双酞菁铒的导电性

双酞菁稀土配合物具有夹心式结构,电导率较高,在有机半导体中有广阔的应用前景。作者曾测试了双酞菁稀土在酸性及碱性气氛中的电导率,发现其电阻率变化较大。用碘掺杂后电导率提高。Yamana等测得双酞菁钕在氢气和空气中的电阻率分别为1.1ΜΩ·cm和1.9ΚΩ·cm,认为双酞菁钕在空气中的低电阻率是吸附氧的缘故。但双酞菁镥在空气、     

酞菁和酞菁铜的电子结构与光谱

用ＩＮＤＯ／ＣＩ方法研究了酞菁和酞菁铜的电子结构和紫外－可见光谱。对酞菁采用共享氢模型。酞菁铜的一个单电子位于１１ｂ１ｇ（ｄｘ＾２－ｙ＾２）的ＭＯ上。从酞菁铜与酞菁，分子对称性由Ｄ４ｈ降低为Ｄ２ｈ，谱线发生分裂。计算结果基本与实验结果相符。     

四氨基酞菁镍与碘复合物的电导

报道了用4-硝基邻苯二甲酸制得四硝基酞菁镍再经Na_2S还原而得四氨基酞菁镍的合成方法以及产物的表征。四氨基酞菁镍与碘所得到的复合物〔Ni(NH_2)_4Pc〕I_x的碘含量范围很宽(0.4≤x≤3.77),其电导率为10~(-2)～10~(-3)S/cm,比未掺杂时提高了4～6个量级,而且在空气中很稳定,放置二个月后电导率仍几乎保持不变。     

铁酞菁/氮掺杂石墨烯复合物的电化学传感研究

本文用快速简便的方法制备了铁酞菁/氮掺杂石墨烯（FePc/N-G）修饰电极,用于定量检测半胱氨酸. 采用电化学方法对修饰电极的性能进行了表征,结果表明氮掺杂石墨烯负载铁酞菁修饰电极对半胱氨酸具有更宽的线性响应范围和较高的灵敏度.     

碘掺杂双酞菁镥结构和电学性能的研究

用饱和碘蒸气掺杂双酞菁镥(Pc2LuH)得到组成为(Pc2LuH.I6)的电荷转移复合物。碘掺杂后仍保持原来Pc2LuH分子的夹心结构, 但使沿酞菁环平面方向上彼此分子间靠近。碘未取代酞菁环上的氢; 因为酞菁配位基, 特别是氮原子向碘转移的电子, 形成I3^-,这样就有了氧化态的共轭分子和还原态的I3^-分别堆砌成两个有序的分子柱, 具备了一维导体的聚集态结构, 用夹心池样品得到ρ25℃=1.58×10^2Ω.cm, ΔE=0.1eV。     

酞菁铜掺杂SnO2超微粒子复合膜的研究

在三－（２，４－二特戊基苯氧基）－一－（８－喹啉氧基）酞菁铜中掺杂ＳｎＯ２超微粒子复合成膜，发现ＳｎＯ２与酞菁铜分子之间有一定的相互作用，对酞菁铜分子的结构有一定的破坏；气敏性研究表明掺杂后导电率提高一个数量级，稳定性提高。     

C 60掺杂酞菁铜的光电特性及其SERS研究

研究了C60 掺杂酞菁铜 (CuPc)双层光导体的光电特性 ,实验结果表明C60 掺杂后 ,可提高其光电性能。对C60 掺杂酞菁铜的表面增强拉曼光谱 (SERS)研究显示 ,C60 与酞菁铜之间生成了电荷转移较小、结构比较松散的分子间电荷转移复合物。     

镥单酞菁和镥双酞菁电子转移过程的研究

本文用循环伏安法研究镥单酞菁和镥双酞菁在非水溶剂中的电化学行为,获得了相应的氧化还原反应半波电位E1/2,测定了其中四个氧化还原反应的电子转移速度常数ks。指出非水溶剂对镥单酞菁和镥双酞菁的电化学行为具有程度不同的影响。     

一种可溶性酞菁的合成、表征和近红外发光性能研究

以4-硝基邻苯二腈为起始原料合成了β-四-(4-甲氧基苯氧基)酞菁(简称MPPc),通过IR、UV-Vis、1H NMR、质谱和元素分析表征了其结构。分别用真空蒸镀和旋涂发光层的方法制备了3种器件,比较研究了它们的电致发光性能。结果表明,3种器件的电致发光波长大约在896 nm附近,器件B和C的发光强度都比器件A强,在掺杂器件C中,酞菁的质量分数为40(wt)%时其发光强度最强。     

酞菁和酞菁铜的三阶非线性光学性质

用INDO/SDCI方法研究了酞菁和酞菁铜的电子结构, 紫外-可见光谱, 三阶非线性光学系数及其色散效应, 发现酞菁铜中Cu^2+对γ的贡献很小, 故酞菁与酞菁铜的γ几乎相等, 我们的计算结果对此进行了合理的解释。     

Synthesis and crystal structure of pyridine and methanol coordinated α-octabutyloxyphthalocyaninatocobalt (II)

Crystal structure of pyridine and methanol axially coordinated 1,4,8,11,15,18,22,25- octabutyloxyphthalocyaninatocobalt(II)(viz.α-octabutyloxyphthalocyaninatocobalt) {[(n-BuO)8Pc]@Co(Py)(MeOH)} (1) was determined by X-ray diffraction methods. Crystal data: monoclinic, space group P21/n, Z = 4, a = 1.06482(4), b = 3.5487(2), c = 1.79428(9)nm, β=103.246(2)°, V = 6.5792(5) nm3, μ = 0.325 mm-1. The result shows that the ring skeleton of 1 maintains planar conformation, which is similar to that of unsubstituted phthalocyanine but is remarkably different from the saddle shapeconformation of 1,4,8,11,15,18,22,25-octabutyloxyphthalocyaninatocopper (II) {[(n-BuO)8Pc]Cu}(2), which has no axial coordination. In the structure of 1, the substituents butyloxy groups of 1 somewhat deviate from the ring plane, while pyridine and methanol are coordinated to the center atom Co from opposite sides of the ring plane. In addition, all molecules are stacked along axis a to form one-dimensional molecule chain, the neighboring molecules in the chain overlap to some extent with a benzene ring and a distance of 0.3565 nm.     

Synthesis and crystal structure of pyridine and methanol coordinated a-octabutyloxyphthalocyaninatocobalt (II)

Phthalocyanines (Pcs) have been widely used as dyes and pigments, photoelectric materials and catalysts. They also bring general attention for potential applications, for example, in solar batteries and fuel cell, charge battery, electrochromic display devices, liquid crystal, sensors and molecular devices. The Pc抯 properties, such as spectroscopic, electronic, and magnetic properties, thermostabilities, and catalytic activities, may be adjusted by modifying the molecular structure. Therefor…     

油溶非对称取代酞菁铜的合成、表征及LB膜

本文以邻苯二甲酰亚胺为原料,合成了两种新的非对称取代酞菁铜配合物:4-(对羧基苯氧基)-三-4-(2,4-二特戊基苯氧基)酞菁铜(Ⅳ)和4-(邻氨基苯氧基)-三-4-(2,4-二特戊基苯氧基)酞菁铜(Ⅴ)。并经元素分析、红外光谱、核磁共振谱、质谱、顺磁共振谱及紫外光谱,对其结构进行了表征。两种配合物都易溶于二氯甲烷、氯仿和甲苯等有机溶剂,不溶于水。配合物的氯仿溶液能在水面上展开形成单分子膜。π-A曲线测定表明,配合物在亚相液面(水)上,随着表面压力的增大,膜面积连续不停地减少,有明显的“气”“固”变化过程,表明配合物能形成较好的LB膜。分子在膜中主要以倾斜的方式排列。以Z型累积方式沉积于金制梳状电极上的LB膜能导电,属于半导体材料,碘掺杂可改善膜的电导。膜电极的气敏特性研究发现,配合物对氨气有专一的气敏特性,氨气浓度为33ppm时即有响应,且灵敏度高。     

Synthesis and crystal structure of pyridine and methanol coordinated α-octabutyloxyphthalocyaninatocobalt (II)

Crystal structure of pyridine and methanol axially coordinated 1,4,8,11,15,18,22,25-octabutyloxyphthalocyaninatocobalt(II)(viz. α-octabutyloxyphthalocyaninatocobalt) [(n-BuO)₈Pc]. Co(Py)(MeOH) (1) was determined by X-ray diffraction methods. Crystal data: monoclinic, space group P2₁/n, Z = 4, a = 1.06482(4), b = 3.5487(2), c = 1.79428(9) nm, β=103.246(2)°, V = 6.5792(5) nm³, μ = 0.325 mm^-1. The result shows that the ring skeleton of 1 maintains planar conformation, which is similar to that of unsubstituted phthalocyanine but is remarkably different from the saddle shape conformation of 1,4,8,11,15,18,22,25-octabutyloxyphthalocyaninatocopper (II) [(n-BuO)₈Pc]Cu(2), which has no axial coordination. In the structure of 1, the substituents butyloxy groups of 1 somewhat deviate from the ring plane, while pyridine and methanol are coordinated to the center atom Co from opposite sides of the ring plane. In addition, all molecules are stacked along axis a to form one-dimensional molecule chain, the neighboring molecules in the chain overlap to some extent with a benzene ring and a distance of 0.3565 nm.     

Structure of Ethanol Coordinated 1,8,15,22-Tetra-(2'''',2'''',4''''-trimethyl-3''''-pentoxy)phthalocyaninatocobalt

1 INTRODUCTION Phthalocyanine and their metal complexes are important materials for the application in advanced technologies[1]. To meet some special purposes in various applications, the introduction of certain kind of substituents to the peripheral po…     

Photocatalytic transformation of 4-nitrophenol in aqueous media using suspended,water-insoluble metallophthalocyanine complexes

Unsubstituted magnesium (MgPc), zinc (ZnPc) and chloroaluminium (ClAlPc) phthalocyanine complexes and the ring substituted zinc tetranitro (ZnPc(NO₂)₄), zinc tetraamino (ZnPc(NH₂)₄), zinc hexadecafluoro (ZnPcF₁₆) and zinc hexadecachloro (ZnPcCl₁₆), phthalocyanine complexes are employed as photocatalysts for the heterogeneous transformation of 4-nitrophenol (4-Np) to fumaric acid and 4-nitrocatechol. ClAlPc is the best catalyst, with 89 ± 8% degradation of 4-Np after 100 min. The least effective catalysts were ZnPcCl₁₆ and MgPc.     

The formation of self-assembled monolayers of thiophthalocyanine complexes of titanium, vanadium and manganese and their use in l-cysteine electrocatalysis

Self-assembled monolayers (SAMs) based on octapentylthiophthalocyanine complexes of oxovanadium (IV) (OVOPThPc), titanium(IV) (OTiOPThPc), and manganese (III) acetate (AcMnOPThPc), and of tetraphenylthiophthalocyanine complexes of hydroxo manganese(III) (OHMnTPPc) and oxotitanium(IV) (OTiTPPc) are described. The oxidation of l-cysteine was observed at potentials which ranged from 0.52 V to 0.67 V. The detection limits for l-cysteine analysis were of the order of 10^− 7 to 10^− 6 M.     

Structure of Ethanol Coordinated 1,8,15,22-Tetra-（2′,2′,4′-trimethyl-3′-pentoxy）phthalocyaninatocobalt

Crystal structure of ethanol coordinated 1,8,15,22-tetra(2′,2′,4′-trimethyl-3-pentoxy) phthalocyaninatocobalt (C64H80N8O4Co·2C2H5OH, Mr = 1176.43) was determined by X-ray diffrac- tion methods. The crystal is of monoclinic, space group P21/c with a = 16.4294(4), b = 8.0560(2), c = 24.3654(7)(A。), β = 98.3680(8)°, Z = 2, V = 3190.6(1) (A。)3, Dc = 1.225 g/cm3, F(000) = 1262, μ(MoKα) = 0.326 mm-1, the final R = 0.0865 and wR = 0.2737 for 4787 observed reflections with I ≥ 2σ(I). The bulky branched alkyloxy substituents lead to a one structural isomer and space the phthalocyanine molecules where two ethanol molecules coordinate to the cobalt atom from two sides of each molecule.     

A new polymeric phthalocyanine containing 16-membered tetrathia macrocyclic moieties by microwave irradiation: Synthesis and characterization

Tetranitrile monomer (3) was synthesized by nucleophilic aromatic substitution of 1,5,9,13-tetrathiacyclohexadecane-3,11-diol (1) onto 4-nitrophthalonitrile (2). The metal-free phthalocyanine polymer (4) was prepared by the reaction of a tetranitrile monomer with 4-({11-[3-cyano-4-(cyanomethyl)phenoxy]-1,5,9,13-tetrathiacyclohexadecan-3-yl}oxy)phthalonitrile in 2-(dimethylamino)ethanol. Ni(II), Co(II), Cu(I)-phthalocyanine polymers were prepared by the reaction of the tetranitrile compound with the chlorides of Ni(II), Co(II) and Cu(I) in DMAE. Zn(II)-phthalocyanine polymer was prepared by the reaction of the tetranitrile compound with the acetates of Zn(II) in DMAE. The new compounds were characterized by a combination of IR, ¹H NMR, ¹³C NMR, UV-Vis, elemental analysis and MS spectral data.     

The syntheses and photophysical properties of 4,4′-isopropylidendioxydiphenyl substituted ball-type dinuclear Mg(II) and Zn(II) phthalocyanines

The syntheses of ball-type dinuclear Zn(II) and Mg(II) phthalocyanines containing four 4,4′-isopropylidendioxydiphenyl substituents at the peripheral and non-peripheral positions are presented. The structures of the synthesized compounds were characterized using elemental analyses, and UV-Vis, FT-IR, ¹H NMR and mass spectroscopies. The Φ_F values were 0.14, 0.11, 0.22, 0.15 and Φ_T values were 0.84, 0.88, 0.62, 0.74, for 6-9, respectively. The largest triplet yields were observed for the non-peripherally substituted complexes 6 and 7, showing that non-peripheral substitution favors increased population of the triplet state. All complexes showed reasonably long triplet lifetimes with τ_T 510, 310, 910 and 350 μs in DMSO, respectively.