共查询到19条相似文献,搜索用时 156 毫秒
1.
2.
3.
在热导率沿试样厚度按指数规律渐变的假设下,利用两种基本数学变换,求解了非均匀材料的热传导方程,得到了试样内及与其相邻媒质内的温度场解析解。再根据光热光偏转理论,确定了检测光束切向偏转分量的位相与调制频率之间的函数关系,如果利用熟知的由检测光束法向偏转分量测定试样热扩散率的技术,测定试样两表面的热扩散率,这样就可以由Mirage效应的两个偏转分量来测定试样热扩散率沿厚度方向的分布。本文给出有关的理论推导,同时也给出了人造金刚石试样内热扩散率分布的实验结果。 相似文献
4.
5.
采用固相烧结工艺制备了Sr2YRu1-xZnxO6(x=0,0.1,0.2)陶瓷样品,采用多晶X射线和扫描电子显微镜技术对样品的物相成分、晶体结构和晶体表面形貌进行了表征与分析,将Sr2YRu1-xZnxO6(x=0,0.1,0.2)样品X射线衍射谱与理论模拟多晶样品X射线标准谱比较显示样品单相已经形成.X射线的实验结果表明:样品均形成了在a-b方向上具有双倍周期的钙钛矿结构,属于立方晶系,晶体空间群为Fm3m(No 225).Sr2YRuO6原胞为立方结构(a=0.816 4 nm),Y离子和Ru离子分别有序占据4a(0,0,0)和4b(1/2,1/2,1/2)原子等效位置.并且发现样品X射线衍射谱中的(111)衍射峰为B位Y离子和Ru离子有序占据时的特征峰.实验显示Zn离子取代Ru离子对晶胞参数影响很小.振动样品磁强计(VSM)测量了在常温下样品Sr2YRu1-xZnxO6(x=0,0.1,0.2)磁化强度与磁场强度的关系,样品在常温下显示顺磁性.计算得到Sr2YRuO6中Ru离子的有效磁矩为2.417 μB.用标准的四端子测量方法测量了样品的电阻随温度的关系,样品电阻随掺杂量的增加而降低,并且实现了由反铁磁绝缘体向半导体转变. 相似文献
6.
采用高温固相反应按化学式Sr4-xCaxAl14O25:Eu2+,Dy3+(x=0,0.8,1.6,2.4,3.2,4)配比原料,合成长余辉发光材料.X射线衍射分析表明当x2.4时,产物物相均为Sr4Al14O25正交结构;当x2.4时,产物物相转变为CaAl4O7单斜结构.对掺Ca量不同,但结构仍保持Sr4Al14O25的样品采用360nm激光照射,发射光谱表明样品发光均由以Eu2+为发光中心的电子4f65d→4f7跃迁所致,并且随着Ca掺入量的增加,样品发射光谱峰位逐渐蓝移.这是由于Ca2+取代Sr2+位置后,导致晶格收缩,影响Eu2+的5d能级劈裂情况,从而影响电子4f65d→4f7跃迁.余辉衰减检测和热释光谱分析发现,不同Ca掺入量的样品余辉衰减快慢不同,是由于其中存在的陷阱能级深度不同,且陷阱能级越深,其余辉时间越长. 相似文献
7.
8.
9.
10.
研究了Sr2Fe1-xAlxMoO6(0≤x≤0.30)系列多晶样品的磁学和输运性质.室温X射线衍射谱图的精修结果显示Al3+掺杂没有改变样品的晶格结构,但提高了Sr2FeMoO6晶格的阳离子有序度.5K时样品的磁化曲线说明平均单位分子饱和磁矩随着Al含量的增加而下降,但平均单位Fe离子磁矩却逐渐提高.磁化曲线的拟合结果显示样品内反铁磁相互作用对饱和磁矩的贡献随着Al含量的增加而下降,说明一定量的Fe离子被Al替代后,抑制了样品内Fe-O-Fe反相边界的形成,从而提高了Sr2FeMoO6晶格的阳离子有序度和平均单位Fe离子磁矩.对饱和磁矩的分析表明非磁性Al3+离子掺杂会形成无磁相互作用的Mo-O-Al-O-Mo区,可以将原来较大的Mo-O-Fe亚铁磁区分割成许多小的区域,并且使这些亚铁磁区间的磁耦合作用变弱,从而提高了低场磁电阻效应.阳离子有序度的提高使来源于自旋相关电子在反相边界处散射的高场磁电阻明显降低,导致了样品的磁电阻在x=0.15时达到了最大值. 相似文献
11.
Laser-induced thermal lens study of the role of morphology and hydroxyl group in the evolution of thermal diffusivity of copper oxide 下载免费PDF全文
The paper explores the evolution of thermal behavior of the material by studying the variations in thermal diffusivity using the single beam thermal lens (TL) technique. For this purpose, the decomposition of Cu(OH)2 into CuO is studied in a time range up to 120 h, by subjecting the sample to morphological, structural, and spectroscopic characterizations. The time evolution of thermal diffusivity can be divided into three regions for demonstrating the dynamics of the reaction. When the reaction is complete, the thermal diffusivity is also found to be saturated. In addition to the morphological modifications, from rods to flakes, the variations in the amount of hydroxyl group are attributed to be responsible for the enhancement of base fluid's thermal diffusivity by 165%. Thus the study unveils the role of hydroxyl groups in the thermal behavior of CuO. 相似文献
12.
Thermoreflectance and photodeflection combined for microscopic characterization of metallic surfaces
A non-contact technique is presented that provides information on thermal diffusivity at the cubic micron scale in metal surfaces.
It relies on the simultaneous fit of the frequency dependence of two mechanisms that appear when heating the surface of the
sample with a modulated laser beam, the thermoreflectance (change in reflectivity with temperature) and photodeflection (the
deflection of the beam due to the surface deformation). A complete analytical model is presented that takes both mechanisms
into account, showing that the relative importance of both mechanisms depends strongly on the material under test and varies
in several orders of magnitude between different metallic alloys. By filtering the reflected signal with an adjustable knife
edge, the photodeflection signal can be enhanced. It is also shown how the signal arising from each mechanism depends strongly
on the relative position of the pump and probe beams. A characteristic modulating frequency appears at which a drop in the
signal with frequency is observed that is coincident for both mechanisms. From the determination of the characteristic frequency,
the local heat diffusivity can be determined as it is shown for the case of an AISI304 stainless steel sample.
PACS 78.20.Nv; 65.40.-b; 72.15.Eb 相似文献
13.
�Ա��������Ƿ����ߴ�������ƽ�������岨��������������� 《核聚变与等离子体物理》2013,33(3):283-288
Thermal diffusivity of reduced activation ferritic/martensitic (RAFM) steel CLF-1 has been determined by the modified photoacoustic piezoelectric (PAPE) technique. Firstly, the modified PAPE theoretical model is introduced and the experimental condition with high measurement precision are identified; Secondly, the experimental system is set up and calibrated by investigating the thermal diffusivity of nickel; Finally, the thermal diffusivity of RAFM steel CLF-1 is measured by the modified PAPE method. The results show that the RAFM steel CLF-1 has good thermal diffusion properties and is a fusion reactor structural material with excellent heat conductivity. The modified PAPE technique can determine the thermal diffusivity of RAFM steel CLF-1effectively, and provides an effective way to investigate the thermal-physical property of fusion reactor structural material. 相似文献
14.
S.D. George P. Radhakrishnan V.P.N. Nampoori C.P.G. Vallabhan 《Applied physics. B, Lasers and optics》2003,77(6-7):633-637
Laser induced transverse photothermal deflection technique has been employed to determine the thermal parameters of InP doped with Sn, S and Fe as well as intrinsic InP. The thermal diffusivity values of these various samples are evaluated from the slope of the curve plotted between the phase of photothermal deflection signal and pump-probe offset. Analysis of the data shows that heat transport and hence the thermal diffusivity value, is greatly affected by the introduction of dopant. It is also seen that the direction of heat flow with respect to the plane of cleavage of semiconductor wafers influences the thermal diffusivity value. The results are explained in terms of dominating phonon assisted heat transfer mechanism in semiconductors . PACS 78.20.Nv; 66.30.Xj; 61.72.Vv 相似文献
15.
G. Leahu R. Li Voti C. Sibilia M. Bertolotti V. Golubev D. A. Kurdyukov 《Optical and Quantum Electronics》2007,39(4-6):305-310
In this paper the thermal and optical properties of the SiO2/GaN synthetic opals are studied by photothermal deflection technique. This technique, used in different configurations, allows
to determine the effective thermal diffusivity and the absorption spectra. 相似文献
16.
Xiao Liantuan Li Changyong Zhang Linjie Zhao Yanting Jia Suotang Zhou Guosheng 《中国光学快报(英文版)》2000,9(6)
The pulsed-laser pumped photothermal deflection spectroscopy (PPDS) is applied to measure liquid thermal diffusivity in a modified collinear configuration. Here the pulsed beam is regarded as in the form of a Dirac delta function. The experiment setup used is described. Measurement result for the thermal diffusivity of a liquid sample(magnta/ethanol saturated solution) is reported. The measurement error is less than 3%. 相似文献
17.
XIAO Liantuan LI Changyong ZHANG Linjie ZHAO Yanting JIA Suotang ZHOU Guosheng 《Chinese Journal of Lasers》2000,9(6):538-544
1 Introduction Thermaldiffusivitymeasurementisparticularlyimportantformaterialsofnewconceptioninordertocontroltheirmanufacturingprocess .Atthesametime ,thedeterminationofliquidthermaldiffusivityisalsoimportantwhentheliquidisusedasacoolantforhigh powera… 相似文献
18.
Study on thermal diffusivity of materials by laser photothermal reflection technique 总被引:1,自引:0,他引:1
A method of measuring thermal diffusivity of materials at room temperature by photothermal reflection technique is described. An intensity-modulated Ar+ laser beam is used as incident light. The beam is focused to about 1 mm diameter spot and illuminates the sample surface. HgCdTe infrared detector is used to receive photothermal signal. Using this technique, the photothermal signals are experimentally measured as the function of different frequencies. The thermal diffusivities can be obtained by fitting the experimental data. On the other hand, the thermal diffusivities of one-way composite and orthogonal symmetric arranged composites Al2O3/Al are measured in transverse, longitudinal and arbitrary directions. The results show that the diffusivity of one-way material decreases with the increase of the measurement angle; the diffusivity of orthogonally arranged material almost keeps the same when measurement angle changes. 相似文献
19.
T. Kawahara M. Miyazaki A. Kimura Y. Okamoto J. Morimoto T. Miyakawa 《Applied Physics A: Materials Science & Processing》1999,69(3):343-346
The noncontact imaging of the buried structures is carried out in the open-air atmosphere by using the photothermal deflection
(PTD) method. We applied these techniques to the layered samples. Besides the PTD images for the optically opaque buried structures,
the parameters of the materials such as thermal diffusivity can also be calculated from the PTD amplitude and phase signal
in the PTD scanning images. When the PTD signals at two different modulation frequencies are used, the thermal diffusivity
of the buried structure can be obtained from the PTD signal outside of the sample nondestructively.
Received: 27 November 1998 / Accepted: 18 March 1999 / Published online: 7 July 1999 相似文献