共查询到19条相似文献,搜索用时 406 毫秒
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在近中性条件下,利用H2O2氧化Fe(OH)2胶体成功制备了Fe3 O4纳米颗粒.分别利用透射电镜(TEM),x射线衍射仪(XRD),振动样品磁强计(VSM)和超导量子干涉仪(SQUI D)对样品的形貌,结构,宏观磁性进行了表征和测量.TEM图像表明样品为球形颗粒,直径 大小约18nm,且分布较均匀.XRD结果表明样品为立方尖晶石结构.穆斯堡尔谱测量表明样品 室温下对应两套六线谱,样品的晶体结构存在缺陷,内磁场略小于块体Fe3O4的值. 宏观磁测量表明样品的饱和磁化强度可达67×10-3A·m2/g,在20 K出现了Verw ey转变.选择该法制备的Fe3O4纳米颗粒与共沉淀法得到的样品作 了磁性比较.宏观磁 测量表明共沉淀法制备的样品在外磁场为1T时仍未饱和,磁化强度仅为46×10-3A·m2/g,在178K出现了超顺磁转变温度,且在测量温度范围内没有发现Verwe y转变.
关键词:
亚铁磁
超顺磁
穆斯堡尔谱 相似文献
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本文用固相反应烧结制备出Li2Mo2O6多晶材料。经X射线分析、红外光谱和电子顺磁共振谱(EPR)的研究,确定了它的结构是Li2Mo2O4和MoO2两个晶相组成的烧结体。钼离子以四价状态存在于MoO2晶相结构中。采用交流阻抗谱分析了晶界与温度变化的相关性。测得了样品的ln(σ总T)-1/T 曲线是由两段直线和一段曲线所组成;总电导率化能σ27℃=1.36×10-3(Ω·cm)-1,σ115℃=1.49×10-3(Ω·cm)-1,σ300℃=9.71×10-3(Ω·cm)-1,σ370℃=2.42×10-3(Ω·cm)-1;电导活化能E1=0.043eV,E2=0.235eV,E平均=0.76eV。采用维格纳极化电池法测得电子电导率σe,σe27℃=2.240×10-5(Ω·cm)-1,σe300℃=4.476×10-3(Ω·cm)-1。实验证明,室温下材料为固体电解质,300℃附近为良好的离子与电子混合导体。
关键词: 相似文献
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通过区熔定向凝固法,生长出[001]易磁化方向与晶体轴向之间存在不同取向差的Fe81Ga19合金单晶体和Fe81Ga19合金多晶体.极图测试结果显示,Fe81Ga19合金单晶体的[001]方向与轴向取向差分别为12°,5°和3°.采用电阻应变片法测定相应磁致伸缩应变,与外加磁场方向平行的轴向磁致伸缩应变分别为254×10-6,271×10-6<
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磁致伸缩
81Ga19合金')" href="#">Fe81Ga19合金
晶体取向 相似文献
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用最小偏向角法在20℃下精确测量了0.62Pb(Mg1/3Nb2/3)O3< /sub>-0.38PbTiO3( 0.62PMN-0.38PT)单晶的折射率,给出了该温度下折射率色散的Sellmeier方程.研究了能带 结构与折射率的关系,计算了样品的Sellmeier光学系数:对no,E0=5.50eV,λ0=0.2 26μm,S0=1.004×1014m-2,Ed=28.1 0eV;对ne,E0=5.57eV,λ 0=0.223μm,S0=1.017×1014m-2,Ed=28.10eV.A BO3型钙钛矿材料中,BO6八面体基元决定了晶体的能带结构,对折 射率产生重要影响.
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PMNT单晶
折射率
Sellmeier光学系数 相似文献
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用直拉单晶生长系统制备TbyDy1-x(Fe1-xTx)2(T=Al,Mn)单晶,并测量其磁致伸缩.用电弧炉合成多晶TbyDy1-y(Fe1-xTx)2(T=Al,Mn),并用X射线衍射方法测量拟合得到内禀磁致伸缩.结果表明,Al和Mn替代后饱和磁场降低,说明Al和Mn的替代明显地降低了各向异性能.随Al和Mn替代量的增加,总的趋势是材料的内禀磁致伸缩λ111降低.对Tb0.5Dy0.5(Fe0.9Mn0.1)2单晶,在不加压情况下的磁致伸缩效果并不明显,但当施加压力时,磁致伸缩变化显著,尤其在12—26MPa压力下,磁致伸缩变化很大,且低场效果很好.
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The effect of the orientation on the magnetostriction in Fe 81 Ga 19 alloy has been investigated experimentally and theoretically.The Fe 81 Ga 19 [001] and [110] oriented crystals were prepared and the magnetostriction was measured under different pre-stress.The saturation magnetostriction of the [001] oriented crystal increases from 170×10-6 to 330×10-6 under the pre-stress from 0 to 50 MPa.The [110] oriented crystal has a saturation magnetostriction from 20×10-6 to 140×10-6 with the compressive pre-stress from 0 to 40 MPa.The magnetostriction of [001] and [110] oriented crystals has been simulated based on the phenomenological theory.The domain rotation path has been determined and the resultant magnetostriction calculated under different pre-stress.The experimental and simulated results both show that the [001] oriented crystal exhibits better magnetostriction than [110] oriented crystal.The enhancement of the saturation magnetostriction by the compressive pre-stress in the [110] oriented crystal is higher than that in the [001] oriented crystal. 相似文献
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The pyroelectric coefficient p3 in 3La(IO3)3.HIO3.7H2O has an average value 2.0×10-5 Cm-2 in the temperature range 152 to 240 K. The resistivity decreases from 1012 to 1010 ohm-cm between 258 and 338 K. At 298 K, the piezoelectric coefficient d33 19×10-12CN-1. Positive polarity is generated on (001) by increasing temperature or tensile stress. A displacement toward (001) by La3+ or H3O+ ions of 1×10-4 Å per K or 106Nm-2, or rotation of the water molecule or iodate ion dipoles by about 5 arc minutes per K or 106Nm-2, produces the observed polarity. 相似文献
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采用传统的固相法制备了(1-x)(K0.5Na0.5NbO3-LiSbO3-BiFeO3)-xCuFe2O4 (x=0.1, 0.2, 0.3, 0.4) 磁电复合陶瓷, 并借助X射线衍射仪、扫描电镜和磁电耦合系数测试仪等对复合陶瓷的微结构和性能进行了分析. 结果表明, 复合陶瓷的K0.5Na0.5NbO3-LiSbO3-BiFeO3和CuFe2O4物相之间发生了一定的离子相互扩散作用, 且两相的颗粒大小匹配性较好. 随着CuFe2O4含量增加, 复合陶瓷的压电系数从130 pC/N减小到30 pC/N, 饱和磁致伸缩系数从4.5×10-6增加到12.4×10-6左右, 磁电耦合系数表现出先增加后减小, 在x=0.3时获得最大的磁电耦合系数9.4 mV·cm-1·Oe-1.
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0.5Na0.5NbO3-LiSbO3-BiFeO3')" href="#">K0.5Na0.5NbO3-LiSbO3-BiFeO3
2O4')" href="#">CuFe2O4
磁电耦合 相似文献
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A series of (La_{1-x}Tb_x)_{2/3}Sr_{1/3}MnO_3 polycrystalline samples has been studied by means of x-ray diffraction, magnetostriction, and thermal expansion measurements. It has been found that this series undergoes a phase transition from a rhombohedral to an orthorhombic form at the doping level x≈0.20 at room temperature accompanied by an anisotropic magnetostriction up to -50×10^{-6} under a magnetic field of 1T. The linear and volume magnetostrictions vary with chemical composition, even change sign. At T=80K, the magnetostrictions for the samples of x=0.20 and 0.40 exhibit different behaviours. The sample of x=0.20 has positive volume and linear magnetostrictions and a negative anisotropic magnetostriction, while the sample of x=0.40 has an opposite behaviour. The magnitude of volume magnetostriction for both the samples is essential (~10^{-4}) at T=80K under a magnetic field of 4T. We conclude that these anomalous effects are due to the charge delocalization and the structural phase transition between orthorhombic and rhombohedral forms induced by the applied magnetic field. 相似文献
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J.J. Neve C.F.J. de Meijer F.A.P. Blom 《Journal of Physics and Chemistry of Solids》1981,42(11):975-980
Shubnikov-de Haas oscillations in the transverse magnetoresistance of single-crystalline n-type CdSnAs2 have been recorded at temperatures between 2 and 25 K in magnetic fields up to 5T. The electron concentration of the samples ranged from 2 × 1017 to 2 × 1018 cm?3. The angular dependences of the oscillation periods and cyclotron effective masses showed that the conduction band exhibits an energy dependent anisotropy, obeying the Kildal band structure model. For the low-temperature values of the band parameters we found: a band gap Eg = 0.30 eV, a spin-orbit splitting Δ = 0.50 eV, a crystal field splitting parameter δ = ?0.09 eV, and an interband matrix element P = 8.5 × 10?8eV cm. This simple four-level model was found to be not adequate to describe quantitatively the observed electronic effective g-factor for a sample with low electron concentration. 相似文献
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The thermal expansion of the a and c axes of lT-TaS2 and of the a axis of 2H-NbSe2 have been measured between 4 K and 360 K. Discontinuities in the lattice parameters of TaS2 were observed at the known charge density wave phase transitions near 200 K and 352 K, and a new transition was found near 283 K. These results are used to estimate the entropy changes occurring at the phase transitions. At the charge density wave onset temperature in NbSe2 we find an upper limit to any discontinuity in the a axis of 2 × 10-7 and to any discontinuity in the expansion coefficient of 3 × 10-7 K-1. 相似文献
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The structural and magnetic properties of the alloy system REIn0.5Ag0.5 [RE = Gd, Tb, Dy, Ho, Er, Tm and Yb] are reported. All these alloys (except that of Yb) crystallize in a cubic CsCl type structure at room temperature. Low temperature X-ray diffraction data does not reveal any structural phase transformation down to 8 K. On the basis of magnetic susceptibility data at a different temperature (3–300 K) and applied magnetic field (2 × 105 to 8 × 106 A m-1, it has been concluded that GdIn0.5Ag0.5 is ferromagnetic (Tc = 118 K), TbIn0.5Ag0.5 and DyIn0.5Ag0.5 are meta magnetic (TN = 66 and 30 K, respectively) and alloys involving Ho, Er, Tm and Yb are ferrimagnetic with Néel temperatures (TN) equal to 24, 22, 21 and 20 K, respectively. The evaluated effective magneton number (p) is found to be slightly larger compared to theoretical values for tripositive ions of Gd, Tb and Dy and a bit smaller for Ho, Er, Tm and Yb. The results have been qualitatively explained using appropriate theories. 相似文献
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通过熔体快淬方法获得Pr(Fe1-xCox)2合金条带,经过X射线衍射、差示扫描量热计和磁性测量对其结构、磁性和热稳定性进行了研究.发现当Co的含量x大于0.2时才可能获得Pr(Fe,Co)2立方Laves相化合物.对Pr(Fe0.6Co0.4)2合金,在快淬速度为30m/s时,条带由Pr2(Fe,Co)17,Pr(Fe,Co)2和富稀土相组成;在速度为40m/s时,获得了几乎单相的Pr(Fe0.6Co0.4)2化合物,其居里温度为305℃;在速度为45m/s时,除了Pr(Fe0.6Co0.4)2化合物外,还存在少量的非晶相.Pr(Fe0.6Co0.4)2化合物在770℃以上发生分解.用40m/s快淬纳米晶粉胶粘磁体有大的磁致伸缩系数(λ∥-λ⊥=140×10-6)和高的硬磁性能(iHc=398kA/m).
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The electron spin resonance of VO2+ is studied in single crystals of Cs2M″ (SeO4)2·6H2O (M″ = Zn, Co) from 290 to 77 K at ~ 9.45 GHz. The line broadening of VO2+ spectra on cooling the Cs2Co(SeO4)2·6H2O crystal is explained on the basis of host spin-lattice relaxation narrowing. T1 for Co2+ is estimated to be ≈ 1.7 × 10?12 sec. at 290 K. 相似文献