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本文采用722S型分光光度计的串行口与计算机通信,构建了基于LabVIEW测定药物有效期的虚拟仪器系统,实现了分光光度计的时间扫描、数据储存、数据处理与结果生成等,避免了人工测定时需要多人协同操作的繁琐和人为误差,提高了测量的精确度。应用该系统测得硫酸链霉素溶液的有效期为250 min,其反应的活化能为67kJ/mol,同时在相同实验条件下,人工实验测定该硫酸链霉素溶液的有效期为231min,反应的活化能为65kJ/mol,效果良好,且该系统还具有人机对话友好、操作简单、功能易扩展等诸多优点。 相似文献
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以磁学测量系统(magnetic property measurement system, SQUID)为主体,LabVIEW图形化编程语言为软件开发平台,利用magnetic property measurement system(MPMS)的扩展接口,由GPIB卡连接Keithley 2400源表、2182A纳伏表等测量仪表,构建实时输入测量参数、采集环境数据、直观显示测量结果的电学性能测试系统. 系统能准确控制温度、磁场,调节范围广,在温度1.9~400 K、磁场0~7 T的环境下,实现I-V曲线、电阻随温度(R-T)曲线、电阻随磁场(R-H)曲线等的电学性能测量,拓展MPMS磁学测量系统功能和应用研究领域. 相似文献
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编程实现了基于LabVIEW的一维和二维无限深势箱中粒子能级与波函数的可视化程序,该程序能完成粒子量子效应图形化、实时绘制波函数、概率密度波函数及波函数概率区间的精确求解。应用表明:该基于LabVIEW的可视化程序根据势箱中粒子Schrödinger方程及其通解,将书本复杂的理论知识联系实际编程实现波函数图形化和自动完成精确计算任务,该程序改进和优化了教学方法,加强了理论学习效果,提高了教学质量;同时基于LabVIEW开发的可视化程序具有编程直观高效、界面友好、功能易扩展等优点。 相似文献
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恒电位仪是腐蚀电化学测量最重要的基本设备.虚拟恒电位仪用图形程序软件取代复杂硬件来实现恒电位功能.它的结构和参数灵活,构建简单,能满足多方面腐蚀电化学测试方法的需求,虚拟恒电位仪的实现是发展虚拟腐蚀电化学仪器的重要步骤.本文采用LabVIEW 2010编程系统和比例-积分-微分(PID)控制技术,研制了虚拟恒电位仪,并组建了VEC11-A腐蚀电化学测试系统,该系统能满足不同阻抗体系的腐蚀电化学测试需求.其腐蚀电位、稳态极化曲线、线性极化曲线、循环伏安、动电位扫描、恒电位阶跃等常规腐蚀电化学测量结果与2263电化学测试系统相近,能够满足常规腐蚀电化学测试要求,具有很大的发展空间. 相似文献
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编程实现了基于LabVIEW的氢原子及类氢原子不同能级波函数的等密度线可视化程序,该程序能自动完成波函数ψ2nlmr,θ,φ在不同角度(θ,φ)时随r变化的曲线及任意截面等密度线图的绘制。应用表明:该程序对氢原子及类氢原子波函数立体图形全局有一个非常直观的描述,能够直观地反映原子、分子的电子结构,并给出立体图不能反映的细节,有助于对化学反应过程、成键本质的理解。同时基于LabVIEW开发的可视化程序具有编程直观高效、界面友好、功能易扩展等优点。 相似文献
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A large computer system for on-line data acquistion and analysis of data from analytical instruments
Summary Experience with a unique large dual processor system designed to acquire and analyze data from about 140 instruments in a research installation will be described. The system has been in operation for nearly 4 years serving a variety of analytical instruments including gas chromatographs, liquid chromatographs, tensile testing machines, differential thermal analyzers, and other miscellaneous instruments. The system also serves a large community of scientific time-sharing users, a substantial portion of which reduce data and carry out scientific calculations on data acquired off-line on paper or magnetic tape. Unique features of the system are long distance transmission of analog data, retention of raw data for reanalysis, post processing of data into material balance, kinetic or statistical equations, interactive graphical display of the data acquired on-line and the ability to monitor instrument performance. Another unique features is the ability to develop new analysis programs in time-sharing without fear of jeopardizing the integrity of the data collection process. 相似文献
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A. L. Voskov I. A. Uspenskaya 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2009,83(4):604-608
The literature data on the thermodynamic properties and phase equilibria in the copper-gadolinium system were generalized. A set of thermodynamic model parameters for system phases that best described these data were obtained. The phase diagram of the system over the temperature range 300–2000 K at a pressure of 1 bar was calculated. 相似文献
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A dual-processor system based on the multibus is described for electroanalytical measurements. Although the hardware configuration is limited, the system is effective for real-time monitoring and control and teh throughput is enhanced. Data acquisition and data processing are divided into consecutive tasks running on separate processors, so that the flexibility of data acquisition is improved. The performances of the multibus-based system and a single processor are compared. 相似文献
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A new method of data acquisition,proceeding and data share is introduced and a data acquisition and transfer system targeting in-situ spectroscopic analysis in metallurgy is established. This system is designed for the critical control of steelmaking, which greatly requires rapid and suitable information feedback. The information includes analysis data, measurement data and controls. The analysis data are acquired from the serial port of the computer-aided spectrometers or other devices and are identified, converted and then stored to the standard database in a network server. The network is based on the Intranet structure and works on the Windows NT operation system. It supports remote access and Internet connection so that the analysis data can be shared,proceeded and developed by certified personnel throughout the network. A set of specially designed data transfer devices with display panel are used in the severe places to display real-time analysis data and other information, which are offered from the nearest workstation on the network. These devices are dust-proofed and anti-magnetic. Each device offers up to 30 terminals with the limited distance of 3000 meters at 2400 baud-rates under the industrial condition. The application program for the data proceeding is integrated to the system. It includes system security, data acquisition, data transfer, data process and display. It also includes auxiliary functions such as operation help, system's resources monitoring and other customer-defined parameters. The software's functions directly related to the system are detailed discussed. Associated with another management and control software programmed for this system,the critical control of steelmaking can be approached. 相似文献
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Akira Yamasaki 《Analytica chimica acta》1981,133(4):741-746
The TOOL-IR. PDB and COOD systems are compared for the construction of data bases for 59Co-n.m.r. bibliographic and spectral data. The spectral data used are the chemical shifts from several different standards, and the line widths and coupling constants (if present). The PDB system is effective for storage and retrieval of bibliographic data, but the COOD system is better for the retrieval of spectral data, and for combination of data files on literature and chemical shifts. 相似文献
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V L Bond C M Bowman L C Davison P F Roush R D McGrew D G Williams 《Journal of chemical information and computer sciences》1979,19(4):231-234
An improved interactive system for searching substructure and biological activity data has been developed. Features of the system include a two-level substructure search (fragment screen and atom by atom) and an expanded biological activity data base. The system operates on a file of about 150 000 compounds. 相似文献
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研制开发基于化学计量学的通用化学数据采集处理系统,该系统硬件采集部分,可与模拟信号输出的分析仪器或有RS-232接口的分析仪器联接进行数据采集,软件部分的数据处理基于化学计量学理论知识,相应数据处理方法,可从采集到数据中获取大量的信息。软件部分的信息管理包含了大量实验要素的归整、查询和统计等。 相似文献
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F. Garay 《Chromatographia》2000,51(1):S108-S120
Summary A capillary column gas chromatographic system employing two serially coupled fused-silica columns and a simple coupling element
is described. The system is operated in flow-tunable mode (flow-tunable tandem system).
The very fact of continuous tuning over a large polarity (selectivity) range, ultimately determined by the two constituent
columns, offers several possibilities in the analysis of complex mixtures. In this paper two applications are discussed in
detail: optimization of peak separation and peak identification. For these applications it is feasible to use, retention data
collected from experiments on the tandem system, and empirical formulas. A relatively simple theoretical mathematical model
valid for the flow-tunable tandem system, however, furnishes an easy way of calculating retention data on the system from
data collected from the individual single columns, thus, creating a new possibility for optimization and peak identification.
Optimization and peak identification processes using the empirical and theoretical models are both demonstrated by analysis
of solvent mixtures.
Dedicated to the memory of Dr. Tibor Tóth
Presented at Balaton Symposium on High-Performance Separation Methods, Siófok, Hungary, September 1–3, 1999 相似文献
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The measured partition data of 26 steroids for six different compositions of ternary liquid-liquid systems consisting of 2,2,4-trimethylpentane, ethanol and water are used in calculations of partition data for new phase system compositions. It was possible to reproduce the original data and to verify new experimental data by this calculation with high accuracy. Calculations were done in three ways. In the first, non-linear regression of the partition coefficients as a function of the phase system composition was examined. With this classical approach it is possible to calculate the values of the partition coefficients, solute by solute, with good accuracy. In the second approach, principal component factor analysis was used. The phase system-specific factors for further phase system compositions were calculated with a non-linear regression of these factors on the phase system composition. In combination with the solute-specific factors, the values of the partition coefficients for all solutes in any phase system composition could be predicted with excellent accuracy. In the third approach, target transformation factor analysis was applied. A relationship between the partition coefficient and the phase system composition was established on the basis of either the phase system composition itself or a simple function of it. This method also gave very accurate predictions of known and unknown partition coefficients. 相似文献