| PHOTOCATALYTIC HYDROGEN EVOLUTION FROM WATER SPLITTING UNDER VISIBLE LIGHT IRRADIATION ON NOVEL PHOTOCATALYST FULLENES-PVP-ZN_(0.999)NI(0.001)S |
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| 作者姓名： | XUE Zhixin YANG Guipeng CHEN Dianbao MA Xiaomei ZHANG Xiqin QUAN Zhenlan College of Chemical Engineering and Environment Qingdao University Qingdao China Key Laboratory of Marine Chemistry Theory and Technology Ministry of Education Ocean University of China Qingdao P.R.China Fullerenes Materials Group Qingdao University of Science and Technology Qingdao China |
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| 作者单位： | XUE Zhixin1，2 YANG Guipeng2 CHEN Dianbao3 MA Xiaomei1 ZHANG Xiqin1 QUAN Zhenlan3 1 College of Chemical Engineering and Environment，Qingdao University，Qingdao 266071，China 2 Key Laboratory of Marine Chemistry Theory and Technology，Ministry of Education，Ocean University of China，Qingdao 266003，P.R.China 3 Fullerenes Materials Group，Qingdao University of Science and Technology，Qingdao 266071，China |
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| 基金项目： | KeyProjectofChineseMinistryofEducationNo.105105),ProgramforNewCenturyExcellentTalentsinUniversityofChineseMinistryofEducation(No.NCET-04-0643),theTaishanMountainScholarConstructionEngineeringSpecialFundofShandongProvince,China. |
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| 摘 要： | 1. INTRODUCTION1. INTRODUCTIONOne of the most widely discussed subjects these days is the energy crisis, i.e. the oil shortage and the oil price rising, which encouraged us to research and develop new green energy-hydrogen energy in the 21st century. Therefore, hydrogen produced from water splittingwith photocatalyst has been extensively studied from the viewpoint of photo energy, such as solar energy conversion to chemical and electricity energy, and environmental concerns. To date, …
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PHOTOCATALYTIC HYDROGEN EVOLUTION FROM WATER SPLITTING UNDER VISIBLE LIGHT IRRADIATION ON NOVEL PHOTOCATALYST FULLENES-PVP-ZN_(0.999)NI(0.001)S |
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| XUE Zhixin, YANG Guipeng CHEN Dianbao MA Xiaomei ZHANG Xiqin QUAN Zhenlan College of Chemical Engineering and Environment,Qingdao University,Qingdao ,China Key Laboratory of Marine Chemistry Theory and Technology,Ministry of Education,Ocean University of China,Qingdao ,P.R.China Fullerenes Materials Group,Qingdao University of Science and Technology,Qingdao ,China.PHOTOCATALYTIC HYDROGEN EVOLUTION FROM WATER SPLITTING UNDER VISIBLE LIGHT IRRADIATION ON NOVEL PHOTOCATALYST FULLENES-PVP-ZN_(0.999)NI(0.001)S[J].离子交换与吸附(英文版),2006(1). |
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| Authors: | XUE Zhixin YANG Guipeng CHEN Dianbao MA Xiaomei ZHANG Xiqin QUAN Zhenlan College of Chemical Engineering and Environment Qingdao University Qingdao China Key Laboratory of Marine Chemistry Theory and Technology Ministry of Education Ocean University of China Qingdao PRChina Fullerenes Materials Group Qingdao University of Science and Technology Qingdao China |
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| Institution: | XUE Zhixin1,2 YANG Guipeng2 CHEN Dianbao3 MA Xiaomei1 ZHANG Xiqin1 QUAN Zhenlan3 1 College of Chemical Engineering and Environment,Qingdao University,Qingdao 266071,China 2 Key Laboratory of Marine Chemistry Theory and Technology,Ministry of Education,Ocean University of China,Qingdao 266003,P.R.China 3 Fullerenes Materials Group,Qingdao University of Science and Technology,Qingdao 266071,China |
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| Abstract: | Fullerenes(C60/C70)linked up to Ni-doped ZnS through the medium of an amphalic polymer polyvinyl pyrrolidone(PVP)to form a new kind of photocatalyst for hydrogen evolution from aqueous Na2S/Na2SO3 solution under visible light irradiation,the photocatalytic activities of this novel photocatalyst C60/C70-PVP-Zn0.999Ni0.001S are 3-5 fold higher compared with that of precurse catalyst Zn0.999Ni0.001S.This result could be attributed to Schottky barrier layer built between C60/C70 and Zn0.999Ni0.001S due to the electro-negativity of C60 and characteristic of being used as a multiple electron acceptor.C60 or C60/C70,its moiety,with its low energy first excited singlet state,is a good energy acceptor and in addition readily accepts multiple electrons,making it a potential electron accumulate as we know,which could protect the separation between electrons and holes against combination.This is an important reason for the marked increase of amount of H2 evolution during the photocatalytic process for the composite system C60/C70-PVP-Zn0.999Ni0.001S. |
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| Keywords: | Fullerenes(C60/C70) Photocatalyst Hydrogen Water splitting Visible light |
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