Dual-sensitive probe 1-imidazole-2-(5-benzoacridine)-ethanone for the determination of amines in environmental water using HPLC with fluorescence detection and online atmospheric chemical ionization-mass spectrometry identification

Dual-sensitive probe of 1-imidazole-2-(5-benzoacridine)-ethanone (IBAE) for the determination of free amines with fluorescence detection and online highly sensitive atmospheric chemical ionization-mass spectrometry identification (APCI-MS) has been developed. 2-(Benzoacridine)-5-acetic acid (BAAA) reacts with coupling agent N,N′-carbonyldiimidazole (CDI) to form a highly activated amide intermediate 1-imidazole-2-(5-benzoacridine)-ethanone (IBAE), which is dual-sensitive probe. The amide intermediate (IBAE) reacts preferably with amines in dimethylformamide (DMF) solvent to give the high yields of derivatives. IBAE-amine derivatives are not only sensitive to fluorescence but also to MS ionizable efficiency. The percent ionization δ values change from 0 to 57.32% in aqueous acetonitrile and from 0 to 62.14% in aqueous methanol. The relative standard deviations of the peak areas with fluorescence detection for each amine are <1.24% (40 ng/ml, n = 6). The fluorescence detection limits (at a signal-to-noise ratio of 3) are in the range of 0.15-0.50 ng/ml. The online APCI-MS detection limits are in the range of 2.07-8.51 ng/ml (at a signal-to-noise ratio of 3). Therefore, the facile IBAE intermediate derivatization allowed the development of a highly sensitive and specific method for the quantitative analysis of trace levels of amines in environmental water.     

Ab initio study of mechanism of forming germanic bis-heterocyclic compound between germylene carbene (H2GeC:) and acetone

The mechanism of the cycloaddition reaction of forming germanic bis-heterocyclic compound between singlet germylene carbene and acetone has been investigated with MP2/6-31G* method, including geometry optimization and vibrational analysis for the involved stationary points on the potential energy surface. The energies of the different conformations are calculated by CCSD (T)//MP2/6-31G* method. From the potential energy profile, it can be predicted that the dominant reaction pathway of the cycloadditional reaction of forming germanic bis-heterocyclic compound consists of three steps: (1) the two reactants firstly form an intermediate INT4 through a barrier-free exothermic reaction of 181.4 kJ/mol; (2) INT4 further reacts with acetone (R2) to form an intermediate (INT5), which is also a barrier-free exothermic reaction of 148.9 kJ/mol; (3) INT5 then isomerizes to a germanic bis-heterocyclic product P5 via a transition state TS5 with an energy barrier of 53.3 kJ/mol.     

Synthesis and Crystal Structure of a New Zn(Ⅱ) Complex Exhibiting Strong Luminescence

The title complex,[Zn(ip)2(H2O)2][ZnCl4]·H2O·2DMF 1(ip=imidazo[4,5-f][1,10] phenanthroline),has been synthesized via the slow evaporation of concentrated reaction solution at room temperature.It was characterized by single-crystal X-ray diffraction.Crystal data for C32H36Cl4N10O5Zn2:white prism,0.17mm×0.15mm×0.10mm,monoclinic,space group P2/c,a=11.928(8),b=9.868(6),c=16.520(11),β=104.879(12)°,V=1879(2)3,Z=2,Mr=913.25,Dc=1.614 g/cm3,F(000)=932,μ=1.616 mm-1,λ(MoKα)=0.71073,GOOF=1.045,R=0.0710 and wR=0.1755 for 3055 observed reflections with Ⅰ2σ(Ⅰ).X-ray diffraction study reveals that the title complex has an interesting 3D architecture via hydrogen bonding interactions and π-π interactions.The IR,TGA,XRD and luminescent properties of complex 1 were also studied.     

磁性碳基磺酸化固体酸催化剂的制备及其催化水解纤维素

以纤维素和硝酸铁为原料,发烟硫酸为磺酸化试剂,采用热解法合成了磁性碳基磺酸化固体酸催化剂(Fe/C-SO3H).利用扫描电镜(SEM)、透射电镜(TEM)、X射线衍射(XRD)、X射线光电子能谱(XPS)、傅里叶变换红外(FT-IR)光谱仪和振动样品磁强计(VSM)等手段对催化剂进行了表征,评价了催化剂在纤维素水解反应中的催化活性.结果表明,Fe是以γ-Fe2O3的形式存在于碳本体中,催化剂呈现超顺磁性.对于纤维素的水解反应,在优化条件下,纤维素的转化率可达40.6%.此外,催化剂可稳定分散于反应体系中,并在外加磁场作用下可快速与反应体系分离.但催化剂重复使用时催化活性有所下降,其失活原因经初步认定是由于表面部分磺酸基团在反应过程中脱落.     

与$\zeta(2k 1)$函数有关的两类快速收敛级数

Values of new series sum（（（2n-1）!ζ（2n））/（2n ＋ 2k）!）α2n from n=1 to ∞,sum（（（2n-1）!ζ（2n））/（2n＋2k ＋1）!）β2n from n=1 to ∞ are given concerning ζ（2k ＋ 1）,where k is a positive integer,α can be taken as 1,1/2,1/3,2/3,1/4,3/4,1/6,5/6 and β can be taken as 1,1/2.Some previous results are included as special cases in the present paper and new series converges more rapidly than those exsiting results for α = 1/3,or α = 1/4,or α = 1/6.     

有限重数的Dirichlet移位

In this paper, we show that a multiplication operator on the Dirichlet space D is unitarily equivalent to Dirichlet shift of multiplicity n ＋ 1 （n ≥ 0） if and only if its symbol is c zn＋1 for some constant c. The result is very different from the cases of both the Bergman space and the Hardy space.     

Polarization singularities in Young's two-slit experiment

Young's interference experiment is regarded as a two-slit diffraction phenomenon, the polarization singularities in Young's two-slit configuration illuminated with two linearly, orthogonally polarized Gaussian vortex beams are studied. It is shown that generally, there exist L-lines (linearly polarization) and polarization singularities including C-points (circular polarization), S₂₃ and S₃₁ singularities even though the parameters of two beams are the same. The pair creation-annihilation and motion of polarization singularities take place upon propagation, or by varying a control parameter, such as the amplitude ratio of two beams or obscure ratio of slits etc. For a special case of the illumination with two linearly, orthogonally polarized Gaussian vortex-free beams, polarization singularities, in particular, C-points may occur if a parameter of two beams is not equal.     

高斯涡旋光束的傍轴度

按单色光束傍轴度的定义,对高斯涡旋光束的傍轴度进行了研究.使用角谱表示法推导出高斯涡旋光束傍轴度的解析公式,用此研究了傍轴度和高斯涡旋光束参数之间的关系.结果表明,随背景高斯光束束腰宽度和光涡旋离轴参数的增加及随光涡旋拓扑电荷的减少,高斯涡旋光束的傍轴度增加.对所得结果用傍轴度与远场发散角间的关系做了物理解释.     

Critical behavior of XY spin chain with Dzyaloshinsky-Moriya interaction studied in terms of Loschmidt echo

In this paper, the critical behavior of the general XY spin chain with the Dzyaloshinsky-Moriya (DM) interaction is studied by means of a Loschmidt Echo (LE) calculation. LE presents a Gauss decay in the region of magnetic field intensity |λ|<1 and an exponential decay in the region of |λ|>1. There exists a critical spin chain size N_C. When spin chain size is larger than N_C, the value of λ corresponding to the minimum value of LE (λ_m) is independent of the spin chain size and keeps a stable value. In the region of λ<0, the stable value is same for different DM interactions. In the region of λ>0, the stable value varies with changing DM interaction.     

Fe3O4薄膜的电输运及光诱导特性研究

用脉冲激光沉积法在(111)Si衬底上成功制备了高度择优取向的Fe₃O₄薄膜.电阻-温度关系表明Fe₃O₄薄膜的Verwey转变(T_V)约在122 K,低温段(T_V)输运特征满足Mott变程跳跃模型,高温段(T>T_V)为小极化子输运.激光作用下的光电导实验发现,在整个温区表现为光致电阻率减小,而且低温段的电阻变化率比高温段要大很多.分析认为Fe₃O₄薄膜的光致电阻率变化主要与激光激发t_2g电子的转移有关. 关键词： 3O₄薄膜')" href="#">Fe₃O₄薄膜 小极化子 光诱导特性