一种脒基碳酸氢盐的NMR研究

采用¹H、¹³C NMR、同核相关谱(gCOSY)、异核相关谱(gHSQC)和远程偶合谱(gHMBC)等多种核磁方法研究了一种脒基碳酸氢盐化合物N, N′-双十二烷基乙脒基碳酸氢盐的结构和构型,证明了该化合物具有两种不同的构型：A[E, Z]和B[E, E],完成了该化合物两种构型中¹H、¹³C NMR谱带的归属. 并考察了不同温度、不同极性溶剂（CDCl₃和DMSO-d₆）对此化合物两种不同构型比例变化的影响. 表明了N, N′-双十二烷基乙脒基碳酸氢盐在溶剂CDCl₃中存在两种构型A和B, 随着温度的升高,构型B的比例增加. 在溶剂DMSO-d₆中只存在一种构型A.     

含芳基噻唑糖基胍的NMR研究

通过对4种含芳基噻唑半乳吡喃糖基胍的¹H NMR谱的分析, 确证其糖苷键为β-构型, 对其一般特征进行了对比和讨论,并用¹H-¹H COSY, gHMQC, gHMBC, NOESY等2D NMR技术对它们的¹H和¹³C NMR谱峰进行了全归属.     

3，5-二甲基金刚胺盐酸盐的NMR研究

NMR核磁共振谱显示3，5-二甲基金刚胺盐酸盐是一个刚性结构，但其分子结构包含2个非对映体的立体构型形式. 我们通过利用DEPT，¹H-¹H COSY，HSQC和HMBC等技术所测得的二维谱图数据对NMR数据进行了完整的归属分析，其中¹³C NMR谱图显示在δ=29~54 ppm之间的十组峰表示所有碳的共振，而且由于不同的分子构象导致在¹³C NMR谱中有3个不同的季碳峰和¹H NMR中的2个不同的甲基峰. 由于H-5的叔碳H原子与邻近CH₂ 的平面二面夹角均约为600，致使耦合常数极其小，波谱仪难以分辨它们从而使¹H NMR峰为单重峰.     

α-山竹黄酮的NMR研究

应用一维¹H NMR、¹³C NMR、DEPT、二维HMBC、HSQC、¹H-¹H COSY、ROESY对1, 3, 6-三羟基-7-甲氧基-2, 8双(3-甲基-2-丁烯)-9-口山酮（α-mangostin、α-MAG）的¹H、¹³C原子进行了指认归属.     

聚氯乙烯辐射效应的NMR研究

用¹H 和¹³C NMR谱,FT-IR光谱等方法研究了聚氯乙烯(PVC)在限量空气氛室温下经⁶⁰Coγ 射线辐照后的辐照效应．结果表明PVC 大分子链的脱HCl 方式,受辐射剂量的影响．当辐射剂量达到2.8×10⁵Gy 时,PVC 以大分子链内脱HCl为主,产生部分－CH＝CH－结构,使得－CHCl的运动受阻,表现为T_２减小．不同溶剂对聚合物质子自旋-自旋弛豫时间（T_２）的影响,反映出溶剂效应和聚合物链在溶剂中的“伸展”状态．而水质子峰随着辐照剂量的增大而逐渐向低场位移,则是由于HCl与溶剂中的H₂O在微酸性溶液中发生了快速的质子交换之故．     

一种新的雄甾烷衍生物的NMR数据分析

采用¹H NMR,¹³C NMR,DEPT,¹H-¹H COSY,HSQC,HMBC等多种核磁共振分析方法,确证了溴化1-[3α,17β-二乙酰氧基-２β-(１-哌啶基)-５α-雄甾烷-16β-基］-１-乙腈基哌啶的结构,对它的¹H 和¹³C NMR谱信号进行了归属和详细分析,为其结构鉴定提供了依据．     

笼状β-碳苷酮衍生物的NMR研究及结构确证

以β-碳苷酮为原料合成了4个新的β-碳苷酮的笼状缩酮衍生物,采用¹H NMR、¹³C NMR、 DEPT及二维谱¹H-¹H COSY、HSQC、HMBC和高分辨质谱（HRMS）对其结构进行了研究和确证,并对它们的¹H、¹³C NMR全谱给予了准确归属.     

一种双香豆蒽衍生物的NMR研究

应用核磁共振技术（¹H NMR, ¹3C NMR, DEPT, ¹H-¹H COSY, HSQC, HMBC）,确定了7-(4-溴苯甲基)-7H-吡喃[3,2-c:5,6-c′]二香豆蒽-6,8二酮的结构,排除了其他可能结构, 准确归属了它的¹H, ¹³C信号.      

射干异黄酮的NMR波谱研究

为研究中药射干(Belamcanda chinensis)的化学成分,应用多种柱色谱方法对其乙醇提取物进行分离和纯化,并得到了11个异黄酮化合物,通过¹H NMR、¹³C NMR及HMBC、HSQC、¹H-¹H COSY、NOESY等波谱手段解析化学结构,发现一个新化合物,命名为异野鸢尾苷. 对这些化合物的¹H NMR和¹³C NMR进行了完全归属,并探讨了取代基对¹H、¹³C化学位移的影响.     

一种新的六氢喹啉衍生物的NMR研究

应用¹H NMR,¹³C NMR,DEPT,¹H-¹H COSY,HSQC,HMBC等多种NMR实验测试分析方法,确证了一种新的六氢喹啉衍生物2,7,7-三甲基-4-(4-羟基-3-甲氧基）苯基-5-氧代-1,4,5,6,7,8-六氢喹啉-3-羧酸甲酯的结构,并对它的¹H、¹³C信号进行了归属.     

Experimental Measurements for the QEC-Value of 183Os-Decay

Activities of ¹⁸³Os were produced by 39MeV α particles bombarding on a natural tungsten target.β⁺ spectrum with coincidence gate set on the strongest 382keV γ-rays of ¹⁸³Os decay was measured.The endpoint energy of the β⁺ spectrum was determined and the Q_EC value of ¹⁸³Os decay was extracted to be 2.24±0.10MeV which is in good agreement with the predicted value 2.30±0.10MeV on the basis of mass systematics.     

Chiral Lagrangian Treatment of 0^＋＋ Mesons and 0^＋＋ Glueballs

Within the framework of a nonlinear chiral Lagrangian the mass spectra and the decay properties of 0^＋＋ states below 2 GeV are studied. Assuming that f0（980）, a0（980）, K0（1430）, and f0（1500） comprise an SU（3） nonet, we make a detailed prediction about the static properties of the 0^＋＋ mesons. The substructure analysis of these states in terms of two- and four-quark components as well as a glueball component is carried out. We also consider the interaction Lagrangian and provide a preliminary study of the strong and radiative decays of the 0＋＋ mesons. The scalar glueball masses and partial widths are also presented. In view of the fact that few data of 0＋＋ mesons are clearly given in the present PDG （Particle Data Group） list and that the four-quark content of mesons is a hot issue both experimentally and theoretically, the predicted results of the paper may be helpful for upcoming experimental and theoretical studies of these mesons.     

取代亚胺中亚胺基15N NMR化学位移规律的研究

提出了计算苯甲醛亚胺、N-苯基亚胺、N-甲基亚胺、N-异丙基亚胺中亚胺基氮原子¹⁵N NMR化学位移的经验公式：δ_cal=δ_0n+Δα+Δβ+Δγ+c. 按亚胺基氮原子和碳原子上两类取代基的不同分别结合最小二乘法通过线性回归各得到5种取代基参数,计算结果分别以其化学位移数据为样本点作回归检验,置信度为99.5%,最大误差Δδ≤3.1,大约有95%的¹⁵N NMR化学位移计算值的计算误差小于3.0（相对误差小于0.3%）. 初步分析了芳香族亚胺苯环上对位取代基对亚胺基氮原子化学位移的影响.     

Experimental Study of High-Spin Band Structures of 183Au

High-spin states in ¹⁸³Au have been studied experimentally using heavy-ion-induced fusion-evaporation reaction and standard in-beam γ-ray spectroscopic techniques. The level scheme of ¹⁸³Au was revised and extended. A rotational band proposed as the unfavored signature branch of the πi_13/2 band has been observed for the first time. Interaction properties between the two negative-signature bands of the πh_9/2-πf^7/2 system have been discussed for the light odd-A Au nuclei.     

New band structures in 107Ag

High spin states in ¹⁰⁷Ag are studied via the ¹⁰⁰Mo(¹¹B, 4n)¹⁰⁷Ag reaction at an incident beam energy of 60 MeV. Prompt γ-γ coincidence and DCO ratios are measured by the detector arrays in CIAE. The level scheme has been updated and a new negative band belonging to ¹⁰⁷Ag is identified. The new negative side band has been constructed and its configuration is tentatively assigned to πg_9/2 νh_11/2(g_7/2/d_5/2).     

Configuration-Dependent Bands in 169Re

High-spin states in ¹⁶⁹Re were studied and resulted in the identification of a strongly coupled band based on the 9/2^－[514] Nilsson state and a decoupled band built on the h_9/2 intruder proton orbital (nominally 1/2^－[541]). The cranked shell nodel calculations present configuration-dependent deformations that can explain the different band crossing frecpiencies. The experimental 9/2^－[514] band in Re shows the largest signature splitting at low spin among the known odd mass Re isotopes. After the alignment of a pair of the i_13/2 neutrons, the phase of the splitting is inverted with a significantly reduced amplitude. Additionally, a three-quasipariticle band was observed and assigned to be built likely on the π9/2^－[514]⊙AE configuration.     

Collective Band Structures in Neutron-Rich Odd-A 145,147Ce Nuclei

Through study of the prompt r-rays emitted in the spontaneous fission of ²⁵²Cf, high spin states of neutron-rich odd-A ^145,147Ce nuclei have been investigated. The levels in ¹⁴⁷Ce have been extended. A collective band in ¹⁴⁵Ce have been identified for the first time. The results from the particle rotor model calculations indicate that the yrast bands in ¹⁴⁵Ce and ¹⁴⁷Ce originate from vi_13/2 orbital coupling and the ground states of ¹⁴⁵Ce and ¹⁴⁷Ce originate from (vh_9/2,vf_7/2) and vh_9/2 configiration, respectively. No obvious octupole deformation was observed in these two isotopes, but a side band obtained in ¹⁴⁷Ce may show some octupole correlations.     

A New Level Scheme of 127I

Study of in beam γ ray spectroscopy of ¹²⁷I has been performed using ¹²⁴Sn(⁷Li, 4n)¹²⁷I reaction at 32 MeV beam energy. A new level scheme of ¹²⁷I has been established including 25 new levels and 52 new γ transitions. Negative parity levels based on 11/2^－ π h_11/2 particle state have been observed up to (35/2^－) extending our knowledge of decoupled structures to the heavier iodine isotope. Two ΔI=2 yrast positive-parity levels have been proposed to be associated mainly with the πg_7/2 configuration due to observations of several strong inter band transitions. Two weakly populated ΔI=2 positive parity levels and a high-lying ΔI=1 cascade have been newly identified and tentatively assigned as πd_5/2 one-quasiparticle and three quasiparticle bands, respectively.     

Measurement of Angular Distribution for the ^8Li（p,d）^7Li Reaction

The ^8Li（p, d）^7 Li reaction plays an important role in the inhomogeneous Big Bang nucleosynthesis and in the seed-nuclide production phase for the r-process. For the first time, its angular distribution at backward angles was measured in inverse kinematics at Ec.m.=4.0 MeV by using an ^8Li secondary beam. The result of measurement includes the contributions of ^8Li（p, d0）^7Li and ^8Li（p, d1）^7Li^＊. The ^8Li（p, d0）^7Li component is estimated to be 40%-58% in the mixture angular distribution by analysing the measured result.     

Mixing between the 23S1 and 13D1 Ds

Mixing between the 2³S₁ and 1³D₁ D_s is studied within the ³P₀ model. If mixing between these two 1^- states exists, D_s1^*(2700)^± and D_sJ^*(2860)^± could be interpreted as the two orthogonal mixed states with mixing angle θ≈ -80° in the case of a special β for each meson. However, in the case of a universal β for all mesons, D_s1^*(2700)^± could be interpreted as the mixed state of 2³S₁ and 1³D₁ with mixing angle 12° < θ < 21° but D_sJ^*(2860)^± seems difficult to interpret as the orthogonal partner of D_s1^*(2700)^±.