第15届固态传感器、传动器与微系统国际会议(Ⅱ)

本届会议的专题报告按日程安排分述如下:(1)T Wacharalindu:以液态半导体为基础的微功率源--采用反射能量转换;(2)C M Waits,MMc Carthy,R Ghodea:供小规模动力系统中输送燃料用的、微电动机械系统的涡轮泵;(3)I D Block、P c Mcthals、M Ganoch:增强荧光与无标记成像联用仪;(4)L H Loo、Y D Lau:应用微结构的流体动力学偶联方法进行微型悬臂的质量因子的调谐;(5)K Imagawa,H Horilauchi,K Ikoda:应用心脏肌肉细胞的药物模拟方法的自给加热与流体泵送凝胶;(6)N Suhkl:供模拟在任何硅取向的表面组织与几何形态用的连续分格自动化技术.     

Synthesis of Calix[4]pyrroles: A Class of New Molecular Receptor

RecentlySesslerandco-workersdiscoveredthatthemeso-octaalkylporphyrinogensshowedinterestinganionandneutralsubstratebindingpropertiesandmightserveasaclassofneweasy-to-makemolecularreceptorintheareaofsupramolecularchemistry'.However,themeso-octaalkylpor...     

苯/二联苯为桥的噻吩-吡咯-噻吩结构:分子构型及电致变色性质

A series of multi-branched dithienylpyrrole (SNS) monomers with rigid phenyl (PhSNS) and biphenyl rings (BPhSNS) as bridges were designed and synthesized, and were fabricated to form cross-linked polymers (pPhSNS, pBPhSNS) by electrochemical polymerization. Cyclic voltammetry (CV) results showed that PhSNS and BPhSNS exhibited similar oxidative properties except for one new higher-potential oxidative peak appearing in the curves of PhSNS. Theoretical calculations indicated that it should be attributed to the different steric configuration between the two dithienylpyrrole (SNS) units in PhSNS. One SNS unit possessed a larger twist angle (40.2°) between thiophene and pyrrole rings than the other one (21.2°), which indicated that PhSNS possessed a relatively larger energy gap (~0.4 eV) between HOMO-1 and HOMO than BPhSNS, for which HOMO and HOMO-1 levels were of almost the same energy. However, both PhSNS and BPhSNS showed similar onset oxidation potentials. The CV curves of pPhSNS and pBPhSNS showed that they presented similar oxidative properties, which enabled their corresponding electrochemical polymers to exhibit similar electrochromic properties. The UV-vis spectra of the corresponding polymers showed that both pPhSNS and pBPhSNS possessed similar optical absorption and similar multicolor switching between yellow (-0.8 V), greyish-green (0.9 V) and gray (1.1 V) colors. Besides, pPhSNS and pBPhSNS showed fast switching times of 0.57 s and 0.93 s at 1100 nm, respectively and reasonable contrasts of 46% and 31% at 1100 nm, respectively. These investigations may help understand the relationship between structural configuration and the electrochemistry/electrochromic properties for polymer electrochromic (PEC) materials research.     

一种定量分析金属镀层中特定元素含量的简单方法

用光学的方法（如常见的X射线荧光分析法、发射光谱分析法^[1]等）分析固体样品中特定元素及其含量是常见的分析方法。相对于化学方法，它们的分析过程简单、迅速。笔者在分析样品中遇到了一些比较特殊的分析要求，例如在金属外镀了另外的合金，要求分析在镀层中特定元素的浓度。一种直接的方法是用X射线荧光做定量分析，可以给出镀层的元素含量。但X荧光定量分析需要特定的标样，对使用者存在一定的不便之处，而且设备也较贵。本研究采用普通的原子光谱分析法结合简单的数学推导，解决了上述问题。本方法也可以应用于普通的光学原子发射光谱分析。     

SIMILARITY LAWS AND SCALING OF PENETRATION TESTS

利用球形空腔膨胀理论的响应函数对靶板在弹体撞击下的侵彻进行分析，并基于量纲理论建立了侵彻相似律的一般形式.通过对侵彻混凝土靶的已有实验数据进行分析，得到了不同缩比因子下，无量纲侵彻深度曲线随侵彻速度不同而发生偏转和偏移.考虑到材料的应变率效应和损伤演化，认为几何相似律对混凝土等脆性材料在抗侵彻时不成立，有必要引入材料应变率效应和损伤演化对几何相似律的修正.     

BEHAVIOR OF CHO CELLS ON MODIFIED POLYPROPYLENE BY LOW TEMPERATURE AMMONIA PLASMA

1. INTRODUCTION Bioreactors using membranes as substrates of cell cultures have become widely used for hybrid liver support systems [1]. For enhancing and prolonging the metabolism of the bioreactors, cytocompatible membranes are necessary because the cell culture is closely affected by the substrate surface. Surface factors considered to be important in cell culture are the concentration of ionic groups, the nature of polar and non-polar groups and the hydrophilic-hydrophobic balance [2].…     

纺锤形BiVO_4微米管:低温离子熔盐合成及光催化性能

以Bi(NO_3)_3·5H_2O和NH_4VO_3为原料,以氯化胆碱和尿素组成的低温离子熔盐为反应介质,采用离子热合成法成功制备出了具有纺锤状外形的BiVO_4微米管。利用XRD,SEM,UV-Vis DRS,光催化测试等手段考察了BiVO_4颗粒的物相、形貌和光催化性能。结果表明,在离子熔盐环境下可以制备出结晶良好的BiVO_4纺锤形微米管,该BiVO_4微米管长10～15μm,直径为1.5μm左右,管壁厚约为200 nm。同时,研究了pH值对BiVO_4颗粒物相与形貌的影响,发现随着pH值的变化可分别合成出具有柱状、纺锤形微米管、柱状微米管和针柱状单斜相BiVO_4颗粒。光催化测试结果表明,这些单斜白钨矿BiVO_4颗粒在可见光范围都具有一定的光催化活性,其中纺锤状微米管对罗丹明B的降解效果最佳,可见光照射4.5h后罗丹明B的降解率可达到93%。     

换热器表面结霜状态下翅片效率公式的理论分析及改进

１引言制冷设备中换热器是重要的部件，在进行换热器设计或对实际系统中换热性能进行计算时，采用的翅片效率的准确与否将会关系到整个系统的工作状况。对于换热器表面处于干或湿工况时，文献中的翅片效率公式形式较统一，但对结霜情况下的研究相对没有一致的结论［１］。Ｓａｎｄｅｒｓ［１］、Ｂａｒｒｏｗ［２］和Ｋｏｎｄｅｐｕｄｉ［３］都曾提及霜工况下换热器翅片效率公式，此外还有包含析湿系数的翅片效率形式。由于所采用的结霜翅片效率表达式不同，最终得到的翅片效率及翅片温度分布也难免存在差别。因而，从众多公式中选择相对准…     

三硼酸锂晶体的多光子散射

本文报道三硼酸锂(LBO)晶体的瞬态前向相干多光子散射,实验表明LBO晶体内部同时发生x~(2)和x~(3)非线性相互作用过程,而未发现光耦合效应,测量了LBO晶体的光栅寿命上限.     

STUDIES ON POLYMERIC DISPERSANTS Ⅰ. DISPERSION OF γ-Fe2O3 IN NON-AQUEOUS MEDIA WITH CARBOXYLATED POLY-n-BUTYL ACRYLATES AS DISPERSANT

Carboxylated poly-n-butyl acrylates were used as model polymeric dispersant. The effect ofpolymers on the dispersion of γ-Fe_2O_3 in cyclohexanone were studied through sedimentation testand rheological measurement. The polymers with strong anchoring groups at one end of the polymerchain were the most effective polymeric dispersant, which improved magnetic properties of the preparedcoatings significantly.