共查询到20条相似文献,搜索用时 31 毫秒
1.
以天然鳞状石墨为原料,采用化学氧化法合成氧化石墨,在此基础上采用低温热解膨胀结合微波加热乙二醇还原法合成石墨烯(Gr)以及铂/石墨烯(Pt/Gr)复合材料。SEM和TEM显示所制备的石墨烯为层状结构的半透明薄膜。采用X射线光电子能谱(XPS)和傅立叶转换红外光谱(FTIR)分别确定氧化石墨、膨胀石墨及石墨烯表面含氧官能团的数量和性质。以所制备的碳氧原子比5.94的石墨烯作为载体制备出可用于质子交换膜燃料电池的高负载量的Pt/Gr催化剂,在铂载量高达60%时,表面铂粒子依然具有高分散性,平均粒径为3.8 nm。 相似文献
2.
3.
Yushu Liu Chun Gao Qing Li Prof. Dr. Huan Pang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(9):2141-2160
Nickel oxide (NiO) has emerged as one of the most promising transition-metal oxides (TMOs) for electrochemical capacitors, batteries, catalysis, and electrochromic films, owing to its cost-effectiveness, abundance, and well-defined electrochemical properties. Recent studies have identified that mixing NiO with graphene or graphene derivatives results in novel composites with synergistic effects and superior electrochemical performance. This review summarizes the latest advances in composites of NiO with graphene or graphene derivatives. The synthetic strategies, morphologies, and electrochemical performance of these composites are introduced, as well as their electrochemical applications in supercapacitors, batteries, sensors, catalysis, and so forth. Finally, tentative conclusions and assessments regarding the opportunities and challenges for the future development of these composites and other TMOs/graphene or graphene-derived composites are presented. 相似文献
4.
使用简单的溶液共混的方法制备了氧化石墨烯/聚甲基丙烯酸甲酯(GO/PMMA)和表面官能化的石墨烯/聚甲基丙烯酸甲酯复合材料.通过透射电镜(TEM),扫描电镜(SEM)和原子力显微镜(AFM)观察了石墨烯及复合材料的表观形貌.通过拉伸实验表征了其力学性能,研究发现随着石墨烯的加入,其拉伸强度和断裂伸长率都有所改善,而且表面官能化的石墨烯的复合材料的改善效果要优于氧化石墨烯. 相似文献
5.
《Electroanalysis》2017,29(3):652-661
The modifications of electrodes using graphene and graphene composites in microbial fuel cells (MFCs) and microbial electrolysis cells (MECs) have been widely applied for enhancing the electrochemical catalytic activity and performance of MFCs and MECs. Graphene as one of advanced materials has shown outstanding features for promoting practical applications of MFCs. This review summarizes the modification methods and characterization methods of graphene and related graphene composites on electrode surfaces in MFCs and MECs. The performance improvements of MFCs and MECs by various graphene related composites have been reviewed, which will provide an efficient guide for selecting suitable graphene material to modify electrodes in MFCs and MECs for improving their performance. 相似文献
6.
Anna‐Katharina Appel Ralf Thomann Rolf Mülhaupt 《Macromolecular rapid communications》2013,34(15):1249-1255
Graphene functionalization by hydroxyalkylation and grafting with polyether polyols enables polyurethane (PU) nanocomposites formation by in situ polymerization with isocyanates combined with effective covalent interfacial coupling. Functionalized graphene (FG) hydroxylation is achieved either by alkylation, transesterification, or grafting of thermally reduced graphite oxide. In the presence of K2CO3 as catalyst the reaction of FG‐OH with ethylene carbonate at 180 °C affords hydroxyethylated FG, whereas transesterification with castor oil produces riconoleiate‐modified FG polyols. In the “grafting‐from” process, FG‐alkoholate macro initiators initiate the graft polymerization of propylene oxide to produce hybrid FG polyols containing 38 and 59 wt% oligopropylene oxide. In the “grafting‐to” process 3‐ethyl‐3‐hydroxymethyl‐oxetane is cationically polymerized onto FG‐OH, producing novel hyperbranched FG‐based polyether polyols. Whereas hydroxylation and grafting of FG greatly improve FG dispersion in organic solvents, polyols and even PU, as confirmed by transmission electron microscopy, matrix reinforcement of FG/PU is impaired by increasing alkyl chain length and polyol graft copolymer content.
7.
通过热还原法成功地制备出了柔性复合织物电极石墨烯/棉布(graphene/cotton)。热还原条件对电极的导电性能具有较大的影响。导电柔性织物电极graphene/cotton特有的多级结构使其既有利于进一步负载膺电容材料,又有利于电子和电解质离子的传输与扩散。通过电化学沉积方法,利用导电柔性织物电极graphene/cotton进一步制备出了电极MnO2/graphene/cotton。利用扫描电子显微镜(SEM),傅里叶变换红外(FTIR)光谱,四探针测试法等表征技术对电极的结构进行了较为详细的表征。结果表明电极MnO2/graphene/cotton的比电容可以达到536 F·g-1。良好的电化学性能和柔性使得此类电极在柔性储能材料应用中具有极大的应用前景。 相似文献
8.
9.
手性科学与手性材料的重要性日益凸显. 本课题基于氧化石墨烯(GO)和生物质胆酸(CA), 建立了一种利用Click技术对GO进行手性功能化的化学方法, 同时制备一类具有手性的新型氧化石墨烯杂化材料. 以石墨粉为原料, 采用改进的Hummers法制备了氧化石墨烯, 之后引入N3基团; 同时将胆酸炔丙基化. 通过点击化学技术制备了胆酸手性化氧化石墨烯杂化材料(CA/GO). 利用FT-IR, XRD, 拉曼光谱, UV-Vis吸收, 热重等技术对所制备的CA/GO手性杂化材料进行了表征. 相似文献
10.
11.
石墨烯/聚苯胺复合材料的制备及其电化学性能 总被引:1,自引:0,他引:1
以苯胺和氧化石墨烯(GO)为原料, 采用电化学方法制备了石墨烯/聚苯胺(GP)复合材料. 利用X射线衍射(XRD)、扫描电镜(SEM)、拉曼(Raman)光谱、X射线光电子能谱分析(XPS)对其结构、微观形貌进行了表征,并对复合材料电化学性能进行了测试. 结果表明, 复合材料保持了石墨烯的基本形貌, 聚苯胺颗粒均匀地分散在石墨烯表面, 复合材料在500 mA·g-1的电流密度下比电容达到352 F·g-1, 1000 mA·g-1下比电容为315 F·g-1, 经过1000 次的充放电循环后容量保持率达到90%, 远大于石墨烯和聚苯胺单体的比电容. 复合材料放电效率高, 电解质离子易于在电极中扩散和迁移. 相似文献
12.
13.
14.
15.
16.
Injectable hydrogels have attracted a lot of attention in drug delivery, however, their capacity to deliver water-insoluble or hydrophobic anti-cancer drugs is limited. Here, we developed injectable graphene oxide/graphene composite supramolecular hydrogels to deliver anti-cancer drugs. Pluronic F-127 was used to stabilize graphene oxide (GO) and reduced graphene oxide (RGO) in solution, which was mixed with α-cyclodextrin (α-CD) solution to form hydrogels. Native hydrogel was used as control. GO or RGO slightly shortened gelation time. The storage and loss moduli of the hydrogels were tracked by dynamic force measurement. The storage modulus of GO or RGO composite hydrogels was larger than that of the native hydrogel. Hydrogels were unstable in solution and eroded gradually. GO or RGO in Pluronic F-127 solution could potentially improve the solubility of the water-insoluble anti-cancer drug camptothecin (CPT), especially with large drug-loaded CPT amount. Drug release behaviors from solutions and hydrogels were characterized. The nanocomponents (GO or RGO) were able to bind more drug molecules either for CPT or for doxorubicin hydrochloride (DXR) in solution. Therefore, GO or RGO composite hydrogel could potentially enable better controlled and gentler drug release (for both CPT and DXR) than native hydrogel. 相似文献
17.
18.
成功地合成了石墨烯/CdTe量子点复合物,并采用透射电镜、紫外吸收光谱、荧光发射光谱、荧光衰减曲线和X射线光电子能谱对产物进行了表征。透射电镜结果显示CdTe量子点被修饰于石墨烯的表面;X射线光电子能谱结果表示石墨烯在合成过程中被还原,还表明在所合材料的表面具有羧基和羟基;荧光发射光谱和荧光衰减曲线的结果显示将CdTe量子点修饰于石墨烯表面显著提高了CdTe量子点的荧光性能。此外,基于克伦特罗和石墨烯/CdTe量子点复合物之间形成的氢键,所合成材料可用于定量分析克伦特罗。克伦特罗对石墨烯/CdTe量子点复合物具有显著的猝灭作用,荧光强度的降低(F0/F)与克伦特罗之间存在良好的线性关系,线性范围为7.22~108.30 μmol·L-1,检出限为4 μmol·L-1。 相似文献
19.