the laminates. Numerical simulation is conducted using finite element method (FEM), taking into account both intralaminar and interlaminar damage. The intralaminar damage model is based on the continuum damage mechanics (CDM) approach, which consists of the strain-based Hashin failure criteria and the exponential damage evolution law, and considers the nonlinear shear behaviour of the material. The interlaminar damage is simulated by interface elements with cohesive zone model. The numerical results show good agreements with the experiments, thus verifying the validity of the presented numerical model. 相似文献
970.
Binhang Yan Pengcheng Xu Xuan Li Cliff Yi Guo Yong Jin Yi Cheng 《Plasma Chemistry and Plasma Processing》2012,32(6):1203-1214
Liquid hydrocarbons including n-hexane, cyclohexane and toluene are pyrolyzed in H2/Ar plasma to investigate the effects of feedstock properties and key operating conditions (e.g., the feedstock specific input power and residence time) on the reaction performance. The experiments verify that the non-aromatic hydrocarbons show better chemical reactivity than partially aromatic substances. Meanwhile, the straight-chain alkanes and cycloalkanes have better yields of ethylene during the pyrolysis. The results also demonstrate that the pyrolysis reactions are almost completed within the first 0.8?ms in Ar/H2 plasma independent of the feed substances (i.e., liquid hydrocarbons), where the increased feedstock specific input power enhances the reactant conversions and correspondingly raises the yields of acetylene. At a feedstock specific input power of 4.7?×?104?kJ/kg, the n-hexane conversion is over 90?% and the yield of acetylene reaches 70?%. In addition, when using n-hexane as the feedstock, very little coke is formed during the course of reaction. Comprehensive comparisons of the current experiments with the data reported in the literature are made to point out the key influencing factors, i.e., the effective mass ratio of C/H (R C/H) in the gaseous phase and the quench temperature. Both two factors would need to be enhanced in order to get a better performance. Finally, the improvements on the specific energy requirement of this process are discussed. 相似文献