电位法测定密闭环境空气中碱性气溶胶

建立电位法测定密闭环境中碱性气溶胶的检测方法。将空气中的碱性气溶胶采集到滤膜上,将滤膜剪碎,置于25 mL比色管中,加入20 mL水,将比色管置于振荡器中,于25℃恒温振荡器中剧烈振荡1 min,立即使用酸度计测定溶液的pH值,计算出空气中碱性气溶胶(以氢氧化钠计)的质量浓度。该方法的检出限为0.001 mg/m^(3),当碱性气溶胶的质量浓度在0.05~1.00 mg/m^(3)的范围内,加标回收率为84.4%~90.4%,测定结果的相对标准偏差小于5%(n=6)。该方法适用于密闭环境空气中碱性气溶胶的测定。     

SCO2 再压缩循环的非设计性能及控制策略研究

SCO₂循环的部件性能随系统负载降低会发生显著变化。因此,本文首先建立了10 MW输出功率的SCO₂再压缩循环。然后分别在库存控制和涡轮旁通控制下研究了系统的非设计性能。结果表明,当系统负载减小到10%时,库存控制的热效率降至21.04%,再压气机趋向失速;涡轮旁通控制的热效率至13.56%,压气机发生堵塞。基于此,提出了库存–旁通混合控制策略。该混合策略的使用改善了两单一策略下的压气机运行状态,且系统性能介于两单一策略的之间。     

Re_3W的点接触安德烈夫反射谱研究

本文通过对不同晶体结构Re_3W样品的点接触测量和对比研究,证实具有中心对称结构和非中心对称结构的Re_3W都是弱耦合Bardeen-Cooper-Schrieffer超导体,同时发现在两个相表面都可以形成很理想的点接触结,即电子通过界面时受到的非弹性散射很弱.将Re_3W样品置于大气环境近六个月后重新进行测量,仍然能够得到类似的结果,表明Re_3W具有很好的稳定性. Re_3W的这种优良特性,不仅可通过点接触实验得到的参数推算出Re_3W两个相的费米速度,而且提供了一种简单的方法,可以在点接触实验中利用Re_3W来印证针尖材料的费米速度和测量其自旋极化率等.作为尝试,本文用Re_3W/Ni点接触结测量了铁磁性金属Ni的自旋极化率,得到了与前人报道一致的结果.     

Magnetic Sensing inside a Diamond Anvil Cell via Nitrogen-Vacancy Center Spins

The diamond anvil cell-based high-pressure technique is a unique tool for creating new states of matter and for understanding the physics underlying some exotic phenomena.In situ sensing of spin and charge properties under high pressure is crucially important but remains technically challenging.While the nitrogen-vacancy(NV)center in diamond is a promising quantum sensor under extreme conditions,its spin dynamics and the quantum control of its spin states under high pressure remain elusive.In this study,we demonstrate coherent control,spin relaxation,and spin dephasing measurements for ensemble NV centers up to 32.8 GPa.With this in situ quantum sensor,we investigate the pressure-induced magnetic phase transition of a micron-size permanent magnet Nd_2Fe_(14)B sample in a diamond anvil cell,with a spatial resolution of ～2μm,and sensitivity of ～20 μT/Hz~(1/2). This scheme could be generalized to measure other parameters such as temperature,pressure and their gradients under extreme conditions.This will be beneficial for frontier research of condensed matter physics and geophysics.     

Phenomenology of b→cτ■ decays in a scalar leptoquark model

During the past few years,signs of lepton flavor universality(LFU)violation have been observed in b→cτ■ and b→sl+l-transitions.Recently,the D* and τ polarization fractions P_L~D* and P_L~τ in B→D*τ■decay were likewise measured by the Belle collaboration.Motivated by these intriguing results,we revisit the RD(*)and RK(*) anomalies in a scalar leptoquark(LQ)model,where two scalar LQs,one of which is a S U(2)L singlet and the other a S U(2)L triplet,are introduced simultaneously.We consider five b→ cτ■ mediated decays,B→D(*)τ■,B_c→ηcτ■,Bc→J/ψt■,and ∧_b→∧_cτ■,and focus on the LQ effects on the q~2 distributions of the branching fractions,LFU ratios,and various angular observables in these decays.Under the combined constraints of the available data on RD(*),RJ/ψ,P_L~τ(D*),and pLD*,we perform scans for the LQ couplings and make predictions for a number of observables.Numerically it is found that both the differential branching fractions and LFU ratios are largely enhanced by the LQ effects,with the latter expected to provide testable signatures at the SuperKEKB and High-Luminosity LHC experiments.     

基于分子对接和QSAR方法预测B-Raf II型抑制剂活性

B-Raf激酶在促分裂素原活化蛋白激酶(MAPK)信号转导通路中起着重要作用,已被确定为癌症治疗非常有吸引力的靶标.新型高效B-Raf抑制剂的开发成为癌症治疗的一个热门研究领域.本文以结构多样的B-Raf II型抑制剂为研究对象,联合应用分子对接和定量构效关系(QSAR)模型研究其定量构效关系去探讨抑制活性的起源.两个主题作为研究重点:生物活性构象和描述符.首先对分子对接方法(Glide、Gold、LigandFit、Cdocker和Libdock)进行准确性评价,后将研究的对象分子对接到B-Raf活性位点并获得生物活性构象.基于准确的对接结果,计算得到16个打分评价函数和21个能量描述符,以此构建定量构效关系模型. QSAR结果表明模型具有高度精确的拟合和强的预测能力(模型M1: r² = 0.852, r_(CV)² = 0.790, r_pre² = 0.864;模型M2: r² = 0.738, r_(CV)² = 0.812, r_pre² = 0.8605).同时探讨了对抑制活性有重要影响的描述符,结果表明打分评价函数(G_Score, -ECD, Dock_Score, PMF)与能量描述符(S(hb_ext), DE(int), Emodel)对抑制活性影响非常大.通过虚拟筛选和QSAR模型理论预测,一些新的具有潜在抑制活性的化合物作为B-Raf II型抑制剂被获得.上述信息对于进一步设计新颖高效的B-Raf II型抑制剂提供了有用的指导.     

基于红色荧光染料3-(dicyanomethylene)-5, 5-dimethyl-1-(4-dimethylamino-styryl) cyclohexene的高性能白色有机电致发光器件

研究了基于红色荧光染料3-（dicyanomethylene）-5, 5-dimethyl-1-（4-dimethylamino-styryl） cyclohexene（DCDDC）的白色有机电致发光器件的性能,分别制备了基于DCDDC超薄层和DCDDC掺杂主体材料的两种器件结构: 1）indium-tin oxide（ITO）/N, N′-diphenyl-N, N′-bis（1-naphthyl-pheny1）-1, 1′-biphenyl-4, 关键词： 有机电致发光器件 白色发光 红色荧光染料 掺杂     

Properties of Graphene Based Parametric Pump

The adiabatic parametric electron pump of the infinite zigzag graphene ribbons and the infinite armchair graphene ribbons is investigated by the tight binding method. The pumping signals are added by two gates around the ribbons. It is shown that the de current can be pumped out by cyclically varying the two gate voltages and the pumped current strongly depends on the driving frequency, the pumping amplitude and the phase difference of the gate voltages. The pumped current is mediated by the graphene energy levels and its peaks occur around the energies where transmission coefficients and density of states are large. The pump current may give one peak or two opposite peaks corresponding to each transmission peak or transmission pair peaks. The height and width of the current peaks increase with the amplitude of the pumping driving voltages. The pumped current is antisymmetric about the phase difference Ф=π and for small pumping amplitude the pumped current is a sinusoidal function of the phase difference. Some graphene ribbons, although with different widths, have very similar contours of the transmission coefficients and give the same pumped current figures.     

Heat Transport of Non-Local Effect with Modulated SMBI on HL-2A

Modulated supersonic molecular beam （SMB） injection is introduced to study transport features of non-local transport phenomenon on HL-2A. Repetitive non-local effect induced by modulated SMBI allows Fourier trans-formation of the temperature perturbation, yielding detailed investigation of the pulse propagation. Fourier analysis provides evidence for existence of internal transport barriers. Meanwhile, experimental progress of nonlocal effect was made in the HL-2A Tokamak in 200Z The core electron temperature Te rise increases from 18% to more than 40% and the duration of the Te rise could be prolonged by changing the conditions of SMB injection.     

聚乙二醇支持的2,5-二取代异噁唑啉衍生物的液相合成

介绍了通过1,3-偶极环加成合成2,5-二取代异噁唑啉衍生物的液相合成方法, 利用聚乙二醇(PEG)支持的烯烃与由醛肟制得的腈氧化物反应制备了多种异噁唑啉衍生物, PEG解脱后产物的产率和纯度均很高.