共查询到20条相似文献,搜索用时 140 毫秒
1.
采用高温固相法合成了适用于UVLED芯片激发的NaCaPO4:Tb3+绿色荧光粉并对其发光性质进行了研究。该荧光粉的发射峰位于418,440,492,545,586,622nm,分别对应Tb3+的5D3→7F5、5D3→7F4、5D4→7F6、5D4→7F5、5D4→7F4、5D4→7F3能级跃迁。其中位于492,545nm的发射峰最强,样品发射很好的绿光。主要激发峰位于380~400nm之间,属于4f→4f电子跃迁吸收,与UVLED芯片的发射相匹配。考察了Tb3+掺杂浓度和Li+,Na+和K+作为电荷补偿剂对样品发光性能的影响:Tb3+的最佳掺杂浓度为10%,以Li+的补偿效果最好。NaCaPO4:Tb3+是一种适用于白光LED的绿色荧光材料。 相似文献
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利用Si(111)衬底, 以Au-Al为金属催化剂, 基于固-液-固生长机理, 在温度为1100℃, N2气流量为1.5 L/min、生长时间为30–90 min等工艺条件下, 制备了直径约为100 nm、长度为数微米的高密度、均匀分布、大面积的Si纳米线(~1010 cm-2). 对Si纳米线进行了Eu掺杂, 实验研究了不同长度的Si纳米线以及不同掺杂温度、掺杂时间等工艺参数对Eu离子红光发射的影响, 利用扫描电子显微镜和X射线衍射仪对Si纳米线表面形貌和Eu掺杂后Si纳米线的结晶取向进行了测量和表征; 室温下利用Hitachi F-4600型荧光分光光度计对样品的激发光谱和发射光谱进行了测试和分析. 结果表明: 在Si纳米线生长时间为30 min、掺杂温度为1000℃、 最佳激发波长为395 nm时, 样品最强荧光波长为619 nm (5D0→7F2); 同时, 还出现了576 nm (5D0→7F0), 596 nm (5D0→7F1), 658 nm (5D0→7F3)和708 nm (5D0→7F4)四条谱带. 相似文献
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本文采用固相法在500℃合成了Er3+/Eu3+共掺BiOCl 荧光粉, 并通过XRD, SEM, 吸收, 激发和发射光谱研究了其结构、形貌和发光特性. XRD 和SEM结果表明在500℃下即可成功合成纯四方相片层结构的Er3+/Eu3+共掺BiOCl荧光粉. 吸收光谱表明掺杂Er3+/Eu3+离子使BiOCl形成杂质能级; 激发光谱显示该荧光粉具有来自于基质BiOCl价带(VB)到导带(CB)跃迁的优异宽带近紫外激发特性. 在380 nm近紫外光激发下, 同时获得了Er3+离子和Eu3+离子的特征发射峰, 其中发光中心位于410 nm (2H9/2→4I15/2), 525 nm (2H11/2→4I15/2), 554 nm (4S3/2→4I15/2), 673 nm (4F9/2→4I15/2)的发射峰来自于Er3+离子的跃迁, 而581 nm(5D0→7F0), 594 nm (5D0→7F1), 622 nm (5D0→7F2), 653 nm (5D0→7F3), 699 nm (5D0→7F4)的发射峰则来自于Eu3+离子的跃迁. 值得注意的是, 与传统Er3+/Eu3+掺杂的材料不同, 该荧光粉还具有独特高效的紫光(Er3+)和长波红光(Eu3+)发射特性, 分析表明这与BiOCl的结构有关; 并且通过改变掺杂浓度, 实现了发光颜色由黄绿光→黄光→橙红光的调节. 研究结果表明Er3+/Eu3+共掺BiOCl荧光粉有望成为一种潜在的近紫外激发白光LED荧光粉. 相似文献
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本工作测量了室温下TbP3O14和EuP5O14晶体的吸收和发射光谱。根据吸收光谱和Judd-Ofelt理论计算了Tb3+和Eu3+的实验和理论的振子强度。用最小二乘法拟合实验与理论的振子强度得到唯象强度参量Ωλ。然后计算了Tb3+的5D3→7F5,5D4→7F4和5D4→7F6以及Eu3+的5D0→7F2,5D0→7F4的跃迁几率和寿命。同时用时间分辨光谱测量了不同温度下相应的荧光辐射寿命。计算与实验结果基本相符。理论和实验的结果表明Tb3+的5D3态的寿命主要取决于5D3→5D4和7F6→7F0两能级对之间的电偶极-电偶极交叉弛豫。
关键词: 相似文献
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采用液相沉淀法合成了铽单掺杂,铕单掺杂,铽、铕双掺杂的硅酸锶发光材料。其结构经X-射线衍射表征。研究了合成样品的激发、发光光谱。研究结果表明:在254nm波长紫外光激发下,SrSiO3:0.04Eu3+的发光光谱中出现4个Eu3+的发光峰,分别为Eu3+的5D0→7F1(588、590nm)、5D0→F2(609nm)、5D0→7F3(626nm)、5D0→4F4(651nm)跃迁峰;SrSiO3:0.04Tb3+的发光光谱中出现4个Tb3+的发光峰,分别为Tb3+的5D4→F6(488nm)、5D4→7F5(541、548nm)、5D4→7F4(584nm)跃迁峰;SrSiO3:0.04Tb3+,0.04Eu3+发光体系中,Tb3+的共掺杂显著增强了Eu3+的特征发射,存在Tb3+→Eu3+的能量传递现象,结果表明有Eu3+和Tb3+两个发光中心。 相似文献
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采用高温溶剂热法合成了下转换发光材料NaYF4∶Eu3+ 和NaYF4∶Eu3+,Tb3+ ,采用X射线衍射(XRD)、场发射扫描电镜(FESEM)、激发(PLE)谱和光致发光(PL)谱对材料的物相结构、形貌特征和发光性质进行了表征和研究,并分析了其发光原理。结果表明:所合成的NaYF4∶Eu3+ 和NaYF4∶Eu3+,Tb3+ 为纯六方相晶体,尺寸在100 nm左右;改变Eu3+ 和Tb3+ 的掺杂浓度后晶格结构没有发生明显变化,说明Eu3+ 和Tb3+ 取代的是Y3+的晶格位置;在394 nm光的激发下,检测到Eu3+ 在5D0→7F1 和5D0→7F2跃迁处的特征发射光,并且可见光强度随着Eu3+ 离子掺杂浓度的变化而变化。另外Tb3+ 离子浓度对NaYF4∶Eu3+ 晶体结构产生了一定的影响,说明掺杂Tb3+ 离子改变了Eu3+ 离子所处的配位环境,导致红色发光带增强,而这主要源于电偶极子跃迁的贡献。 相似文献
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采用溶胶凝胶-燃烧法合成了系列不同掺杂浓度Y3+和Gd3+的LaBO3∶Eu3+发光粉,对其结构、形貌和发光性能进行了表征。XRD研究结果表明:发光粉的结构与基质掺杂离子的种类和掺杂浓度有关系。荧光光谱结果表明:适量比例Y3+和Gd3+离子掺杂将提高LaBO3∶Eu3+发光粉的发光强度。Y3+和Gd3+离子最佳掺杂摩尔分数分别为1.5%和12.5%。5D0→7F2与5D0→7F1跃迁发射的相对强度比值说明:掺杂改变LaBO3∶Eu3+中Eu3+局域环境的对称性。发光性能改变主要受晶体结构、掺杂离子电负性影响。Gd3+离子掺杂更有利于发光粉结构稳定性和发光性能的改善。 相似文献
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采用凝胶法分别制备出4.5ZnO-5.5Al2O3-90SiO2(ZAS)以及ZAS[DK]:RE3+ (RE=Eu,Tb,Ce) 透明微晶玻璃。利用X射线衍射仪(XRD)、透射电子显微镜(TEM)和荧光光谱仪(PL)等测试手段,研究了稀土离子掺杂浓度对ZAS微晶玻璃的结构和发光性能的影响。XRD结果表明,ZAS[DK]:RE3+ (RE=Eu,Tb,Ce)微晶玻璃包含ZnAl2O4晶相和SiO2非晶相,ZnAl2O4平均晶粒尺寸约为30 nm,稀土离子的掺杂没有显著改变原来的ZnAl2O4晶体结构。TEM结果表明,900 ℃时ZnAl2O4从ZAS体系中析出。PL光谱显示,Eu3+ 存在 5D0→7F2跃迁,ZAS[DK]:Eu3+在611 nm 处发出强烈的红色光;由于Tb3+ 的5D4→7F5 跃迁,ZAS[DK]:Tb3+在541 nm 处发出明亮的绿色光;ZAS[DK]:Ce3+ 在381 nm处显示了蓝光发射,对应于Ce3+ 的5d→4f 轨道跃迁。ZAS[DK]:RE3+ (RE=Eu, Tb, Ce)的PL发射光谱存在着浓度猝灭现象,Eu3+、Tb3+ 和Ce3+的最佳单掺杂摩尔分数分别为20%、20%和3%。CIE色度图表明,ZAS[DK]: RE3+ (RE=Eu,Tb,Ce)的色坐标分别位于红光、绿光和蓝光区域。实验结果表明,ZAS:RE3+ (RE=Eu,Tb,Ce) 微晶玻璃是一种良好的可用于全色显示的白光LED材料。 相似文献
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V.P. Solntsev A.P. YelisseyevT.B. Bekker A.E. KokhS. Yu. Stonoga A.V. DavydovA. Maillard 《Optics Communications》2012,285(24):5205-5209
Optical absorption and luminescence spectra of ytterbium and terbium codoped BaB2O4 (β-BBO and α-BBO) crystals grown in different conditions have been studied. Low-temperature absorption peaks were observed in all samples. Features related to rare earth ions were observed in absorption and luminescence spectra. Absorption and emission in the range 860-1000 nm are caused by 2F5/2↔2F7/2 transitions in Yb3+ ions. Emission peaks at 500, 550, 590 and 630 nm correspond to 5D4→7F6, 7F5, 7F4, and 7F3 transitions of Tb3+ ions, respectively. The probable reasons of variations in spectroscopic features related to Yb in BBO host are discussed. It has been shown that the replacement of Ва2+ by Yb3+ in the lattice of ВаВ2О4 results in the decrease in the symmetry of oxygen surrounding of Yb3+. 相似文献
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J. Pisarska M. Sołtys L. Żur W. A. Pisarski C. K. Jayasankar 《Applied physics. B, Lasers and optics》2014,116(4):837-845
Excitation and luminescence properties of Eu3+, Tb3+ and Er3+ ions in lead phosphate glasses have been studied. From excitation spectra of Eu3+ ions, the electron–phonon coupling strength and phonon energy of the glass host were calculated and compared to that obtained by Raman spectroscopy. Main intense and long-lived luminescence bands are related to the 5D0–7F2 (red) transition of Eu3+, the 5D4–7F5 (green) transition of Tb3+ and the 4I13/2–4I15/2 (near-infrared) transition of Er3+. The critical transfer distances, the donor–acceptor interaction parameters and the energy transfer probabilities were calculated using the fitting of the luminescence decay curves from 5D0 (Eu3+), 5D4 (Tb3+) and 4I13/2 (Er3+) excited states. The energy transfer probabilities for Eu3+ (5D0), Tb3+ (5D4) and Er3+ (4I13/2) are relatively small, which indicates low self-quenching luminescence of rare earth ions in lead phosphate glasses. 相似文献
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In this paper, Eu3+ β-diketone Complexes with the two ligands 1-(2-naphthoyl)-3, 3, 3-trifluoroacetonate (TFNB) and 2’2-bipyridine (bpy) have
been synthesized. Furthermore, we reported a systematical study of the co-fluorescence effect of Eu(TFNB)3bpy doped with inert rare earth ions (La3+, Gd3+ and Y3+) and luminescence ion Tb3+. The co-luminescence effect can be found by studying the luminescence spectra of the doped complexes, which means that the
existence of the other rare earth ions (La3+, Y3+, Gd3+ and Tb3+) can enhance the luminescence intensity of the central Eu3+, which may be due to the intramolecular energy transfer between rare earth ions and Eu3+. The efficient intramolecular energy transfer in all the complexes mainly occurs between the ligand TFNB and the central
Eu3+. Full characterization and detail studies of luminescence properties of all these synthesized materials were investigated
in relation to co-fluorescence effect between the central Eu3+ and other inert ions. Further investigation into the luminescence properties of all the complexes show that the characteristic
luminescence of the corresponding Eu3+ through the intramolecular energy transfers from the ligand to the central Eu3+. Meantime, the differences in luminescence intensity of the 5D0→7F2 transition, in the 5D0 lifetimes and in the 5D0 luminescence quantum efficiency among all the synthesized materials confirm that the doped complex Eu0.5Tb0.5(TFNB)3bpy exhibits higher 5D0 luminescence quantum efficiency and longer lifetime than the pure Eu(TFNB)3bpy complex and other materials. 相似文献
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Nanometer-sized Eu3+-doped ZnS and Mn2+-doped ZnS particles were prepared by solid-state method at low temperature. The structures and properties of those materials were characterized by X-ray diffraction (XRD) and photoluminescent spectroscopy techniques. The XRD patterns reveal that the doped ZnS nanoparticles belong to zinc-blende structure. The concentration of doping ions has little effect on the sizes of the doped ZnS nanoparticles, which mainly depends on the temperature of preparation. The emission peaks from the 5D0→7FJ (J=1, 2, and 4) electronic energy transitions of Eu3+ were observed in the emission spectra of the ZnS:Eu3+ nanoparticles. The intensity ratio of the two peaks from the 5D0→7F1 and 5D0→7F2 transitions indicates that more Eu3+ ions occupy the sites with no inversion symmetry. For the ZnS:Mn2+ nanoparticles, an orange emission from the 4T1→6A1 transition of Mn2+ is present, indicating that the doping ions occupy the positions of the ZnS lattices. Meanwhile, UV-induced luminescence enhancement was observed for the ZnS:Mn2+ nanoparticles, the possible reason of which is discussed primarily. 相似文献
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《Current Applied Physics》2020,20(10):1110-1117
The emission properties of the rare earth (RE) elements have been found to be sensitive to the local lattice environment around them, and could be employed for probing the local lattice environment. Because each constituent ion of a material should have its own particular structural environment, the emission profiles in RE elements depend strongly on the doping sites of RE elements inside the host crystals. We investigated the emission properties of the Eu3+ ion doped BaZrO3 (BaZrO3:Eu) with doping site dependence (A-site vs. B-site), as well as ambient dependence in the post-annealing process. The site-selective doping was identified from the Rietveld refinement analysis on the XRD patterns of our BaZrO3:Eu samples. Photoluminescence and photoluminescence excitation measurements showed that the emission properties of the samples with the Eu3+ ions substituted at Zr sites revealed much greater emission properties than those at the Ba sites. This behavior was found to accord with the change in intensity ratio of 5D0 → 7F0,2 to 5D0 → 7F1 in Eu ions, which should be a measure of the local lattice asymmetry around the Eu ions. We also found that with post-annealing in H2 atmosphere, the emission intensities of the Eu ions increased significantly, while with post-annealing in O2 atmosphere, they were suppressed. Our findings indicated that the cation/oxygen vacancies could change the local lattice environment around the Eu ions, as well as the valence states of Eu ions, depending on the doping site in the cubic perovskite. 相似文献
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Radio-, photo- and thermally stimulated—luminescence (RL, PL, TSL) measurements have been performed on SiO2 sol-gel glasses doped by 0.1 mol% Ce and 3 mol% Gd, and on (0.1 mol% Ce, 3 mol% Gd) co-doped samples. Ce3? 5d-4f emission peaking at about 2.7 eV has been observed in the RL of SiO2: 0.1 mol% Ce, while the typical 6P-8S emission of Gd3? centred at 3.97 eV has been detected in SiO2: 3 mol% Gd. The co-doped sample displays both 5d-4f Ce3? and 6P-8S Gd3? emissions with reduced intensities with respect to those observed in the singly doped glasses. Moreover, in co-doped glasses the PL time decay patterns of both rare earth ions show a non exponential dependence and are significantly shortened. To explain such an effect non radiative de-excitation of both RE ions excited states involving energy transfers to defect levels is suggested. Bidirectional Gd3? ? Ce3? energy transfers could also occur. Complementary TSL measurements put in evidence the existence of broad glow peaks at about 100 K and 220 K. The TSL spectra feature the RE ions emissions. 相似文献
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Irene Teresinha Santos Garcia Patrícia Velleda RibeiroDiogo Silva Corrêa Igor Michel Neto da CunhaNeftali Lenin Villarreal Carreño Eduardo Ceretta MoreiraFabiano Severo Rodembusch 《Applied Surface Science》2011,258(4):1437-1442
A photoactive complex based on europium(III) using the amino acid phenylalanine as ligand was prepared and characterized. The obtained europium(III)/phenylalanine complex presents an effective energy transfer from ligands to the rare earth center. The observed photoluminescent behavior for europium(III)/phenylalanine complex was similar to the well known europium(III)/ acetyl-β-acetonate hydrate. New photoactive polyamide thin films were prepared using polycaprolactam as host of these complexes. The structural characterizations of the films were studied through Rutherford backscattering (RBS), Fourier transform infrared (FTIR) and Raman spectroscopies. The polyamide films doped with the amino acid and acetyl-β-acetonate rare earth complexes maintain the original photoluminescent behavior, narrow emission bands corresponding to transitions 5D0 → 7F0-4, which indicates that this polymer is an excellent host to these complexes. 相似文献
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Lines due to cooperative optical absorption of Eu3+ have been observed in the luminescence excitation spectra for Eu2O2S at 75 K. A pair of Eu3+ ions are simultaneously excited by one photon to the 5DJ and 7F'J states from the ground state 7F0. Estimated oscillator strengths of the pair absorption are of the order of 10-9, and are much larger than those in other rare earth compounds reported elsewhere. Multipolar interaction between Eu3+ ions cannot explain such a large oscillator strength. Hole-exchange through the charge transfer state, or a super-exchange mechanism, gives a reasonable order of the pair absorption strength in Eu2O2S. 相似文献
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Ling Zhu Yangjia Liu Xizhi Fan Daowu Yang Xueqiang Cao 《Journal of luminescence》2011,131(7):1380-1385
Highly uniform and monodisperse KY3F10:Ln3+ (Ln=Eu, Ce, Tb) nanospheres, with an average diameter of 300 nm, have been successfully prepared through a simple template-free and surfactant-free stirring method under ambient conditions. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and photoluminescence (PL) spectra were used to characterize the samples. The SEM images illustrate that these spheres were actually composed of randomly aggregated nanoparticles. The doped rare earth ions show their characteristic emission in the KY3F10 samples, i.e., Eu3+ 5D0–7FJ (J=1, 2, 3, 4), Tb3+ 5D4–7FJ (J=6, 5, 4, 3, 2) and Ce3+ 5d–4f transition emissions, respectively. An energy transfer phenomenon from Ce3+ to Tb3+ has been observed in KY3F10 nanospheres, and the energy transfer efficiency depends on the doping concentration of Tb3+ if the concentration of Ce3+ is fixed. 相似文献