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排序方式: 共有9737条查询结果,搜索用时 78 毫秒
981.
Chun Hong LI Xue Song CHEN Guang Lian ZHOU Zhi Xiang XIE Ying LI? National Laboratory of Applied Organic Chemistry Institute of Organic Chemistry Lanzhou University Lanzhou 《中国化学快报》2005,16(8):1024-1026
Marine natural products have received much attention for their attractive structural features and biological activities1. Since the isolation of the moritoside, about 10 related triprenylquinones and hydroquinones were isolated. Some of these natural products exhibit interesting biological effects including inhibit cell division of fertilized starfish eggs2 and anti-HIV3. Triprenylquinone and hydroquinones 1, 2 and 3 were recently isolated from endemic nudibranch Leminda millecra collected i… 相似文献
982.
983.
23Na nuclear magnetic resonance (NMR) spectroscopy of NaCl-exchanged polyamide (PA) films comparable to those of the active skin layer of many reverse osmosis (RO) membranes provides novel insight into the structural environments and dynamical behavior of Na+ in such films. Unsupported PA films were synthesized via interfacial polymerization of trimesoyl chloride in hexane and m-phenylenediamine in aqueous solution, and SEM, FT-IR, and 13C NMR data demonstrate successful thin film polymerization. Compositional data confirm this conclusion and demonstrate equal Na and Cl incorporation during NaCl exchange from aqueous solution. The 23Na NMR spectra for freshly made polymer samples exchanged in 1 M NaCl solution show significant relative humidity (RH) dependence. At near 0% RH, there are resonances for crystalline NaCl and rigidly held Na+ in the PA. With increasing RH, a resonance for solution-like dynamically averaged Na+ appears and above 51% RH is the only signal observed. The slightly negative chemical shift of this resonance suggests a dominantly hydrous environment with some atomic-scale coordination by atoms of the polymer. The greatly reduced 23Na T1 relaxation rates for this resonance relative to bulk solution and crystalline NaCl confirm close association with the polymer. Variable temperature 23Na NMR spectra for a sample equilibrated at 97% RH obtained from −80 to 20 °C show the presence of rigidly held Na+ in a hydrated environment at low temperatures and replacement of this resonance by the dynamically averaged signal at temperatures above about −20 °C. The results provide support for the solution–diffusion model for RO membranes transport and demonstrate the capabilities of multi-nuclear NMR methods to investigate molecular-scale structure and dynamics of the interactions between dissolved species and RO membranes. 相似文献
984.
Catalytic Hydrolysis of Lipophilic Amino Acid Esters by Metallomicelles as Carboxypeptidase A Models
Metallondcellesasthemodelofhydrolyticmetalloenzymes.havebegunrecently'.Exam-plesarethemetal-ioncomplexesoflipophilicinddazoles2andpyridines'co-ndcelledwithsurfactantS.Hereinwereportthecomplexesofanovelmacrocyclicl2-membereddioxotetradrineligandbearingbis-hydroxygroupsasfunctionalpendantSwhichcanmindcthecatalyticfunctionofcarboxypeptidaseAinndcellarmedia.2,6-Dioxo-l,4,7,lo-tetraazacyclo1(O.2Og,1.onuno1)'anddodecylglycidylether(O.54g,2.2nunol)'wererefluxedinEtOH(3OoInL)for24h.Thesolventwase… 相似文献
985.
The current nano-technology revolution is facing several major challenges: to manufacture nanodevices below 20 nm, to fabricate three-dimensional complex nano-structures, and to heterogeneously integrate multiple functionalities. To tackle these grand challenges, the Center for Scalable and Integrated NAno-Manufacturing (SINAM), a NSF Nanoscale Science and Engineering Center, set its goal to establish a new manufacturing paradigm that integrates an array of new nano-manufacturing technologies, including the plasmonic imaging lithography and ultramolding imprint lithography aiming toward critical resolution of 1–10 nm and the hybrid top-down and bottom-up technologies to achieve massively parallel integration of heterogeneous nanoscale components into higher-order structures and devices. Furthermore, SINAM will develop system engineering strategies to scale-up the nano-manufacturing technologies. SINAMs integrated research and education platform will shed light to a broad range of potential applications in computing, telecommunication, photonics, biotechnology, health care, and national security. 相似文献
986.
本文获得了几个压缩型映射的不动点定理,改进了相应文献的结果.应用该定理,给出了一类时滞积分方程的正概周期解的存在性结果.推广了已有的结果. 相似文献
987.
Qiuhua Nie Tiefeng Xu Xiang shen Xudong Zhang 《Journal of Physics and Chemistry of Solids》2006,67(11):2345-2350
The absorption and upconversion fluorescence spectra of a series of Er3+/Yb3+-codoped natrium-germanium-bismuth glasses have been studied. The transition probabilities, excited state lifetimes, and the branching ratios have been predicted for Er3+ based on the Judd-Ofelt theory. At room temperature, an upconversion efficiency of 6.1×10−2 has been obtained for the green emission from the glass with 0.5 wt% Er2O3 and 3.0 wt% Yb2O3 pumped by 980 nm radiation with an intensity of 270 W/cm2. And the “standardized” efficiency for green upconversion light is higher than that reported in lead-germanate, lead-tellurite-germanate, and silicate glasses. The results indicate that the Er3+/Yb3+-codoped natrium-germanium-bismuth oxide glass may be a potential material for developing upconversion optic devices. 相似文献
988.
采用溶胶-凝胶旋涂法在Si(111)衬底上生长了ZnO薄膜,并用荧光光谱、原子力显微镜和XRD对ZnO薄膜样品进行了分析.结果表明,溶胶-凝胶旋涂法制备的ZnO薄膜为纤锌矿结构,其c轴取向程度与热处理温度有很大的关系.当热处理温度小于550℃时,氧化锌薄膜在室温下均有较强的紫外带边发射峰,而可见波段的发射很弱;当热处理温度高于550℃时,可见波段发射明显增强.对经过不同时间热处理的ZnO薄膜样品分析表明,氧化锌薄膜的荧光特性及表面形貌与热处理时间也有很大关系,时间过短可见波段的发射较强,但时间过长会导致晶
关键词:
ZnO薄膜
光致发光 相似文献
989.
Ce3+离子激活的SrB4O7的VUV光谱 总被引:4,自引:3,他引:1
Ce3+只有一个4f电子,具有最简单的4f15d0基态结构,其激发光谱直接反映了5d轨道的能量状态。由于同一基质晶格相同格位上不同稀土离子受基质晶体场影响相近,所以根据Ce3+离子的光谱可以推测和分析其他稀土离子的5d轨道能量,是研究其他稀土离子f-d跃迁的基础。采用高温固相法合成了Ce3+离子激活的SrB4O7发光体,测定了样品在130~350nm波长范围的激发光谱和相应的发射光谱。指认了VUV激发光谱上Ce3+离子的5个4f1→4f05d1跃迁激发带,讨论了SrB4O7的基质吸收带和Ce3+的5d轨道在SrB4O7中的晶体场劈裂、5d轨道能级重心及SrB4O7:Ce3+的发射光谱和Stokes位移。 相似文献
990.
Xiang Yang Zeng 《Applied Acoustics》2005,66(11):1309-1319
More and more literature has paid attention to the diffuse reflections in enclosed space during the past few years. In this paper, the current computer models including diffuse reflections have been reviewed briefly at first. Then, to realize the broad-spectrum simulation for enclosed sound fields including diffuse reflections, an improved ray-tracing algorithm, which combines the splitting coefficient diffusion model and a dynamic sound ray receiving method, has been given. The algorithm can deal with broad frequency bands simultaneously by using the frequency independent splitting coefficient. To test the algorithm and also to investigate the significance of the diffuse reflections in enclosed sound fields, experiments have been made in three spaces including a virtual room and two real rooms. The results and discussions have validated the applicability of the improved algorithm and they have also shown that diffuse reflections can improve room acoustic prediction, although it not always promote a sound field to be more diffused. 相似文献