| Synthesis and Crystal Structure of a New Zn(Ⅱ) Complex Exhibiting Strong Luminescence |
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| 引用本文： | 冯蕊,闫春凤,陈莲,吴明燕,江飞龙,洪茂椿.Synthesis and Crystal Structure of a New Zn(Ⅱ) Complex Exhibiting Strong Luminescence[J].结构化学,2010,29(1):57-62. |
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| 作者姓名： | 冯蕊 闫春凤 陈莲 吴明燕 江飞龙 洪茂椿 |
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| 作者单位： | State;Laboratory;Structural;Chemistry;Fujian;Institute;Research;Structure;Matter;Chinese;Academy;Sciences;Graduate;School; |
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| 基金项目： | supported by 973 (2006CB932900);;NNSFC (20571074);;NSF of Fujian Province (2007J172) |
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| 摘 要： | The title complex,Zn(ip)2(H2O)2]ZnCl4]·H2O·2DMF 1(ip=imidazo4,5-f]1,10] phenanthroline),has been synthesized via the slow evaporation of concentrated reaction solution at room temperature.It was characterized by single-crystal X-ray diffraction.Crystal data for C32H36Cl4N10O5Zn2:white prism,0.17mm×0.15mm×0.10mm,monoclinic,space group P2/c,a=11.928(8),b=9.868(6),c=16.520(11),β=104.879(12)°,V=1879(2)3,Z=2,Mr=913.25,Dc=1.614 g/cm3,F(000)=932,μ=1.616 mm-1,λ(MoKα)=0.71073,GOOF=1.045,R=0.0710 and wR=0.1755 for 3055 observed reflections with Ⅰ2σ(Ⅰ).X-ray diffraction study reveals that the title complex has an interesting 3D architecture via hydrogen bonding interactions and π-π interactions.The IR,TGA,XRD and luminescent properties of complex 1 were also studied.
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| 关 键 词： | 锌（Ⅱ） 三维结构 发光性能 合成 π-π相互作用 X射线衍射 晶体 知识产权 |
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