共查询到20条相似文献,搜索用时 140 毫秒
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本文主要研究了CO2的三种同位素分子16O12C16O , 16O12C17O ,16O13C17O 70 K~6000 K的总内配分函数 (TIPS)。在总内配分函数的计算中, 转动配分函数的计算采用了McDowell的解析式法, 振动配分函数则采用了简谐振动近似(HOA)获得。最后通过将两配分函数乘积近似计算得出TIPS, 并将其70~3000 K的数据和HITRAN04数据进行了比较, 发现所得结果和数据库符合的较好, 且其误差可以近似看成一条直线。并通过对误差的拟合修订了高温区(3000~6000 K)的计算数据, 给出了在高温下的较为准确的TIPS值。 相似文献
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S. A. Gridnev A. G. Gorshkov E. S. Grigor’ev Yu. E. Kalinin 《Bulletin of the Russian Academy of Sciences: Physics》2010,74(9):1272-1276
The magnetoelectric effect in two- and three-layered composites based on nickel-zinc ferrite and lead zirconate-titanate was
investigated. The value of the magnetoelectric response in layered composites depends largely on the frequency of the alternating
magnetic field, the volume ratio of the electric phase forming the composite, and the mechanical interaction between magnetostriction
and piezoelectric layers. 相似文献
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Jianhua Wang Kang Li Sayipjamal Dulat Yi Yuan Kai Ma 《International Journal of Theoretical Physics》2012,51(8):2639-2647
By studying the scattering process of scalar particle pion on the noncommutative scalar quantum electrodynamics, the non-commutative amendment of differential scattering cross-section is found, which is dependent of polar-angle and the results are significantly different from that in the commutative scalar quantum electrodynamics, particularly when cosθ∼±1. The non-commutativity of space is expected to be explored at around ΛNC∼TeV. 相似文献
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O.N. Ulenikov E.S. Bekhtereva O.L. Petrunina H. Bürger 《Journal of Molecular Spectroscopy》2003,219(1):13-29
The P-H stretching bands ν1/ν5 and 2ν1/ν1+ν5 were recorded using a Bruker 120 HR interferometer with a resolution of 0.0042 and 0.0088 cm−1, respectively, and analyzed. From the fits 33 and 50, respectively, vibrational, rotational, centrifugal distortion, and resonance interaction parameters were obtained. These reproduce 668 and 497 rovibrational energies of the pairs of states ν1/ν5 and 2ν1/ν1+ν5 with experimental accuracies, rms=0.00016 and , respectively. “Local mode” behavior of the PH2 fragment is established and discussed in detail. 相似文献
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H. Albrecht H. Ehrlichmann T. Hamacher R. P. Hofmann T. Kirchhoff A. Nau S. Nowak H. Schr?der H. D. Schulz M. Walter et al. 《Zeitschrift fur Physik C Particles and Fields》1992,56(3):339-345
An analysis of the decay --0
v
has been performed using the ARGUS detector at the DORIS II storage ring. The branching ratio has been determined to be Br(--0
v
=(22.6±0.4±0.9)%. The shape of the -0 invariant mass spectrum is found to be in good agreement with the predictions obtained using the conserved vector current (CVC) hypothesis, suggesting that the -0 system is produced in aJ
P=1– state. An analysis of the measured decay angular distribution of the pions with respect to the flight direction of the -0 system demonstrates the vector nature of the coupling at the v
vertex. With the assumption of zerov
mass thev
spin has been shown to be
.Supported by the German Bundesministerium für Forschung und Technologie, under contract number 054DO51 P 相似文献
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本文用X射线和差热分析方法对BaO-Li2O-B2O3三元系中的两个截面:BaB2O4-Li2B2O4和BaB2O4-Li2O作了研究。在BaB2O4-Li2B2O4赝二元系中发现了一个新的化合物4BaB2O4·Li2B2O4。化合物在930±3℃由包晶反应形成,并与Li2B2O4形成共晶反应。共晶温度为797±3℃,共晶点组分为79mol%Li2B2O4。在BaB2O4-Li2O截面中也存在化合物4BaB2O4·Li2B2O4,其包晶反应温度从930±3℃随Li2O含量增加下降到908±3℃。在组分60mol%Li2O处形成另一个新的化合物2BaB2O4·3Li2O。该化合物在630±3℃也是由包晶反应形成,并与Li2O和Li2CO3分别形成共晶反应,共晶温度分别为400±3℃和612±3℃。在BaB2O4-Li2B2O4和BaB2O4-Li2O体系中都没有观察到固溶体。用计算机程序分别对化合物4BaB2O4·Li2B2O4和2BaB2O4·3Li2O的X射线粉末衍射图案进行了指标化,其结果:4BaB2O4·Li2B2O4的空间群为Pmma,a=13.033?,b=14.630?,c=4.247?,每个单胞包含两个化合式单位;2BaB2O4·3Li2O的空间群为Pmmm,a=4.814?,b=9.897?,c=11.523?,每个单胞也含有两个化合式单位。
关键词: 相似文献
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采用磁控溅射,紫外线光刻和离子束刻蚀制备了La2/3Ca1/3MnO3/Eu2CuO4/La2/3Ca1/3MnO3磁性隧道结.通过对获得的磁性隧道结的I-V特性测量,发现非线性的I-V特性,显示结样品的隧穿特性.有趣的是发现在电极材料La2/3Ca1/3MnO3的金属-绝缘体转变温度(Tp)以下,I-V曲线出现一个跳变.随着温度降低,开始出现跳变的临界电流增大,但是跳变都发生在同样的电压下~209mV.当电流增大或减小在跳变点附近出现回滞.这一跳变只发生在铁磁金属态,表明这是一个磁性相关联的效应,可能对应一种新的磁性开关过程.虽然,目前对这一现象背后的物理机理还不清楚,但是,这一现象有可能在未来自旋电子学器件方面具有潜在的应用价值.
关键词:
庞磁电阻
磁性隧道结
开关效应 相似文献
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Felicia Gheorghiu Radu Tanasa Maria Teresa Buscaglia Vincenzo Buscaglia Cristina G. Pastravanu Eveline Popovici 《Phase Transitions》2013,86(7):726-736
In the present study, particles with different Bi2Fe4O9 micro/nanostructures with a few particular morphologies (flower-like nanoplatelets, hierarchical microstructures, perfectly square platelets single crystals, etc.) obtained under specific hydrothermal synthesis conditions were investigated. The role of the processing parameters (such as NaOH concentration, reaction temperature, and reaction duration time) on the phase formation mechanism and on the microstructural characteristics was investigated. All the Bi2Fe4O9 morphologies showed orthorhombic symmetry with space group Pbam. The photocatalytic properties and magnetic behavior as a function of the micro/nanostructural characteristics of various Bi2Fe4O9 powders were determined. In the presence of Bi2Fe4O9, a degradation rate of Rose Bengal in the range of 52–61% was determined after 180?min under UV light irradiation (λ?=?254?nm). Magnetic activity with antiferromagnetic behavior and a transition at ~240?K slightly dependent on the microstructures was found. The role of Bi2Fe4O9 microstructures in the photocatalytic activity and magnetic properties was discussed. 相似文献
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多组分复合体系有利于电荷的有效分离,减少电子空穴对的复合几率。通过低温液相法首次合成Ag-Bi2MoO6/BiPO4三元异质结构光催化剂。利用XRD、SEM、EDX及XPS等技术对样品进行了表征。结果表明,Ag纳米粒子光照积累在Bi2MoO6/BiPO4的表面,通过表面等离子共振增加对可见光的吸收,同时作为电子受体促进了光生电子的转移。Ag、BiPO4和Bi2MoO6形成三元异质结构有效地抑制了光生电子空穴对的复合。Ag-Bi2MoO6/BiPO4表现出优异的光催化性能,其光催化活性较BiPO4、Bi2MoO6和Bi2MoO6/BiPO4样品有较大提高。并且对Ag-Bi2MoO6/BiPO4三元异质结构的光催化机制进行了讨论。光催化过程中反应活性物种捕获实验结果表明h+和O2·-是主要的活性基团. 相似文献
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Synthesis and photoluminescence properties of Nd2O3 nanoparticles modified by sodium bis 2-ethylhexyl sulfosuccinate 下载免费PDF全文
This paper reports that Nd2O3 nanoparticles modified by
AOT(sodium bis(2-ethylhexyl) sulfosuccinate) were prepared using
microemulsion method in the system of water and
propanol/AOT/toluene. Transmission electron microscopy shows that
the Nd2O3 nanoparticles take the shape of sphere with
18\,nm and 31nm with different preparation. The organic sol of
Nd2O3 nanoparticles is very stable at room temperature.
X-ray diffraction results show that the product has hexagonal phase
structure. Two ultraviolet emission band at 344\,nm and 361\,nm
corresponding to the transition of 4D3/2→4I9/2 and 2P3/2→4I112 or 4D3/2
→4I13/2 were observed. 相似文献
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光催化降解有机污染物由于其具有低能耗和绿色环保的特点,已经成为研究的热点. 氧化铋纳米晶体的带隙在2.0∽2.8 eV之间,利用它催化可见光降解有机污染物具有较高的活性,从而引起了越来越多的关注. 尽管近年来已经开发了几种制备Bi2O3基半导体材料的方法,但是仍然难以用简单的方法大规模地制备高活性的Bi2O3催化剂. 因此,开发简单可行的大规模制备Bi2O3纳米晶体的方法对于工业废水处理的潜在应用具有重要意义. 本文通过蚀刻商用BiSn粉末,然后进行热处理,成功地大规模制备了多孔Bi2O3. 获得的多孔Bi2O3在亚甲基蓝(MB)的光催化降解中表现出优异的活性和稳定性. 对该机理的进一步研究表明,多孔Bi2O3合适的能带结构允许生成活性氧物种,例如O2-·和·OH,可有效降解MB. 相似文献
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Li ZhangYoshio Hashimoto Toshinori TaishiIsao Nakamura Qing-Qing Ni 《Applied Surface Science》2011,257(15):6577-6582
A novel flower-shaped Bi2O3 superstructure has been successfully synthesized by calcination of the precursor, which was prepared via a citric acid assisted hydrothermal process. The precursor and Bi2O3 were characterized with respect to morphology, crystal structure and elemental chemical state by field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). It was shown that both the precursor and Bi2O3 flower-shaped superstructure were constructed of numerous nanosheets while the nanosheets consisted of a great deal of nanoparticles. Furthermore, key factors for the formation of the superstructures have been proposed; a mechanism for the growth of the superstructure has been presented based on the FESEM investigation of different growth stages. 相似文献
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Kenta Nagamine Keita Hirose Tsuyoshi Honma Takayuki Komatsu 《Solid State Ionics》2008,179(13-14):508-515
The glasses with the composition of 37.5Li2O–(25 − x)Fe2O3–xNb2O5–37.5P2O5 (mol%) (x = 5,10,15) are prepared, and it is found that the addition of Nb2O5 is effective for the glass formation in the lithium iron phosphate system. The glass–ceramics consisting of Nasicon-type Li3Fe2(PO4)3 crystals with an orthorhombic structure are developed through conventional crystallization in an electric furnace, showing electrical conductivities of 3 × 10− 6 Scm− 1 at room temperature and the activation energies of 0.48 eV (x = 5) and 0.51 eV (x = 10) for Li+ ion conduction in the temperature range of 30–200 °C. A continuous wave Nd:YAG laser (wavelength: 1064 nm) with powers of 0.14–0.30 W and a scanning speed of 10 μm/s is irradiated onto the surface of the glasses, and the formation of Li3Fe2(PO4)3 crystals is confirmed from XRD analyses and micro-Raman scattering spectra. The crystallization of the precursor glasses is considered as new route for the fabrication of Li3Fe2(PO4)3 crystals being candidates for use as electrolyte materials in lithium ion secondary batteries. 相似文献
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采用有机溶剂热法在FTO衬底上制备{001}面暴露的单晶锐钛矿相TiO2纳米片阵列,通过FESEM和XRD研究样品的形貌和晶体结构. 与水热法制备的纳米片阵列相比,有机溶剂热法制备的样品取向性更好. 采用光沉积方法在纳米片阵列上沉积Pt,所得到的Pt纳米颗粒粒径更为均匀,并且更容易沉积在{001}面上. 所负载的Pt 纳米颗粒增强了TiO2纳米片的光吸收性能,同时大大减弱了光致发光强度. 在光催化性能测试中,具有最优负载量的样品催化性能提高了一倍. 与传统的Pt负载相比,{001}面的最优负载量显得相当小,这可能源于高活性{001}面的原子结构. 相似文献
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In this study we present the effects of iron oxide (Fe2O3) on titanium dioxide (TiO2) in synthesising visible-light reactive photocatalysts. A Fe2O3-TiO2 composite photocatalyst was synthesized from Fe2(SO4)3 and Ti(SO4)2 by a ethanol-assisted hydrothermal method. The preparation conditions were optimized through the investigation of the effects of hydrothermal temperature and time as well as molar ratio of Ti to Fe on the photocatalytic activity. The visual, physical and chemical properties of the Fe2O3-TiO2 composites were investigated. The results showed that α-Fe2O3 and anatase TiO2 were present in the composites. The Fe2O3-TiO2 synthesized under optimum condition consisted of mesoporous structure with an average pore size of 4 nm and a surface area of 43 m2/g. Under visible and solar light irradiation, the photocatalytic activity of optimized sample was significantly higher than that of pure TiO2. This sample led to a photodegradation efficiency of 90% and 40% of auramine under visible light and solar light, respectively. 相似文献