PHOTOCATALYTIC HYDROGEN EVOLUTION FROM WATER SPLITTING UNDER VISIBLE LIGHT IRRADIATION ON NOVEL PHOTOCATALYST FULLENES-PVP-ZN_(0.999)NI(0.001)S

1. INTRODUCTION1. INTRODUCTIONOne of the most widely discussed subjects these days is the energy crisis, i.e. the oil shortage and the oil price rising, which encouraged us to research and develop new green energy-hydrogen energy in the 21st century. Therefore, hydrogen produced from water splittingwith photocatalyst has been extensively studied from the viewpoint of photo energy, such as solar energy conversion to chemical and electricity energy, and environmental concerns. To date, …     

Controllable Synthesis of Titania Nanocrystals with Different Morphologies and Application to the Degradation of Phenol

Titania nanocrystals with different morphologies were prepared using the hydrothermal method via controlling the pH values of solution, the ratio of reactants, temperature, and time of the hydrothermal reaction. The experimental results showed that uniform rod-like titania particles with an average aspect ratio of 6：1 could be obtained under the conditions of pH=11, n（TBOT）：n（TEA）=1：2, hydrothermal treatment at 150 °C for 24 h. When pH〈10, spherical titania nanocrystals could be obtained; with increasing the pH value, the diameter became smaller. Finally, the smallest size of the particles could reach 7 nm. Nanocrystals with uniformly well-dispersed and perfect crystallographic form were obtained via the above method. Phenol was used as the degradation model for testing the photocatalytical activity of the titania nanocrystals with different morphologies.     

供应链多级系列系统库存控制策略

供应链管理的目标是通过成员间的密切合作和信息共享,以最小的成本提供最大的客户价值(包括产品的服务),这就要求供应链上各节点企业的活动同步进行,对库存管理职能进行必要的整合,集中管理整个供应链系统的库存,从而降低整个供应链的库存成本.基于供应链多级系列系统为研究对象,给出了在需求率为恒定情况下的级库存的表达方式,提出了递归搜索的概念,并采用该办法求出了多级系列系统的最佳订货周期及批量,计算出了多级系统最小总费用.     

弱相依数据中的分组经验Cressie-Read似然方法

本文考虑一般的弱相依数据, 提出了分组经验Cressie-Read似然方法. 得到了分组经验Cressie-Read似然参数估计的强收敛性、渐近正态性和其分组经验Cressie-Read统计量的渐近$\chi^{2}$性.     

一类具有Allee影响的捕食与被捕食模型

分析并建立了具有Allee影响的捕食与被捕食模型,被捕食者由于自身繁殖或是被捕食而具有了Allee效应,分别讨论了强Allee和弱Allee对被捕食种群的影响,讨论了解的有界性和各平衡点的存在性,并证明了各平衡点的局部渐近稳定性,进一步通过构造适当的Lyapunov函数分析了正平衡点E*的全局渐近稳定性.     

Si(111)-(7×7)衬底上合成有序的IV族金属铅团簇阵列

文章作者在Si(111)(7×7)衬底上合成出位于同一主族的Pb的全同纳米团簇有序阵列.有趣的是,当衬底温度相对于最佳的生长温度范围发生微小的偏离时,Pb纳米团簇很容易转变为其他结构的团簇.结合实验结果和第一性原理总能量计算,文章作者揭示了几种Pb团簇的原子结构.这些结构都是以表面Pb和Si原子互换导致的混合模型为中心的衍生结构.Pb/Si(111)体系的这种边缘性质为研究表面幻数团簇的合成、分解等动力学过程提供了重要信息.     

北京慢正电子强束流磁场输运系统设计研究

针对基于北京正负电子对撞机的慢正电子强束流系统对输运磁场的设计要求,本文对不同规格的磁场输运线圈模型、长螺线管端口处磁场的补偿以及地磁场和弯管道对正电子束流的影响等进行了计算,提出适用于本系统传输慢正电子束流的输运磁场分布、补偿线圈、调整线圈的加工参数,计算表明,系统的总体磁场不均匀度小于10髎.实际运行束流测试表明,所设计的磁场系统能够很好的将慢正电子束流输运到约16m远的样品测量室,慢正电子束斑尺寸基本没有变化,满足慢正电子束流系统的设计要求.     

Synthesis of Diphosphites from trans, trans-Spiro[4.4]nonane-1,6-diol and Their Application in Rh-catalyzed Asymmetric Hydroformylation of Styrene

Chiral diphosphite ligands were prepared by the reaction of (1R,5S,6R)-(trans, trans)-spiro[4.4]nonane-1,6-diol with chlorophosphites. The rhodium(Ⅰ) complexes containing these ligands were tested in the asymmetric hydroformylation of styrene and moderate enantioselectivity (up to 49% ee) was obtained. A pair of diastereomers 5a and 5b gave the opposite configuration of the product, which implies that the sense of enantioface selection is mainly dictated by the configuration of the terminal group on the ligand.     

吊桥方程非对称周期解的存在性

在本文中,利用Jabri Y和Moussaoui M在最近的文献中得到的一个临界点定理,我们在没有对称性假设的情况下,证明了Lezer A C和McKenna P J吊桥方程周期解的存在性.