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101.
利用激光驱动气库材料形成的等离子体射流对材料进行斜波加载, 可以获得高应变率的准等熵压缩. 在神光III 原型高功率激光装置上开展了激光驱动铝材料的准等熵压缩实验, 成像型速度干涉仪VISAR记录到样品自由面连续、光滑的速度历史, 采用反积分法得到60 GPa以上的峰值压强, 加载上升沿约10 ns,应变率可达108 s -1, 并且观察到了压缩波在样品后表面的反射效应. 相似文献
102.
利用红外光谱、核磁共振氢谱、紫外光谱以及质谱等表征手段对一种新型蛋白同化激素(AAS)口服药物的主成分进行了研究和鉴定,推定主成分为甲基-1-睾酮(methyl-1-testosterone, M1T, 17β-hydroxy-17α-methyl-5α-androst-1-en-3-one)。在此基础上,建立了M1T的气相色谱-质谱联用检测方法。方法的检出限(信噪比(S/N)为3)为2 ng/mL,定量限(S/N=10)为10 ng/mL;7次平行测定前处理后的加内标尿样的相对标准偏差为9.8%。用该方法测定了该药物在尿样中的排泄曲线。该方法的建立为AAS新药的发现、检测和监控做了很有意义的基础研究工作。 相似文献
103.
104.
熔体旋淬MI(NiCoMnAl)5贮氢合金的组织结构与电化学特性 总被引:6,自引:1,他引:5
对比研究了熔体旋淬和常规熔铸Ml(NiCoMnAl) 相似文献
105.
邻甲苯基异腈酸酯与3,6-二甲基-1,6-二氢-S-四嗪在催化剂4-二甲胺基吡啶存在下反应,生成标题化合物( C20H22N6O2, Mr = 378.43 )。经X-射线单晶结构分析表明此晶体属单斜晶系,P21/c空间群,a = 11.151(4),b = 15.318(2),c = 11.352(2)?,β=103.85(2)°,V = 1882.7? 3,Z = 4,μ= 0.093mm-1,Dc = 1.413g/cm3,F(000) = 800。结果表明,该化合物的两个酰胺基处于S-四嗪环的1,4位,而四嗪环本身呈船式构象。 相似文献
106.
The synthesis of filled skutterudite compounds (Ce or Y)_y(Fe)_x(Co)_(4x)(Sb)_(12), through a solidstate reaction using chloride of Ce or Y,high purity powder of Co, Fe, and Sb as starting materials,was investigated. (Ce or Y)_y(Fe)_x(Co)_(4x)(Sb)_(12) (x=0--1.0, y=0--0.15) compounds were obtained at850--1 123 K. The results of Rietveld analysis demonstrate that (Ce or Y)_y(Fe)_x(Co)_(4x)(Sb)_12synthesized by a solid state reaction possesses a filled skutterudite structure. The filling fraction ofCe or Y obtained by Rietveld analysis agrees well with the composition obtained by chemicalanalysis. The lattice constant of (Ce)_y(Fe)_x(Co)_(4x)(Sb)_(12) increases with increasing substitution of Fe at Cosites, and with an increasing Ce filling fraction in the Sb-dodecahedron voids. The lattice thermalconductivity of (Ce or Y)_y(Fe)_x(Co)_(4x)(Sb)_(12) decreases significantly with an increasing Ce or Y fillingfraction in the voids and with substitution of Fe at Co sites. 相似文献
107.
Considering the properties of slow change and quasi-periodicity of
magnetocardiography (MCG) signal, we use an integrated technique of adaptive
and low-pass filtering in dealing with two-channel MCG data measured by high
$T_{\rm c}$ SQUIDs. The adaptive filter in the time domain is based on a noise feedback
normalized least-mean-square (NLMS) algorithm, and the low-pass filter with
a cutoff at 100Hz in the frequency domain characterized by Gaussian functions is
combined with a notch at the power line frequency. In this way, both
relevant and irrelevant noises in original MCG data are largely eliminated.
The method may also be useful for other slowly varying quasi-periodical
signals. 相似文献
108.
Z-pinch experiments with two arrays consisting, respectively, of 32
4-μm- and 6-μm-diameter tungsten wires have been carried out on
QiangGuang-1 facility with a current rising up to 1.5MA in 80ns. At early
time of implosion, x-ray framing images show that the initial emission comes
from the central part of arrays, and double clear emission rings, drifting
to the anode and the cathode at 5×106cm/s and 2.4×107cm/s respectively, are often produced near the electrodes. Later,
in a 4-μm-diameter tungsten wire array, filamentation caused by ohmic
heating is prominent, and more than ten filaments have been observed. A
radial inward shift of arrays starts at about 30\,ns earlier than the
occurrence of the x-ray peak power for both kinds of arrays, and the
shrinkage rate of emission region is as high as 1.7×107cm/s in
a 4-μm-diameter tungsten wire array, which is two times higher than
that in a 6-μm one. Emission from precursor plasmas is observed in
implosion of 6-μm-diameter tungsten wire arrays, but not in implosion
of a 4-μm-diameter tungsten wire array. Whereas, in a 4-μm-diameter tungsten wire array, the soft x-ray emission shows the growth of
m=1 instability in the plasma column, which is caused by current. The
reasons for the discrepancy between implosions of 4-μm- and 6-μm-diameter tungsten wire arrays are explained. 相似文献
109.
This paper reports that DLC (diamond like carbon)/Ti and DLC films were prepared by
using pulsed laser arc deposition. R-ray diffraction, Auger electron spectroscopy,
Raman spectroscopy, atomic force microscopy, nanoindenter, spectroscopic
ellipsometer, surface profiler and micro-tribometer were employed to study the
structure and tribological properties of DLC/Ti and DLC films. The results show that
DLC/Ti film, with $I(D)/I(G)$ 0.28 and corresponding to 76{\%} sp$^{3}$ content
calculated by Raman spectroscopy, uniform chemical composition along depth
direction, 98 at{\%} content of carbon, hardness 8.2 GPa and Young's modulus 110.5
GPa, compressive stress 6.579 GPa, thickness 46~nm, coefficient of friction 0.08,
and critical load 95mN, exhibits excellent mechanical and tribological properties. 相似文献
110.
荧光法研究牛血清白蛋白与三羟基苯基荧光酮-钼(Ⅵ)配合物探针的作用机理 总被引:2,自引:2,他引:0
用荧光光谱法研究了三羟基苯基荧光酮(TH-PF)-钼(Ⅵ)配合物与牛血清白蛋白的结合反应。探讨了TH-PF-Mo(Ⅵ)配合物对蛋白质内源荧光的猝灭机理,并测定了不同温度下的结合常数,温度为25 ℃时,荧光猝灭法测得该反应的结合常数为K=4.78×104 L·mol-1,温度为40 ℃时,荧光猝灭法测得该反应的结合常数为K=3.72×104 L·mol-1。根据Frster非辐射能量转移理论,确定了给体-受体之间的作用距离和能量转移效率(E=0.314),并根据热力学参数确定了TH-PF-Mo(Ⅵ)配合物与牛血清白蛋白之间的作用力类型,以静电引力为主。 相似文献